• Title/Summary/Keyword: polyvinyl alcohol(PVA)

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Characterization of Immobilized Denitrifying Bacteria Isolated from Municipal Sewage

  • Kim, Joong-Kyun;Kim, Sung-Koo;Kim, Sang-Hee
    • Journal of Microbiology and Biotechnology
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    • v.11 no.5
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    • pp.756-762
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    • 2001
  • As a component for a recirculating aquaculture system, a new strain of denitrifying bacterium was isolated from municipal sewage. The isolate was motile by means of one polar flagellum, catalase-positive, and a Gram-negative rod-shaped cell measuring $0.5-0.6{\mu}m$ in width and $1.3-1.9{\mu}m$ in length. The isolate was identified as Pseudomonas fluorescens and produced dinitrogen gas via the reduction of nitrate. The optimal growth conditions (pH, temperature, carbon source, and C/N ratio) of the isolate were found to be 6.8, $30^{\circ}C$, malate, and 3, respectively. Under optimal growth conditions of P. fluorescens, dinitrogen gas was first detected in the exponential growth phase, then a small amount of nitrite was developed and converted to dinitrogen gas in the stationary phase. Pseudomonas fluorescens cells were immobilized in modified polyvinyl alcohol (PVA) gel beads, and the maximum denitrification rate was measured as $36.6 {\mu}lN_2h^-1$ per bead with an optimum cell loading of $20mg {\mu}l^-1$ and $2\%$ sodium alginate added to the PVA gel. The operating stability of the modified PVA gel beads remained unchanged for up to 43 repeated batches.

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An Experimental Study for Basic Properties of Mortar Applied PC Panels by PVA and Nylon Fiber Ratio (PVA 및 나일론 섬유 혼입률에 따른 PC 패널용 모르타르의 기초 물성에 관한 실험적 연구)

  • Lee, Jae-Hyun;Song, Young-Chan;Kim, Yong-Ro;Kim, Ook-Jong;Lee, Do-Bum
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.137-140
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    • 2009
  • Nowadays, the high performance composite materials are famous for the new construction materials as the construction buildings are bigger and higher. Out of them of all, the fiber reinforced concrete and mortar have been studied to develop and strengthen the performances of concrete, such as tensile strength, durability and the resistibility of crack. Also, it is considered that precast concrete is important alternatives of dry process for saving time, upgrading the material's quality and the productivity. Thus, PC panel is being produced for the use of dry wall as well as exterior finishing materials and it requires lots of tests and studies to be conducted to meet the various functional conditions. According to this study, it is considered that PVA fiber might be more effective than nylon fiber for developing the exterior PC panels.

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Mechanical Properties and Impact Resistance of Hybrid Fiber Reinforced Concrete with Type of Reinforcing Fibers for Precast Concrete (하이브리드섬유보강 프리캐스트 콘크리트의 보강섬유 종류에 따른 역학적 특성 및 충격저항성)

  • Oh, Ri-On;Park, Chan Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.4
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    • pp.29-35
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    • 2013
  • The objective of the current study is to evaluate the effects depending on the types of reinforcing fibers being influential in view of mechanical properties and impact resistance of hybrid fiber reinforced concrete (HFRC) for applications to precast concrete structure. Hybrid fibers applied therefor were three types such as PP/MSF (polypropylene fiber+macro synthetic fiber), PVA/MAF (polyvinyl alcohol fiber+MSF) and JUTE/MSF (natural jute fiber+MSF), where the volume fraction of PP, PVA and natural jute was applied with 0.2 %, respectively, while based on 0.05 % volume fraction of MSF. The HFRC was tested for slump, compressive strength, flexural strength and impact resistance. The test result demonstrated that mixture of such hybrid fibers improve compressive strength, flexural strength and impact resistance of concrete. Moreover, it was found that HFRCs to which hydrophilic fibers, i.e. PVA/MSF and JUTE/MSF, were mixed show more improved features that HFRC to which non-hydrophilic fiber, i.e. PP/MSF was mixed. Meanwhile, the finding that PVA/MSF HFRC exhibited better performance than JUTE/MSF HFRC was attributed from the former having higher aspect ratio than that of the latter.

