• Title/Summary/Keyword: polyurethane film

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Coating properties of PPG-based Polyurethane Dispersion wound covering resin by Addition of PVA (PVA의 첨가에 의한 PPG기반 수분산 창상피복수지의 코팅 물성)

  • Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.1
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    • pp.178-185
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    • 2021
  • In this study, polyvinyl alcohol (PVA) and polypropylene glycol (PPG)-based polyurethane dispersion resin for wound coating was synthesized. And the physical properties of the sample were coated on the surface of the film sample and the leather (Full-Grain) to study the physical properties change. In the case of tensile strength, PUD-PA1, which reacted with the least amount of PVA, showed the highest resistance at 2.00 kgf/㎟. Likewise, the rate of elongation was measured as high as 554% for PUD-PA1, which reacted with the least amount of PVA. The abrasion resistance measurement result showed that as the PVA response increased, the strength of the surface decreased to 36.77 mg.loss.

Study of Adhesion according to Various Surface Treatments for Lithium Ion Secondary Battery Pouch Film (다양한 표면처리에 따른 리튬이온 이차전지용 파우치 필름을 위한 접착성에 관한 연구)

  • Kim, Do Hyun;Bae, Sung Woo;Cho, Jung Min;Yoo, Min Sook;Kim, Dong Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.33 no.3
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    • pp.231-234
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    • 2016
  • Pouch film is manufactured by laminating aluminum foil, polyamide film and polypropylene film with an adhesive or extrusion resin. However, a surface treatment is required for the aluminum because bonding does not occur easily between the aluminum foil and the polymer film. Thus, for this study, surface treatment experiments were performed in order to confirm the effect on adhesion strength. First, a variety of surface treatment solutions were coated on aluminum foil, and contact angle and surface morphology analysis was carried out for the surface-treated aluminum. For lamination of the surface-treated aluminum foil with polyamide film, a polyurethane base adhesive was prepared for the adhesive strength test specimens. The adhesive strength between the aluminum foil and the polyamide film of the resulting specimens was measured (UTM). With such an experiment, it was possible to evaluate the effect on adhesive strength of the various surface treatments.

Optical Waveguiding in the Polymerized Organic Films (유기물 박막에서의 광도파 현상)

  • 박홍준;권영세
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.19 no.5
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    • pp.5-11
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    • 1982
  • The dielectric slab waveguide is fabricated on the slide glass or oxidized silicon wafer, by spin coating polyurethane, epoxy or photoresist, and the phenomenon of dielectric waveguiding is oboerved. Using the fact that the refractive index of K.P.R. is larger than that of polyurethane, thin film prism with two layered structure is fabricated, and the refraction of light is observed.

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Preparation of Thin Nickel Foam for Nickel-Metal Hydride Battery (Ni-MH 전지용 thin nickel foam의 제조)

  • 신준호;김기원
    • Journal of the Korean institute of surface engineering
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    • v.28 no.2
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    • pp.83-91
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    • 1995
  • A new method for preparation of thin nickel foam for Ni-MH battery was investigated. In this method, fine graphite powders of $1\mu\textrm{m}$$2\mu\textrm{m}$ diameter were pasted into pores of thin polyurethane foam film in order to supply electric conducting seeds for nickel deposition by electroless plating reaction. After electroless plating, remaining polyurethane foam was removed chemically by organic solvent treatment and graphite particles also removed by ultrasonic cleaning. Porosity of formed nickel foam was about 85% During electroplating, porosity of the nickel foam decreased less than 5% up to $30\mu\textrm{m}$ coating thickness. And then it was electroplated and heat-treated to improve mechanical strength and ductility. Finally, thin nickel foam for Ni electrode of Ni-MH battery with 80% porosity and $350\mu\textrm{m}$~X$400\mu\textrm{m}$ thickness was obtained.

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Preparation and Properties of Waterborne Polyurethanes and Their Blend Films (수분산 폴리우레탄과 그의 블렌드물의 제조 및 물성)

  • Yoo, Byung-Ha;Kim, Eun-Young;Kim, Han-Do
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.38-41
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    • 2003
  • Recently, Waterhorne polyurethane(WBPU) have been used for a wide range of commercial applications due to the increasing environmental regulation to reduce low-volatile organic compounds in coating and adhesives materials [1-8]. The WBPU was used in coating industry on fiber at first, and its market is increasing these days. Especially, the Waterborne polyurethane film even is widely used in the field of breathable coating fiber or medical science [9-10]. Water vapor permeability(WVP) is the key property for application to breathable coating fiber. (omitted)

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Liquid Crystal Alignment on the Films of Polymethacrylate and Polyurethane Bearing an Aminotroazobenzene Chromophore

  • Park, Dong-Hoon;Kim, Jae-Hyung;Cho, Kang-Jin
    • Macromolecular Research
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    • v.8 no.4
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    • pp.172-178
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    • 2000
  • We synthesized polymethacrylate and polyurethane bearing a photosensitive azobenzene chromophore. Photo-induced birefringence of the thin film was observed under a linearly polarized light(λ = 532 nm). Dynamic behaviors of birefringence in two polymers were investigated in terms of the rate constants of growth and decay. An induced dichroism was observed from polarized UV-VIS absorption spectroscopy. Layers of two photosensitive polymers were used for aligning liquid crystal (LC) molecules instead of one of the rubbed polyimide layers in the conventional twisted nematic cell. For producing homogeneous alignment of a nematic LC molecule, a linearly polarized light was exposed to the films of two polymers. The stability of the LC alignment upon the linearly polarized light exposure was also studied.

