• 대한건축학회논문집:구조계
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• 제35권1호
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• pp.21-28
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• 2019

This study investigates the applicability of composite polyurea to contain fiber reinforcement like fiber glass, steel fiber and carbon nanotube. Polyurea as elastomer is an excellent water-proofing material with many mechanical characteristics such as high tensile strength, ductility, high rate of expansion and contraction, and so on. The reinforcing fibers can be utilized for improving the load-carrying capacity of concrete structures. The polyurea plays a role to improve the ductility and toughness. Composite polyurea takes the mechanical advantages of the fibers and the polyurea. The test variables include the type of reinforcing fiber, its spraying thickness, and its weight ratio contained in the composite polyurea. It is observed that the load-carrying capacity, and the ductility and toughness are improved with the increase in the spraying thickness and the weight ratio contained in the composite polyurea. It is expected that the composite polyurea can be widely utilized in enhancing the structural and seismic performance.

• 콘크리트학회논문집
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• 제23권4호
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• pp.511-520
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• 2011

최근 국내에서는 고분자 화합물인 폴리우레아를 이용하여 보강 성능의 향상을 위한 연질형 폴리우레아를 개발하여 구조물에 적용하였지만 보강 성능은 미비한 것으로 나타났다. 따라서, 이 연구에서는 폴리우레아를 구조물의 보강재로 사용하기 위하여 연질형 폴리우레아의 구성 요소를 변화시켜 경질형 폴리우레아를 개발하였다. 개발된 경질형 폴리우레아는 연질형 폴리우레아에 비해 경도와 인장강도가 향상된 성능을 나타내었다. 경질형 폴리우레아를 일반 구조물의 보강재로 사용하기 위하여 RC 슬래브 시험체를 제작하여 보강 성능을 평가하였으며, 현재 보강재로 사용되는 섬유 시트와 적층하여 보강한 후 성능을 평가하였다. 실험 결과 경질형 폴리우레아만으로 보강한 시험체가 무보강 시험체보다 우수한 강성 증진 효과와 연성 증진 효과를 나타내는 것으로 나타났다. 또한, 섬유 시트를 부착한 후 경질형 폴리우레아를 외부에 도포하여 보강한 시험체는 섬유 시트만으로 보강한 시험체보다 보강 성능이 매우 우수한 것으로 나타났다. 그러나 경질형 폴리우레아를 도포한 후 섬유 시트를 부착한 시험체는 경질형 폴리우레아의 변형을 강성이 높은 섬유 시트가 억제하여 하중이 가해지며 생기는 응력이 한곳에 집중되어 취성적인 파괴 거동을 보이는 것으로 나타났다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2012년도 춘계 학술논문 발표대회
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• pp.41-42
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• 2012

High temperature / high pressure spray equipment using a conventional method, unlike spray polyurea adjustable pot life and yellowing caused by UV light and chemicals do not occur, or discoloration of Self-Leveling Type of rugged hand-polyurea resin for technology development is underway. This new concept of polyurea resin roller, brush, airless spray, and they installed easily using the unfamiliar labor, and curing time of approximately four hours to gain control of the glass because it is Pot. Construction, but does not like the spray polyurea resin, compared to the existing degradation of the adhesion strength is concerned. In this study, Self-Leveling Type Manual of polyurea resin adhesion strength of target deterioration Let's minimize problems by reviewing existing domestic and infrastructure long-term durability for long life of the facility is to obtain.

• 접착 및 계면
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• 제22권4호
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• pp.136-143
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• 2021

폴리우레아 소재는 폴리우레탄 화학결합과 높은 유사성을 가지고 있으면서, 높은 기계적 강성 및 탄성을 가지고 있어 경량 복합재의 고분자 기지 상으로 연구되어 왔다. 본 연구에서는 이방성을 가진 CNT (carbon nanotube)와 GO (graphene oxide)를 폴리우레아 기지 상에 첨가하여 제작한 복합재를 제작하였고 그 특성을 분석하였다. 원자힘현미경 이용해 CNT와 GO의 각각 1차원의 선형 및 2차원의 층상의 이방성을 확인한 후, 5 wt%으로 각각 폴리우레아 Resin에 혼합 후 cross-link 형성 및 건조 과정을 거쳐 복합재를 제작하였다. FTIR과 Raman 분광법을 이용해 제조한 CNT/폴리우레아와 GO/폴리우레아 복합재의 화학적 구조를 분석하였다. 그 결과, 폴리우레아와 첨가물의 화학결합 변화없이 혼합된 것이 확인되었다. 전자현미경을 이용해 첨가제/폴리우레아/유리섬유 직물 복합재의 표면과 단면에서의 CNT와 GO의 분포를 관찰하였다. 인장 강도 시험 결과, 1 wt%의 CNT와 GO가 첨가된 폴리우레아의 경우 인장강도 향상이 관측되었다.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2003년도 학술대회지
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• pp.149-151
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• 2003

