• Applied Chemistry for Engineering
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• v.33 no.4
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• pp.367-372
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• 2022

The effect of the addition of a polyvinylchloride (PVC) non-solvent to a PVC-tetrahydrofuran (THF) solution on the surface properties of the PVC thin film was analyzed. The non-solvents used were composed of alcohol-based and non-alcoholic ones. Surface morphologies of PVC thin films according to the addition of the non-solvent were compared. In addition, the hydrophobic properties relying on the surface characteristics were compared. The micro-bubbles generated in the preparation of PVC-THF solution affected the surface morphology of the thin film. In order to implement the normal surface physical properties of the coating thin film at the relatively high concentration of PVC-THF solution, the selection of appropriate drying method was required. When an alcohol-based non-solvent was added, a PVC thin film having a granular porous surface was obtained and exhibited super hydrophobic properties. The volume ratio of the PVC-THF solution to the non-solvent affects the surface shape of the coating thin film. The larger the amount of non-solvent was added, the more advantageous it was to form a super hydrophobic PVC thin film.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.14 no.2
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• pp.53-56
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• 2008

Polyvinylchloride(PVC) is variously used to produce food packaging, wrap film, sealing compound of drinking bottle cap. Safety of these PVC food package is controlled by Food Code, PVC regulation. This study was carried out researches on manufacture process, physical, chemical properties and monomer(CAS No., common name, molecular structure) of PVC to help the understanding of PVC material. Also, this study helps us the understanding of regulation through researches on the foundation of PVC regulation, the purpose of test and the comment of test method. It is considered that these informations of material properties and explanations of test method are very useful to PVC producers, users and analyzers of them.

• Elastomers and Composites
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• v.45 no.4
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• pp.250-255
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• 2010

From the three element non-Newtonian model of one non-Newtonian viscoelastic Maxwell elements and a elastic spring, the stress relaxation equation was derived. The various model parameters of this equation were evaluated by appling the experimental results of stress relaxation to the stress relaxation equation. The theoretical curves calculated from this model parameters agreed with the experimental stress relaxation curves. From the parameters of nonlinear viscoelastic model, the hole volume, fine structure, viscoelastic properties and mechanical properties of polymer fibers were studied. The experiments of stress relaxation were carried out using the tensile tester with the solvent chamber. The stress relaxation curves of the two types polyacrylonitrile-polyvinylchloride copolymer and another two types PVC monofilament fibers were obtained in air and water of various temperatures.

• Journal of the Korea Safety Management & Science
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• v.11 no.3
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• pp.217-226
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• 2009

The combustion reaction of polyvinylchloride(PVC) was investigated using a thermogravimetric technique under an air atmosphere condition at several heating rates from 10 to $50^{\circ}C$/min. To obtain information on the kinetic parameters, the dynamic thermogravimetric analysis curve and its derivative were analyzed by a variety of analytical methods such as Kissinger, Friedman, Chatterjee-Conrad, Ozawa and Coats-Redfern methods. The combustion reaction of PVC proceeded in two steps; the first step was caused by the dehydrochlorination process in PVC, and the second step by the combustion of polyene. The comparative works for the kinetic results obtained from various methods should be performed to determine the kinetic parameters, because there are tremendous differences in the calculated kinetic parameters depending upon the mathematical method taken in the analysis.

• Applied Chemistry for Engineering
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• v.26 no.1
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• pp.35-39
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• 2015

Polyvinylchloride (PVC) thin films having a microporous structure could be prepared by using the solubility difference in solvents. PVC thin film with a water contact angle of $150^{\circ}$ or more was obtained from the PVC solution consisting of the mixture of tetrahydrofuran as a solvent and propanol as a non-solvent. In the drying process of dip-coated PVC film, the increase of drying temperature reduced the tendency of roughened surface, which led the decrease of surface hydrophobicity. As the addition of propanol in the solution with 1 wt% PVC increased, the uniformity of surface roughness was improved. In the case of oxygen plasma treatments, even though the surface structure of PVC thin film was not notably changed, the surface property of the film was changed from the super-hydrophobicity to hydrophilicity as a function of the plasma exposing time.

