• Journal of Industrial and Engineering Chemistry
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• 제67권
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• pp.478-485
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• 2018

The effect of reduced graphene oxide (RGO) addition on the dielectric and piezoelectric behavior of the polyvinylidene fluoride (PVDF) films was studied. Dielectric constant increased by four times and piezoelectric coefficient also increased twice by the addition of RGO in the PVDF films. Based on capacitance-voltage and ellipsometry measurements and the Kramers-Kronig transformation, it is concluded that the enhanced dielectric and piezoelectric properties of the PVDF/RGO films resulted from the increased orientational polarization due to a phase transition from nonpolar crystalline ${\alpha}$ phase to polar crystalline ${\beta}$ phase in the PVDF structure.

• Progress in Superconductivity
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• 제3권1호
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• pp.74-77
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• 2001

We have fabricated a high-Tc superconductive transistor with polyvinylidene fluoride (PVDF) gate electrode on MgO bicrystal Josephson junction by spin-coating method. The PVDF ferroelectric film is found to be suitable fur a gate electrode of the superconductive transistor since it has not only small leakage current but also high dieletric constant at low temperature. For the application of superconducting-FET, we investigated millimeter wave properties (60 GHz band) of the Josephson junction with PVDF gate electrode.

• 비파괴검사학회지
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• 제17권1호
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• pp.23-30
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• 1997

최근 시료 내부의 미세 결함의 측정을 위하여 초음파의 발생 소자로 polyvinylidene fluoride(PVDF)나 polyvinylidene fluoride trifluoroethylene P(VDF-TrFE) 압전 재료를 사용한 광대역 고주파수 초음파 탐촉자가 이용되고 있다. 중심 주파수 80MHz의 PVDF 수침용 집속형 초음파 탐촉자의 특성과 물과 시료에서의 초음파의 검출장을 측정하였으며 강재 시편에서의 결함 검출능을 측정하였다. 물과 강재 시험편에서 고주파수 초음파의 감쇠가 결함 검출능을 좌우하는 주요 변수이었다. 작은 결정립을 지닌 크롬-니켈강 재료를 사용하여 12mm 깊이에 직경 $50{\mu}m$에서 $560{\mu}m$ 범위의 flat-bottom hole들을 가공한 시편을 준비하였고 C-scan과 B-scan을 수행하였다. 직경 $280{\mu}m$ 이상의 flat-bottom hole들은 검출되었고 파장에 대한 결함 크기의 비가 약 0.48 이하의 결함은 검출되지 않았다. 시편에 초음파의 고주파수 성분이 입사되었으나 약 25MHz 이상의 고주파수 성분이 시편내의 초음파의 전파 경로에서 모두 감쇠되어 더 작은 결함에 대한 검출장이 형성되지 못했다.

• International journal of advanced smart convergence
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• 제2권2호
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• pp.16-18
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• 2013

In this paper, we develop a method to design a flexible thin film audio systems utilizing Polyvinylidene fluoride. The system we designed showed the properties of increased transparency and sound pressure levels. As an input terminal transparent oxide thin film is adopted. In order to provide dielectric insulation, a transparent insulating oxide thin film is coated to obtain double -layered structure. In the range of visible light, the output from the output of the system showed an increased and improved sound pressure level. The piezoelectric polymer film of polyvinylidene fluoride (PVDF) is used to produce mechanical vibration due to the applied electrical voltage signal. An analog electric voltage signal is transformed into sound waves in the audio system.

• Journal of Radiation Protection and Research
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• 제48권4호
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• pp.184-196
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• 2023

Background: Radiation protection is crucial in various fields due to the harmful effects of radiation. Shielding is used to reduce radiation exposure, but gamma radiation poses challenges due to its high energy and penetration capabilities. Materials and Methods: This work investigates the radiation shielding properties of polyvinylidene fluoride (PVDF) samples containing different weight fraction of tungsten carbide (WC), tungsten trioxide (WO₃), and tungsten disulfide (WS₂). Parameters such as the mass attenuation coefficient (MAC), half-value layer (HVL), mean free path (MFP), effective atomic number (Z_eff), and macroscopic effective removal cross-section for fast neutrons (Σ_R) were calculated using the Phy-X/PSD software. EpiXS simulations were conducted for MAC validation. Results and Discussion: Increasing the weight fraction of the additives resulted in higher MAC values, indicating improved radiation shielding. PVDF-xWC showed the highest percentage increase in MAC values. MFP results indicated that PVDF-0.20WC has the lowest values, suggesting superior shielding properties compared to PVDF-0.20WO₃ and PVDF-0.20WS₂. PVDF-0.20WC also exhibited the highest Z_eff values, while PVDF-0.20WS₂ showed a slightly higher increase in Z_eff at energies of 0.662 and 1.333 MeV. PVDF-0.20WC has demonstrated the highest Σ_R value, indicating effective shielding against fast neutrons, while PVDF-0.20WS₂ had the lowest Σ_R value. The Monte Carlo N-Particle Transport version 5 (MCNP5) simulations showed that PVDF-xWC attenuates gamma radiation more than pure PVDF, significantly decreasing the dose equivalent rate. Conclusion: Overall, this research provides insights into the radiation shielding properties of PVDF mixtures, with PVDF-xWC showing the most promising results.