This report describes the adhesibility of the polyurea greases. Generally, Polyurea greases were divided into three classes, aliphatic, alicyclic, and aromatic, according to the differences of the terminal alkyl group. The adhesion properties of polyurea greases were tested with Adhesion Tester by In-house method.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.264.2-264.2
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• 2013

Molecular layer deposition (MLD) is sequential, self-limiting surface reaction to form conformal and ultrathin polymer film. This technique generally uses bifunctional precursors for stepwise sequential surface reaction and entirely organic polymer films. Also, in comparison with solution-based technique, because MLD is vapor-phase deposition based on ALD, it allows epitaxial growth of molecular layer on substrate and is especially good for surface reaction or coating of nanostructure such as nanopore, nanochannel, nanwire array and so on. In this study, polyurea film that consisted of phenylenediisocyanate and phenylenediamine was formed by MLD technique. In situ Fourier Transform Infrared (FTIR) measurement on high surface area SiO2 substrate was used to monitor the growth of polyurethane and polyurea film. Also, to investigate orientation of chemical bonding formed polymer film, plan-polarized grazing angle FTIR spectroscopy was used and it showed epitaxial growth and uniform orientation of chemical bones of polyurea films.

• 한국염색가공학회지
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• 제19권5호
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• pp.30-36
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• 2007

Cypermethrin-containing polyurea microcapsules were prepared by interfacial polymerization using aromatic 2,4-toluene diisocyanate(TDI) and Ethylene diamine(EDA) as wall forming materials. The effects of the protective colloids of polyvinylalcohol(PVA) and gelatin were investigated through experimentation. The mean size of the polyurea microcapsules was smaller and the surface morphology of the PVA was much smoother than gelatin. In addition the release behavior was much more controlled and better sustained. As the concentration of protective colloid increased, the wall membrane of the polyurea microcapsules became more stable, the thermal stability of the wall membrane increased, the mean particle size became smaller, and the particle distribution was more uniform. The release behavior of the core material changed according to the concentration. As the gelatin concentration was increased, a more controlled and sustained release behavior was observed. However, in the case of PVA, the increase of PVA concentration lead to a more rapid release rate.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2001년도 학술발표회 논문집(Proceedings of the Korean Textile Conference)
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• pp.35-38
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• 2001

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2003년도 학술.기술논문 발표회
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• pp.91-95
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• 2003

There is a problem to be solved for improvement of durability and safety supervision. When you do the waterproofing and anticorrosive work of main concrete from the design stage, the material and method of construction need to be correctly applied to appropriate circumstance conditions. Epoxy have mostly been used for concrete water tank structure. Lately, lots of subjects on adaption of polyurea resin waterproofing and anticorrosive are under discussion. Then, we attempt to approach by evaluating and comparing every capabilities with another waterproofs in this study. Performance evaluation items include the adherence performance, the imprint of seal performance, temperature dependence performance, promotion weatherizing ability, inner chemical performance, drinking water eruptive performance. Through the experiment analysis, we found that the polyurea resin waterproofing membrane is dominantly superior to other waterproofs. According to this study, we suggest the polyurea resin waterproofing membrane as a new waterproofing material for concrete structure.

• 한국건축시공학회지
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• 제2권1호
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• pp.131-138
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• 2002

There is a problem to be solved for improvement of durability and safety supervision. When you do the waterproofing work of main concrete from the design stage, the material and method of construction need to be correctly applied to appropriate circumstance conditions. Epoxy have mostly been used for concrete water tank structure. Lately, lots of subjects on adaption of polyurea resin waterproofing and anticorrosive are under discussion. Then, we attempt to approach by evaluating and comparing every capabilities with another waterproofs in this study. Performance evaluation items include the adherence performance, the imprint of seal performance, temperature dependence performance, promotion weatherizing ability, Inner chemical performance. drinking water eruptive performance. Through the experiment analysis, we found that the polyurea resin waterproofing membrane is dominantly superior to other waterproofs. According to this study, we suggest the polyurea resin waterproofing membrane as a new waterproofing material for concrete structure.