• Proceedings of the Korean Fiber Society Conference
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• 2002.04a
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• pp.259-262
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• 2002

Polyvinylchloride(PVC)는 1838년 Regnault에 의해 처음으로 합성된 고분자로 1920년대 후반부터 섬유로 이용하기 위한 많은 연구가 시도되었으나, 상업적 규모로 제조되기 시작한 것은 1942년경부터였다[l]. 현재, PVC는 건축자재용 파이프, 필름 등의 포장재, 가구 및 수송자재, 자동차 내장재 등의 다양한 용도로 사용되어지고 있으나, 다른 폴리머에 비해 열안정성이 낮아 분해시 HCl 외에도 benzene, naphthalene, toluene과 다른 alkylated benzene이 방출되어 유독성과 금형 및 기기의 부식에 있어서 문제가 되고 있다[2]. (중략)

• Proceedings of the Membrane Society of Korea Conference
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• 1992.10a
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• pp.49-52
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• 1992

본 연구에서는 기체분리용 고분자 분리막을 박막화하기 위하여 기체의 선택도와 투과도가 서로 상이한 celluloseacetate(CA), polyvinylchloride(PVC) 및 polystyrene(PS) 등의 고분자용액을 사용하여 수면전개법에 수면 전개기구와 박막의 구조적 특성을 연구하였고, 또한 기체 분리막으로서의 이 수면전개막을 개발하기 위하여 CA, PVC, PS 단일 적층막, CA-PVC 복합적 층막, PVC/PS 혼합적층막의 형태로 제막하여 기체분리효과를 검토하였다.

• Applied Chemistry for Engineering
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• v.5 no.2
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• pp.215-222
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• 1994

As a toughness modifier for plastics chlorosulfonated polyethylene(CSM) can be used. CSM has a good resistance to oxygen and ozone. CSM has a crosslinkable functional group(sulfonyl chorid) with sulfur and metal oxide. Polyvinylchloride(PVC) is widely used industrial plastics because of its balanced properties and low cost. But it has some disadvantages such as low impact strength, light, ozone and oxygen degradation. In order to improve these properties of PVC, CSM was blended with PVC. The toughening effect appeared at about 10wt% and there is no additional effect above 30wt% of CSM. The weatherability, ozone resistance and mechanical properties of PVC were improved by blending with CSM. The toughening mechanism is studied by SEM.

• Journal of Radiation Protection and Research
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• v.3 no.1
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• pp.23-28
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• 1978

In order to investigate corelation between contents of dioctylphthalate in polyvinylchloride blent dibutyl tin dilaulate with dibutyl tin maleate as stabilizer and the behaviors of radiation resistance as well as electrical conductivity on irradiated specimens, several observations were carried out. A characteristic peak observed in the range of $1,540-1,640cm^{-1}$ on infrared spectra shows such a sensitive response to radiation as the intensity decreases with increasing doses and that this tendency strongly depressed in the presence of plasticizer. It is seemingly attributed for origin of the peak to the existence of RCOO- ion resulting from dissociation of stabilizere, further the depressive effect of decreasing peak intensity influenced by radiation seems to be caused by resonance absorption in benzen ring being a consistituent of plasticizer. It is also suggestive to be use the peak behavior influenced by radiation as a criterion for the evaluation of radiation resistance of PVC. Further the results obtained from electrical conductivity measurement also exhibit reasonable characteristics explainable with views used for the interpretation of the peak behavior mentioned previousely.

• Proceedings of the Korean Fiber Society Conference
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• 1998.10a
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• pp.83-86
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• 1998

PVC사의 연신은 Fig. 1과 같이 끊는 물 속에서 이루어지며 연신 후 정전기 방지를 위해 유제를 습식 방법으로 처리한다. 따라서 건조와 heat set chamber에 들어가기 전 어느 정도의 수분과 유제를 함유한 체 각각의 chamber를 통과하며 건조, heat set된다. 본 연구의 목표는 연신 후 squeezing roller의 접압에 따른 건조시간의 관계와 heat set온도, 시간에 따른 열 수축률의 관계를 알아보고자 한다. (중략)