• Fire Science and Engineering
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• v.16 no.4
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• pp.77-84
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• 2002

In this paper, we had analyzed comsbustion gases using a GASTEC colorimetric gas detector tube according to the method of NES 713 in order to combustion gases toxicity evaluation for beads polystyrene foam, extruded polystyrene foam, rigid polyurethane foam, flexible polyurethane foam, flexible polyvinyl chloride pipe, vinyl floor cover, polyethyelene foam(flame retardant untreated) and polyethyelene foam (flame retardant treated) of plastics material. As results of gas analyses by using this method, comsbustion gases producted from small specimens of plastics material had reached fatal to man at 30 minutes exposure time that had possesed toxicity index of more than 1. Toxicity indexes of each specimen were estimated range of 4.3∼179.2, flexible polyvinyl chloride showed the hightest toxicity index at 179.2, and beads polystyrene foams showed the lowest toxicity index at 4.3.

• YAKHAK HOEJI
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• v.33 no.4
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• pp.211-218
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• 1989

Twenty-six injectable drug products, many of which are administered by i.v. infusion, were studied for loss from aqueous solutions stored in polyvinyl chloride (PVC) infusion bags for various periods of time. The PVC infusion bags were stored in the dark room at room temperature for up to one month. Drugs stored in glass bottle served as controls. The solutions were assayed Spectrophotometrically at regular intervals. The effect of drug concentration and pH on the loss of drug from solution were studied. Octanol-water partition coefficients were used as a guage of lipid solubility of drugs. The elution of di(2-ethylhexyl)phthalate(DEHT) from PVC infusion bags was studied. For most of the drug studied, minimal loss from the aqueous solutions were observed over periods of storage time. Six of the drug products - Thiopental sodium, Hydralazine HCl, Thioridazine HCl, Trifluoperazine 2HCl, Metronidazole, Chlorpromazine HCl - were found to be lost a substantial extent. DEHP was found to be migrating from PVC infusion bags.

• Elastomers and Composites
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• v.54 no.4
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• pp.294-298
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• 2019

A three-layered PVC sheet consisting of polyvinyl chloride (PVC) and woven polyester fabric was prepared by extrusion and calendering. The flexibility and durability of the PVC were tuned by adding plasticizers, additives, and surface coatings. The tensile and tear strengths of the three-layered PVC sheet were higher than those of commercial two-layered sheet, while exhibiting low weight. The concentrations of the total volatile organic compounds (TVOCs) and formaldehyde (HCHO) emitted from the sheet were also lowered. The PVC sheet remained stable after prolonged exposure to UV light, signifying that the PVC sheet is suitable for cargo screen applications.

• Advances in nano research
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• v.15 no.3
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• pp.253-261
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• 2023

This study investigates the application of nano-composite materials in physical education, specifically focusing on improving the performance of sports hall flooring. The research centers on carbon nanotube reinforced polyvinyl chloride (PVC) composites, which offer enhanced mechanical properties and durability. The incorporation of carbon nanotubes as reinforcements in the PVC matrix provides notable benefits, including increased strength, improved thermal stability, electrical conductivity, and resistance to fatigue. The key parameters examined in this study are the weight percentage of carbon nanotubes and the temperature during the fabrication process. Through careful analysis, it is found that higher weight percentages of carbon nanotubes contribute to a more uniform dispersion within the PVC matrix, resulting in improved mechanical properties. Additionally, higher fabrication temperatures aid in repairing macroscopic defects, leading to enhanced overall performance. The findings of this study indicate that the utilization of carbon nanotube reinforced PVC composites can significantly enhance the strength and durability of sports hall flooring. By employing these advanced materials, the safety and suitability of physical education environments can be greatly improved. Furthermore, the insights gained from this research can contribute to the optimization of composite material design and fabrication techniques, not only in the field of physical education but also in various industries where composite materials find applications.

• Journal of the Korean Chemical Society
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• v.7 no.2
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• pp.96-105
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• 1963

The weight decrease curves of 18 kinds of polymers have been measured by thermobalance at the same condition where temperature is increased $1^{\circ}C$ per minutes under nitrogen or air atmosphere. The curves are further differentiated to obtain rate curve of weight decrease. Those curve offer a method to compare relative thermal stability, effects of oxygen or modes of thermal degradation of polymers qualitatively. The curves could be classified into following four types: Polystyrene, polymethylmethacrylate and acetal polymer belong to the first type. Those polymers depolymerize mainly into corresponding monomers, weight decrease curves are steepy up to perfect vaporization of polymers and rate curves show a relatively sharp peak. (Type I) Polyvinyl chloride represents the second type. This polymer decomposes with splitting off of hydrogen chloride. The thermogravimetric curve rises rapidly at first, then level off at the moderate weight decrease and gradually rises. Polyvinyl acetate also belongs to this class. (Type II) The modification of the second type is represented by polyester. The curve at the early stage is less steep, the leveling off at the next stage is less clear and the final rising of the curve is steeper than the normal second type. Polyamide, polyurethane, and polycarbonate belong to this type. (Type II') The thermal decomposition of the third type polymers is more complex than that of others. Various irregular chain scissions including side chain splitting and depolymerization to monomers occur simultaneously. The weight of the polymer decreases gradually and the rate curve does not show sharp peaks. Polyvinyl alcohol and diene polymers belong to this type. (Type III) Generally, polycondensation polymers are more stable toward heat than addition polymers and polymers having aromatic nucleus show good thermal stability. Polymers having tertiary carbon atoms such as polystyrene or polypropylene and acetal resin start decomposition under airatmosphere at the temprature below $50^{\circ}C$ or more of the temperature where the polymers start decomposition under nitrogen atmosphere.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.19 no.3
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• pp.139-141
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• 2013