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A study on properties and synthesis of polyurethane compound formed hard segments by polyether polyol for lamb skin coat (Lamb skin 코팅용 polyether polyol을 이용한 hard segment를 형성하는 polyurethane compound의 합성 및 물성에 관한 연구)

  • Lee, Joo-Youb;Nam, Sang-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.2
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    • pp.296-304
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    • 2014
  • For this research, prepared polyurethane dispersion of hard segment type and polyethylene emulsion wax. Use these resin, this article has been analyzed about mechanical properties variation by increasing amount of polyethylene emulsion wax on Lam skin leather and dried film. According to measure data for solvent resistance, PUD had good property. As known in the results, increase of polyethylene wax constant did not influence to big variation of hybrid resin properties. As test of tensile strength, PUD had good tensile characteristic($1.235kg_f/mm^2$) and PUD-EW4 had lowest tensile characteristic($1.022kg_f/mm^2$). As same as tensile characteristic, abrasion test determined PUD(52.225 mg.loss) had highest properties. In elongation case, PUD showed 698 % modulus which was best properties in this experiment.

Preparation and Curing Behavior of Polyurethane Coatings by Polyester/Lactone Polyol and HDI-biuret (폴리에스테르/락톤 폴리올과 HDI-Biuret에 의한 폴리우레탄 도료의 제조 및 경화거동)

  • 최용호;김대원;황규현;박홍수;김태옥
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.72-81
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    • 2000
  • Benzoic acid polyester/lactone polyol were synthesized by polycaprolactone 0201 as diol, trimethylolpropane as triol, adipic acid as dibasic acid, and benzoic acid as monobasic acid. Polyisocyanate prepolymer Desmodur N-100 of HDI-biuret type was used in this study. Two-component polyurethane coatings were prepared by blending benzoic acid polyester/polycaprolactone, polyisocyanate, wetting/dispersing agent, white pigment, and flowing agent. Various properties were examined on the film coated with the prepared polyurethane. They showed excellent physical properties such as abrasion resistance, accelerated weathering resistance, and yellowness index. They also showed good physical properties such as flexibility, impact resistance, 60$^{\circ}$ specular gloss, cross hatch adhesion, hydrocarbon resistance, and lightness index difference. Hardness of coating showed a little poor character. The introduction of polycaprolactone 0201 as diol in the polyurethane coatings improved the hydrocarbon resistance, impact resistance, and flexibility of coatings. According to the drying and curing behavior with the contents of benzoic acid, they seem to have reasonable coating properties such as drying time of 2 to 4 hours and pot-life time of 20 to 37 hours.

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Analysis of Properties of Water-Dispersed Bio-Polyurethane Based on Caster Oil for Lamb Leather Surface (Lamb Leather용 Caster Oil 기반 수분산 바이오 폴리우레탄필름의 제조)

  • Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.39 no.2
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    • pp.161-168
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    • 2022
  • Unmodified castor oil (CO) was used to obtain a castor-based aqueous polyurethane (CPUD) and isophorone diisocyanate (IPDI) was used to obtain a transparent film. The mixing effect of polypropyleneglycole (PPG) was analyzed to increase flexibility. In addition, ethylenediamine (EDA) was used as a chain extender. Tensile strength, elongation, and abrasion resistance were measured according to the change according to the castor oil content and the change in the chain extender, respectively. The tensile strength of the sample containing a lot of castor oil was 1.112 kgf/㎟, and the elongation was 88%. The tensile strength of the sample containing a lot of chain extender was 3.33kgf/㎟, and the elongation was 99%. The surface strength was visually confirmed through SEM. The surface strength was visually confirmed through SEM.

Study on the High-Strength Air-Cushion Fabrics for Impact-Relief Application Prepared through Primer Coating and Thermal Film Laminating (프라이머 코팅과 열융착 필름 라미네이팅을 통해 제조한 충격 완화용 고강력 에어쿠션 직물에 관한 연구)

  • Kim, Ji Yeon;Kim, Hun Min;Min, Mun Hong
    • Textile Coloration and Finishing
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    • v.33 no.4
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    • pp.269-279
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    • 2021
  • In this study, the laminating of TPU film after coating of primer adhesive on the fabrics was applied in order to secure the strength to withstand a fall from a higher altitude by increasing the adhesion between the fabric and the film layer. It seems that the fineness of the yarn and the weave construction have a greater effect than the type of the laminating films. The order of superiority of the laminated fabrics by film type and thickness was the same for 1000 denier and 210 denier fabrics, and the tendency was consistent with the order of superiority in the film properties and peel strength tests. The tear strength of laminating fabrics increased three to four times for 1000 denier fabrics compared to the fabric alone, but it decreased by 2 times for the 210 denier fabrics. Summarizing the above results, it is most appropriate to combine 1000d fabric with three types of laminating films(100~200㎛ thickness) of A(0.2T) or B(0.15T) or D(0.1T) considering the air pressure resistance, the impact resistance during the fall, and the durability against damage during use.