• Title/Summary/Keyword: polyvinyl alcohol(PVA)

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Engineering Property of Basalt Fiber as a Reinforcing Fiber (보강 섬유로서 현무암 섬유의 공학적 특성)

  • Choi, Jeong-Il;Jang, Yu-Hyun;Lee, Jae-Won;Lee, Bang-Yeon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.1
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    • pp.84-89
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    • 2015
  • Basalt fiber has many advantages as a reinforcing fiber such as high tensile strength and similar density to concrete. This study investigated the bonding property and the effect of fiber orientation on tensile strength of basalt fiber. Single fiber pullout tests for basalt and polyvinyl alcohol (PVA) fibers were performed to evaluate the bonding property between basalt fiber and mortar. And then tensile strength of basalt, PVA, and polyethylene (PE) fibers according to fiber orientation were measured. From the test results, it was exhibited that the chemical bond, frictional bond, and slip-hardening coefficient of basalt fiber were 1.88, 1.03, 0.24 times of PVA fibers, respectively. And the strength reduction coefficient of basalt fiber was 9 times of PVA fiber and 3 times of PE fiber.

Evaluating Local Damages and Blast Resistance of RC Slabs Subjected to Contact Detonation (접촉 폭발 하중을 받는 RC 슬래브의 국부 손상 및 내폭 성능 평가)

  • Li, Ling;Lee, Jin Young;Min, Kyung Hwan;Yoon, Young Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.1
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    • pp.37-45
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    • 2013
  • In this study, the resistance of various reinforced concrete (RC) slabs subjected to contact detonation was assessed. In order to enhance the blast resistance, fibers and external FRP sheets were reinforced to RC slabs. In the experiment, the $2,000{\times}1,000{\times}100mm$ sized RC slabs were fabricated using normal concrete (NC), steel fiber reinforced concrete (SFRC), polyvinyl alcohol fiber reinforced cementitious composite (PVA FRCC), and ultra-high performance cementitious composites (UHPCC). The damage levels of RC slabs subjected to contact detonation were evaluated by measuring the diameter and depth of crater, spall and breach. The experimental results were compared to the analyzed data using LS-DYNA program and three different prediction equations. The diameter and depth of crater, spall and breach were able to be predicted using LS-DYNA program approximately. The damage process of RC slabs under blast load was also well expressed. Three prediction equations suggested by other researchers had limitations to apply in terms of empirical approaches, therefore it needs further research to set more analytical considerations.

Effect of Macromolecules in Maturation Medium on Oocyte Maturation and Embryonic Development after Parthenogenesis and Nuclear Transfer in Pigs

  • You, Jin-Young;Kim, Jin-Young;Lee, Eun-Song
    • Journal of Embryo Transfer
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    • v.24 no.2
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    • pp.97-104
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    • 2009
  • The objective of this study was to examine the effect of macromolecule in a maturation medium on nuclear maturation, intracellular glutathione (GSH) level of oocytes, and embryonic development after parthenogenetic activation (PA) and somatic cell nuclear transfer (SCNT) in pigs. Immature pig oocytes were cultured in maturation medium that was supplemented with each polyvinyl alcohol (PVA), pig follicular fluid (pFF) or newborn calf serum (NBCS) during the first 22 h and the second 22 h. Oocyte maturation was not influenced by the source of macromolecules during in vitro maturation (IVM). Embryo cleavage and cell number in blastocyst after PA was altered by the source of macromolecule but no difference was observed in blastocyst formation among treatments. Oocytes matured in PVA-PVA medium showed lower rates of oocyte-cell fusion (70.4% vs. 77${\sim}$82%) and embryo cleavage (75% vs. 86${\sim}$90%) after SCNT than those matured in other media but blastocyst formation was not altered (13${\sim}$27%) by different macromolecules. pFF added to IVM medium significantly increased the intracellular GSH level of oocytes compared to PVA and NBCS, particularly when pFF was supplemented during the first 22 h of IVM. Our results demonstrate that source of macromolecule in IVM medium influences developmental competence of oocytes after PA and SCNT, and that pFF supplementation during the early period (first 22 h) of IVM increases intracellular GSH level of oocytes.