In respect of environmental hazard or human safety, the use of the chloride-based packaging materials like polyvinyl chloride (PVC) blister and film, Polyvinylidene chloride (PVDC) laminated film has been restricted with national regulations. In this study, I intended to develope the reagent solution for identifying the chloride-based packaging materials, so that it was made by mixing methanol ($CH_3OH$) saturated with sodium hydroxide (NaOH) and pyridine as solvent with same ratio. The efficacy of this reagent solution was verified by the analysis of chemical mechanism and experiments that showed the color change (brown) of the specimens. This analysis methode using reagent solution is so simple, convenient, inexpensive and immediate that I expect it will be useful in the field of packaging.

• Journal of Conservation Science
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• v.31 no.2
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• pp.87-94
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• 2015

Plastic artwork can be appeared crack, change of color and whitening event by various environment conditions. A large scale plastic artwork often exhibits in outside it will be directly degraded by physical and chemical degradation factor such as strong sunlight, high humidity and rainfall. We should know degradation characteristic of plastics to prevent these damages. In this study, we studied degradation characteristic of plastics (5 types of wide use plastics; polypropylene, polystyrene, polyethylene, polyvinyl chloride, polyurethane) depending on various artificial degradation conditions such as high temperature, ultraviolet and these complex conditions (high temperature and ultraviolet). As a result, polypropylene, polystyrene and polyethylene show the most visible change especially polypropylene, polystyrene. Polypropylene didn't show a great change degree of tensile strength and contact angle, on the other hand polystyrene did. Polypropylene and polystyrene weakened by photo degradation, polyvinyl chloride and polyurethane had relatively good light stability. Also the high temperature and complex conditions were most degradation characteristic. High temperature worked for degradation catalyst because its energy can not enough worked for cut off binding energy of plastics while ultraviolet condition effected as directly degradation condition. Though following results, we expect it can be applied to investigation of degradation factor depending on plastic artwork materials and basic result of plastic artworks conservation.

• The Korean Journal of Rheology
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• v.2 no.1
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• pp.27-32
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• 1990

본 연구에서는 전선피복 die 내고분자 물질의 이동현상에 관한여 Carreau model을 도입하여 유한요소법으로 수치해석을 수행하였다. Polyvinyl chloride(PVC)의 유변상수들의 변화가 유동에 미치는 영향을 조사하였고 온도에 따른 점도의 변화를 고려한 비등온 조건 및 전선피복 공정에서 발생할 수 있는 slip 경계조건을 적용시킨 경우에 대한 수치모사도 수행하였다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.161-161
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• 2016

연질 폴리염화비닐 졸 (PVC Sol) 코팅의 물리적, 화학적 내구성을 향상시키기 위하여 표면 개질된 무기물 입자를 첨가시킨 PVC 코팅을 형성하였고 그 특성을 분석하였다. 이를 통해 다양한 분야에 적용할 수 있는 고내구성 PVC sol 코팅공정을 확립하였다.

• Journal of the Korean Chemical Society
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• v.52 no.2
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• pp.133-139
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• 2008

A new sensitive and selective spectrophotometric method for determination of trace amounts of cadmium using a polyvinyl chloride membrane containing bis-(2-ethylhexyl)phthalate as a solid phase extraction medium was investigated. Bis-(2-ethylhexyl)phthalate has used as a plasticizer. Cd(II) in an aqueous solution was trapped on the membrane in the form of colorful Cd (II)-I- - MG complexes (which MG is malachite green) and the cadmium complex was concentrated in the membrane. The absorbance of the green membrane was measured at 629 nm using a spectrophotometer, and then, the concentration of the cadmium was calculated using a calibration curve, which expressed the relationship between the Cd(II) concentration and the membrane absorbance after coloring for 25 min. The calibration curve was linear in the range of 10-760 μgL-1 cadmium in the test solution. The detection limit based on the 3Sbl criterion was 1.8199 μgL-1 and the relative standard deviations (RSD) were less than 4 % (n=5). The proposed method has been successfully applied to the determination of trace amounts of cadmium in the Tadjan River water sample (Sari-Iran), and the mean value of 28.7 μgL-1 was obtained.