• 한국안전학회지
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• 제19권3호
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• pp.26-31
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• 2004

The radiation-induced changes taking place in poly(vinylidene fluoride) (PVDF) exposed to $^{60}Co$ $\gamma-ray$ irradiation were investigated in correlation with the applied doses. Samples were irradiated in air at room temperature by $^{60}Co$ $\gamma-ray$ to doses in the range of 200 to 1000kGy. Various properties of the irradiated PVDF were studied using FTIR, differential scanning calorimetry (DSC), gel fraction and elongation. $^{60}Co\gamma-ray$ irradiation was found to induce changes in chemical, thermal, mechanical and structural properties of PVDF and such changes vary depending on the radiation dose.

• 한국재료학회지
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• 제15권6호
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• pp.382-387
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• 2005

Polyvinylidene fluoride (PVDF) surface was irradiated and became superhydrophilic by low energy (180 eV) and high flux $(\~10^{15}/cm{\cdot}s)$ ion beam. As an ion source, a closed electron Hall drift thruster of $\phi=70mm$ outer channel size without grid was adopted. Ar, $O_2$ and $N_2O$ were used for source gases. When $N_2O^+$ and $O_2^+$ reactive gas ion beam were irradiated with the ion fluence of $5\times10^{15}/cm^2$, the wetting angle for deionized water was drastically dropped from $61^{\circ}\;to\;4^{\circ}\;and\;2^{\circ}$, respectively. Surface energy was also increased up to from 44 mN/m to 81 mN/m. Change of chemical component in PVDF surface was analyzed by x-ray photoelectron spectroscopy. Such a great increase of the surface energy was intimately related with the increase of hydrophilic group component in reactive ion irradiated PVDF surfaces. By using an atomic force microscopy, the root-mean-square of surface roughness of ion irradiated PVDF was not much altered compared to that of pristine PVDF.

• 센서학회지
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• 제14권4호
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• pp.225-230
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• 2005

This paper describes a novel tip position sensor made of a triangularly shaped piezoelectric PVDF (polyvinylidene fluoride) film for a cantilever beam. Due to the boundary condition of the cantilever beam and the spatial sensitivity function of the sensor, the charge output of the sensor is proportional to the tip position of the beam. Experimental results with the PVDF sensor were compared with those using two commercially available position sensors: an inductive sensor and an accelerometer. The resonance frequencies of the test beam, measured using the PVDF sensor, matched well with those measured with the two commercial sensors and the PVDF sensor also showed good coherence over wide frequency range, whereas the inductive sensor became poor above a certain frequency.

• Membrane and Water Treatment
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• 제8권2호
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• pp.149-160
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• 2017

This study investigated effects of NaOH cleaning on the intrinsic permeability of polyvinylidene fluoride (PVDF) membranes and flux recoveries and membrane resistances under various conditions encountered during ultrafiltration in water treatment plants. The NaOH cleaning using 10,000 mg/L NaOH led to discoloration of PVDF membranes and had little effect on water flux. The NaOH cleaning was efficient in removing the fouling layer caused by humic water. However, long filtration induced a fouling layer that was not removed easily by NaOH cleaning. The lower temperature during filtration yielded rapid increases in transmembrane pressure and decreases in NaOH cleaning efficiency. The alkaline cleaning of PVDF changed the membrane properties such as the hydrophobicity and morphology. Foulant properties, operational conditions such as temperature, and chemical agents should be considered for cleaning strategies for PVDF applied in water treatment.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1995년도 추계학술대회 논문집 학회본부
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• pp.420-422
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• 1995

PVDF (polyvinylidene fluoride) has at least from known crystalline structure ( ; they are referred to as the $\alpha$, $\beta$, $\gamma$ and $\alpha_p$ phase or forms II, I, III and $IV_p$). In this study, the manufactured PVDF thin films through vapor deposition method had for II ( ; the substrate temperature at 30$^{\circ}C$). The dielectric behavior of poly(vinylidene fluoride) is affected by orientation and crystal modification. The very high value of the dielectric constant for high temperature conditioned film is believed to be due to the orientation effect. The loss peak caused by molecular motion of the molecules in crystalline regions.