Bond Properties of GFRP Rebar in Fiber Reinforced Concrete (Engineered Cementitious Composite) (섬유보강 콘크리트(ECC)와 GFRP 보강근의 부착 특성)

  • Choi, Yun-Cheul;Park, Keum-Sung;Choi, Chang-Sik;Choi, Hyun-Ki
    • Journal of the Korea Concrete Institute
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    • v.23 no.6
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    • pp.809-815
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    • 2011
  • An experimental investigations on the bond-slip properties of the steel and Glass Fiber Reinforced Polymer(GFRP) bars in engineered cementitious composite (ECC) with Polyvinyl Alcohol (PVA) fibers are presented. Total of 8 beam specimens prepared according to the Rilem procedures with 2% of PVA and PE fiber volume percentage and steel and GFRP reinforcements significantly changed the failure mechanism and slightly improved bond strength. The main objective of the tests was to evaluate the load versus displacement and load versus slip behaviors and the bond strength for the following parameters: concrete type (normal and fiber concrete) and bar diameter (10 and 13 mm). The study results showed that ordinary concrete and ECC specimens showed similar behavior for steel reinforced specimen. However, GFRP reinforced specimen showed different behavior that the steel specimen. The code analytical results showed more accuracy compared to the experimental results as expected in conservative code provisions. Based on the obtained results, it is safe to conclude that the new parameters need to be adopted to ensure safe usage of ECC for construction applications.

Preparation and Characterization of transparent electrode based on polymer/metal oxide composite via electrospinning (전기 방사를 이용한 고분자/금속산화물 복합소재 기반의 투명전극 제조 및 특성 분석)

  • Kang, Hye Ju;Jeong, Hyeon Taek
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.6
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    • pp.1553-1560
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    • 2021
  • We have confirmed that optimized transmittance and surface resistance by electrospinning time, also the fabricated transparent electrode composed of silver nanofiber with excellent electrical, optical and mechanical performances is showed applicability to next generation flexible displays such as solar cells, displays, and touch screens. → We have confirmed the optimized transmittance and surface resistance by electrospinning time Also the fabricated transparent electrode composed of silver nanofiber with excellent electrical, optical and mechanical performances showed applicability to next generation flexible displays such as solar cells, displays, and touch screens.

Detrimental Effect of Bovine Serum Albumin in a Maturation Medium on Embryonic Development after Somatic Cell Nuclear Transfer in Pigs

  • Lee, Hanna;Lee, Yongjin;Park, Bola;Elahi, Fazle;Lee, Joohyeong;Choi, Jung Hoon;Lee, Seung Tae;Park, Choon-Keun;Hyun, Sang-Hwan;Lee, Eunsong
    • Journal of Embryo Transfer
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    • v.29 no.4
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    • pp.361-368
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    • 2014
  • This study was designed to evaluate the effect of bovine serum albumin (BSA) in a maturation medium on oocyte maturation and embryonic development in pigs. Immature pig oocytes were matured for 44 h in a medium supplemented with 0.4% (w/v) BSA, 0.1% (w/v) polyvinyl alcohol (PVA), or 10% (v/v) pig follicular fluid (PFF). After IVM, oocytes reached metaphase II stage were activated for parthenogenesis (PA) or used as cytoplasts for somatic cell nuclear transfer (SCNT). Nuclear maturation (89.5%, 90.7% and 91.3% for BSA, PVA and PFF, respectively) and intraoocyte glutathione contents (1.20, 1.16 and 1.00 pixels/oocyte for BSA, PVA and PFF, respectively) were not altered by the macromolecules added to maturation medium. IVM of oocytes in a medium containing BSA (21.4%) and PVA (20.7%) showed significantly lower blastocyst formation after PA than culture in medium with PFF (39.2%). After SCNT, oocytes matured in medium with BSA showed decreased embryonic development to the blastocyst stage (9.2%) compared to those matured in medium with PFF (28.9%), while 23.6% of SCNT oocytes matured in medium with PVA developed to the blastocyst stage. When the effect of BSA in a maturation medium during the first 22 h and the second 22 h of IVM in combination with PFF or PVA was examined, PVA-BSA showed a higher nuclear maturation (94.1%) than BSA-PFF (84.5%). However, there was no significant difference in the blastocyst formation among tested combinations (47.3, 52.2, 50.0, 44.4 and 49.0% for PFF-PFF, PFF-BSA, PVA-BSA, BSA-PVA and BSA-PFF, respectively). Our results demonstrate that BSA and PVA added to maturation medium can support oocyte maturation comparable to PFF-supplemented medium. However, maturation of oocytes in a BSA-containing medium decreases embryonic development after PA and SCNT when compared with the medium supplemented with PFF.

Effect of Cardanol Content on the Antibacterial Films Derived from Alginate-PVA Blended Matrix (알지네이트-폴리비닐알콜 블랜드 항균 필름 제조를 위한 카다놀 함량의 영향)