Mechanical Properties of Styrene-Butadiene Rubber Reinforced with Hybrids of Chitosan and Bamboo Charcoal/Silica

  • Li, Xiang Xu;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.54 no.1
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    • pp.22-29
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    • 2019
  • Chitosan-polyvinyl alcohol (PVA) -bamboo charcoal/silica (CS-PVA-BC/SI) hybrid fillers with compatibilized styrene-butadiene rubber (SBR) composites were fabricated by the interpenetrating polymer network (IPN) method. The structure and composition of the composite samples were characterized by scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FT-IR). The viscoelastic behaviors of the rubber composites and their vulcanizates were explored using a rubber processing analyzer (RPA) in the rheometer, strain sweep and temperature sweep modes. The storage and loss moduli of SBR increased significantly with the incorporation of different hybrid fillers, which was attributed to the formation of an interphase between the hybrid fillers and rubber matrix, and the effective dispersion of the hybrid fillers. The mechanical properties (hardness, tensile strength, oxygen transmission rate, and swelling rate) of the composite samples were characterized in detail. From the results of the mechanical test, it was found that BC-CS-PVA0SBR had the best mechanical properties. Therefore, the BC-CS-PVA hybrid filler provided the best reinforcement effects for the SBR latex in this research.

Thermomechanical behavior of alkali-activated slag/fly ash composites with PVA fibers exposed to elevated temperatures

  • Kim, J.S.;Lee, H.K.
    • Advances in concrete construction
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    • v.11 no.1
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    • pp.11-18
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    • 2021
  • The present study fabricated polyvinyl alcohol (PVA) fiber-reinforced alkali-activated slag/fly ash (AASF) composites with varying mixture ratios of slag and fly ash. The thermomechanical behaviors of the AASF composites exposed to 200, 400, 600, or 800℃ were evaluated by means of compressive strength test, visual observation, and fire resistance tests. X-ray diffractometry, mercury intrusion porosimetry, and thermogravimetry tests were performed to analyze the microstructure change of the AASF composites upon exposure to high temperatures. Specimens exhibited a gradual strength loss up to 600℃, while also showing a significant decrease in the strength above 600℃. The fire resistance test revealed the occurrence of an inflection point as indicated by an increase in the internal temperature at around 200℃. In addition, specimens showed the dehydration of C-S-H gel, the presence of åkermanite, gehlenite, and anorthite upon exposure to 800℃, which is associated with the formation of macropore population with pores having diameters of 1-3 ㎛ and 20-40 ㎛. Visual observation indicated that the PVA fibers mitigated the cracking and/or spalling of the specimens upon exposure to 800℃.

Preparation of Pelletized Porous Adsorbent with Pyrolysis Temperature and Its Toluene Gas Adsorption Characteristics (열분해 조건에 따른 펠렛형 다공성 흡착재의 제조 및 톨루엔 가스 흡착 특성)

  • Kim, Do Young;Kim, Yesol;Cho, Seho;Jung, Jin-Young;Kim, Min Il;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.587-592
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    • 2013
  • In this study, we prepared pelletized porous carbon adsorbent (PCA) according to the different pyrolysis temperature using activated carbon and polyvinyl alcohol (PVA) as a binder for the removal of toluene, which is one of the representative volatile organic compounds (VOCs). We investigated physical characteristics of PCA using FE-SEM, BET, TGA and evaluated their adsorption capacity for toluene using GC. It was confirmed that the formability of pellets composed of the activated carbon, PVA and solvent of mass mixing ratio was 1 : 0.2 : 0.8 was the most outstanding. Toluene adsorption capacity was evaluated by measuring the maximum time when more than 99% of toluene adsorbed on the pellet. The specific surface area of the adsorbent pyrolyzed at $300^{\circ}C$ was measured as 4.7 times in $941.9m^2/g$ compared to that of the unpyrolyzed pellet. Micropore volume and toluene adsorption capacity of PCA increased fivefold to be 0.30 cc/g and thirteenfold to be 26 hours compared to that of the unpyrolyzed pellet, respectively. These results were attributed to the change of pore size and specific surface area due to the PVA content and the different pyrolysis temperature.