  • Ahn, Hee Ju;Kang, Kyung Soo;Song, Yun Ha;Lee, Da Hae;Kim, Mun Ho;Lee, Jae Kyoung;Woo, Hee Chul
    • Clean Technology
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    • v.28 no.1
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    • pp.24-31
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    • 2022
  • Petroleum-based plastics are used for various purposes and pose a significant threat to the earth's environment and ecosystem. Many efforts have been taken globally in different areas to find alternatives. As part of these efforts, this study manufactured alginate-based polyvinyl alcohol (PVA) blended films by casting from an aqueous solution prepared by mixing 10 wt% petroleum-based PVA with biodegradable, marine biomass-derived alginate. Glutaraldehyde was used as a cross-linking agent, and cardanol, an alkyl phenol-based bio-oil extracted from cashew nut shell, was added in the range of 0.1 to 2.0 wt% to grant antibacterial activity to the films. FTIR and TGA were performed to characterize the manufactured blended films, and the tensile strength, degree of swelling, and antibacterial activity were measured. Results obtained from the FTIR, TGA, and tensile strength test showed that alginate, the main component, was well distributed in the PVA by forming a matrix phase. The brittleness of alginate, a known weakness as a single component, and the low thermal durability of PVA were improved by cross-linking and hydrogen bonding of the functional groups between alginate and PVA. Addition of cardanol to the alginate-based PVA blend significantly improved the antibacterial activity against S. aureus and E. coli. The antibacterial performance was excellent with a death rate of 98% or higher for S. aureus and about 70% for E. coli at a contact time of 60 minutes. The optimal antibacterial activity of the alginate-PVA blended films was found with a cardanol content range between 0.1 to 0.5 wt%. These results show that cardanol-containing alginate-PVA blended films are suitable for use as various antibacterial materials, including as food packaging.

Flexural and Impact Resisting Performance of HPFRCCs Using Hybrid PVA Fibers (하이브리드 PVA 섬유를 이용한 HPFRCCs의 휨 및 충격 성능 평가)

  • Kim, Young-Woo;Min, Kyung-Hwan;Yang, Jun-Mo;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.705-712
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    • 2009
  • HPFRCCs (high-performance fiber reinforced cementitious composites), which is relatively more ductile and has the characteristic of high toughness with high fiber volume fractions, can be used in structures subjected to extreme loads and exposed to durability problems. In the case of PVA (polyvinyl alcohol) fiber, it is noted by former studies that around 2% fiber volume fractions contributes to the most effective performance at HPFRCCs. In this study, flexural tests were carried out to evaluate the flexural behavior of HPFRCCs and to optimize mix proportions. Two sets of hybrid fiber reinforced high performance specimens with total fiber volume fraction of 2 % were tested: the first set prepared by addition of short and long PVA fibers at different combination of fiber volume fractions, and the second set by addition of steel. In addition, in order to assess the performances of the HPFRCCs against to high strain rates, drop weight tests were conducted. Lastly, the sprayed FRP was applied on the bottom surface of specimens to compare their impact responses with non-reinforcing specimens. The experimental results showed that the specimen prepared with 1.6% short fibers (REC 15) and 0.4% long fiber (RF4000) outperformed the other specimens under flexure, and impact loading.

Synthesis of Oxide Ceramic Powders by Polymerized Organic-Inorganic Complex Route

  • Lee, Sang-Jin;Lee, Chung-Hyo;Waltraud M. Kriven
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 2000.06a
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    • pp.151-163
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    • 2000
  • A polymerized organic-inorganic complexation route is introduced for the synthesis of oxide ceramic powders. Polyvinyl alcohol was used as the organic carrier for precursor ceramic gel. Porous and soft powders, which have a high specific surface area, were obtained after calcinating the aerated precursors. The PVA content and its degree of polymerization had a significant influence on the homogeneity of the final powder. In particular, attrition milling process with the porous powder resulted in ultra-fine particles. In the case of the preparation of cordierite powder, nano-size powder, which has a high specific surface area of 181 ㎡/g, was obtained by the milling process. The complexation route was also applied to the synthesis of unstable phase in room temperature like beta-cristobalite, high temperature form of silica.

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Interfacial Properties of Polypropylene Fiber in High Performance Fiber Reinforced Cement Composites (고인성 섬유보강 복합체 내에서 폴리프로필렌 섬유의 계면 부착성능)

  • Han Byung-Chan;Jeon Esther;Park Wan-Shin;Lee Young-Seak;Hiroshi Fukuyama;Yun Hyun-Do
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.108-111
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    • 2004
  • The polypropylene(PP) fiber is poised as a low cost alternative for reinforcement in structural applications in comparison with other high performance fibers, such as the polyvinyl-alcohol(PVA), polyethylene, carbon and aramid fiber. The mechanical properties of the composite are strongly determined by the interfacial behavior of fiber and cementitious matrix. The crack bridging mechanism contribute to composite toughness from activation of the fiber-matrix interface where energy is dissipated through debonding of the interface and fiber pullout. In this study, therefore, the pullout behavior of PP fibers is investigated. Experimental work includes the investigation of the interfacial properties, and the composite property. The quantification of interfacial properties, the frictional bond is achieved through single fiber pullout test. A study on the effect of inclination angle on fiber pullout behavior is also conducted.

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