Usefulness of a new polyvinyl alcohol hydrogel (PVA-H)-based simulator for endoscopic submucosal dissection training: a pilot study

  • Dong Seok Lee;Gin Hyug Lee;Sang Gyun Kim;Kook Lae Lee;Ji Won Kim;Ji Bong Jeong;Yong Jin Jung;Hyoun Woo Kang
    • Clinical Endoscopy
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    • v.56 no.5
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    • pp.604-612
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    • 2023
  • Background/Aims: We developed a new endoscopic submucosal dissection (ESD) simulator and evaluated its efficacy and realism for use training endoscopists. Methods: An ESD simulator was constructed using polyvinyl alcohol hydrogel sheets and compared to a previous ESD simulator. Between March 1, 2020, and December 30, 2021, eight expert endoscopists from three different centers analyzed the procedure-related factors of the simulator. Five trainees performed gastric ESD exercises under the guidance of these experts. Results: Although the two ESD simulators provided overall favorable outcomes in terms of ESD-related factors, the new simulator had several benefits, including better marking of the target lesion's limits (p<0.001) and overall handling (p<0.001). Trainees tested the usefulness of the new ESD simulator. The complete resection rate improved after 3 ESD training sessions (9 procedures), and the perforation rate decreased after 4 sessions (12 procedures). Conclusions: We have developed a new ESD simulator that can help beginners achieve a high level of technical experience before performing real-time ESD procedures in patients.

Assessment of Hydraulic Properties of Bentonite Swelling Agents by Blending with Additives (첨가제 혼합에 의한 벤토나이트 팽윤재의 수리학적 특성평가)

  • Jeon, Han-Yong;Park, Yeoung-Mog;Mok, Mun-Sung
    • Journal of the Korean Geosynthetics Society
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    • v.1 no.1
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    • pp.43-51
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    • 2002
  • In this study, free swell index of betonite was examined in several regeants; distilled water, leachate, seawater and 3% NaCl solution. Free swell index values of bontonite to be added Poly(acrlylic acid), PYA(Polyvinyl Alcohol) or SCMC (Sodium Carboxymethyl Cellulose) were evaluated and compared. From this, it was confirmed that hydraulic conductivities of GCL in seawater were examined and the hydraulic conductivities of GCL in seawater were compared to those in distilled water. The average values of free swell indices of bentonite were decreased in order of distilled water>leachate>seawater. It was shown that no significant differences were occurred for free swell index between seawater and 3% NaCl solution. For bentonite to be added PVA, the other reagents except distilled water didn't affect increase of swelling. Swelling properties of bentonite to be added SCMC were improved except 3% NaCl solution.

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The Drawability of Iodinated at Solution Before Casting Polyvinyl Alcohol Films and Structure and Properties of Maximum-Drawn Films After Deiodination (성형 전 용액상태에서 요드화된 폴리비닐알코올 섬유의 연신 및 요드제거)

  • 신은주;이양헌;박찬헌;최석철
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.348-349
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    • 2003
  • PVA는 열가소성 고분자임에도 불구하고 융점(230~25$0^{\circ}C$)에 이어 바로 측쇄의 분해(270 $^{\circ}C$)가 시작되므로 공정상 많은 어려움을 가지고 있다. 그러나 요드와 같은 극성의 가소제를 사용하면 결정영역 까지도 가소화 시킬 수 있는 이점이 있어 PVA 유연성, 가공성 둥의 성질을 개선시킬 수 있다. [1-3] 특히 본 연구에서 성형 전 요드화된 폴리비닐알코올 필름을 제작하여 구조를 살펴본 결과, 결정성이 많이 감소하다가 요드흡착량이 150%의 경우에서는 무정형상태까지 나타났다. (중략)

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Studies on semiconducting metal-oxide(ZnO) Nanoweb from Electrospinning (전기방사를 이용한 반도체 산화물(ZnO) 나노웹 제조에 관한 연구)

  • Jo, Na-Gyeong;Kim, Han-Seong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.253-253
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    • 2009
  • Electrospinning is one of the simple, cost- efficient methods to produce long continuous semiconducting oxide nanofibers. Polyvinyl Alcohol (PVA) and zinc acetate were used. PVA/Zinc acetate aqueous solutions were electrospun into nonwoven webs. CCD camera, with a lens of long working distance and digital video board were used in capturing the drop and web deposition. The diameter and morphology of nanofibers were analyzed with a Field-emission scanning electron microscopy (FE-SEM). In this study, the average diameter and morphology of nanofibers have been explorered.

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