• Title/Summary/Keyword: polystyrene particle

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Effects of Wind Depending on Tracers in an Application of LSPIV (LSPIV 적용시 Tracers에 따른 바람의 영향)

  • Kim, Young-Sung;Yang, Jae-Rheen
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.836-840
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    • 2007
  • Large-Scale Particle Image Velocimetry (LSPIV)는 Particle Image Velocimetry (PIV)를 자연하천이나 실험실에서 넓은 영역($4m^2{\sim}45,000m^2$)에 적용할 수 있도록 확장시킨 것으로 지난 10여년 이상 세계적으로 널리 이에 대한 연구가 진행되고 있다. PIV는 seeding, illumination, recording 그리고 image processing으로 구성된다. LSPIV(Large Scale PIV)는 PIV의 기본원리를 근거로 하여 기존의 PIV에 비하여 실험실 내에서의 수리모형실험이나 일반 하천에서의 유속측정과 같은 큰 규모의 흐름해석을 할 수 있도록 seeding, illumination에 대한 조정이 필요하고, 촬영된 image에 대한 왜곡을 없애는 작업이 필요하다. LSPIV는 PIV의 네가지 단계를 포함하여 seeding, illumination, recording, image transformation, image processing 및 post-processing의 여섯 단계로 구성되어진다 (Li, 2002). LSPIV를 일반 하천에 적용시, 자연발생적인 tracers - 난류로 인한 표면 교란, 부유물, 수공구조물로 인해서 발생하는 자연 발생되는 거품 - 가 풍부해서 seeding이 불필요한 경우를 제외하고는 정확한 유속장의 해석을 위하여 인공적인 seeding을 필요로 한다. 일반적으로 Seeding 재료로 많이 이용되는 것은 wood mulch, Ecofoam, grain-straw 등이다. 하천에서 자연발생적 혹은 인위적 seeding을 하였을 때 이들 tracers의 물리적인 속성으로 바람에 쉽게 영향을 받고 이로 인하여 실제의 물표면유속을 대표하지 못하는 경우가 있다. 이에 실험실의 개수로에서 여러 가지 이용 가능한 tracers에 대하여 바람에 의한 오차 발생의 정도를 조사하였다. 실험에 사용된 seeding 재료로는 black polypropylene, Ecofoam, white polystyrene의 세가지를 이용하였다. black polypropylene (SG=0.92)과 white polystyrene (SG=0.0125)은 폭 1 m 이내의 개수로 실험 장치에서 유속장의 해석에 많이 이용되고 Ecofoam (SG=0.0065)은 수리 모형실험에서 많이 이용된다. seeding 물질에 따른 바람의 영향을 분석하기 위해서 폭 60cm의 개수로에서 seeding 물질을 변경하면서 펌프의 조작에 의해 3가지 단면평균유속을 발생시키고, 각 평균유속조건에 대해 4가지의 바람세기 - 바람이 없을 때와 팬의 바람세기를 1단, 2단, 3단으로 조정 - 를 발생시켰으며, 개수로위에서 촬영한 이미지의 상류측기준점으로부터 0.3556m 하류 지점을 횡단하는 단면의 표면유속을 측정하여 비교하였고, 그 단면의 중앙에서 물표면 바로 위 지점의 풍속을 측정하였다. 각 Seeding 물질에 대해 팬을 켜지 않았을 때, 즉 바람의 영향이 없을 때 측정한 표면유속을 바람의 세기가 변한 경우의 기준 표면유속으로 이용하였다. 본 연구의 결과 비중이 0.01 내외인 Ecofoam과 white polystyrene에 비해 비중이 0.92인 black polypropylene은 대부분이 물속에 잠겨 있어 흐름과 거의 일치하여 움직임을 알 수 있었다. 또한 흐름의 평균유속이 0.165 m/s의 저유속에서 바람이 tracers에 미치는 영향이 평균유속 0.558m/s인 경우보다 커서, 바람의 세기의 증가에 따라 표면유속 측정값이 급속히 감소되었다. 흐름의 평균유속이 큰 경우에는 바람이 tracer에 마치는 영향이 현격히 줄어듬을 보이고 있다. 결론적으로 유속이 증가함에 따라 바람의 영향은 감소하나, 바람의 영향을 최소화시키기 위해서는 가급적 비중이 큰 물질(0.5

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Detection of Colloidal Nanoparticles in KURT Groundwater by a Mobile Laser-Induced Breakdown Detection System (이동식 레이저 유도 파열 검출 장치를 이용한 KURT 지하수 내 콜로이드 나노 입자 검출)

  • Jung, Euo-Chang;Cho, Hye-Ryun;Park, Mi-Ri;Baik, Min-Hoon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.9 no.1
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    • pp.41-48
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    • 2011
  • A mobile laser-induced breakdown detection (LIBD) system was developed for the field measurement of the size and concentration of aquatic colloidal nanoparticles sampled from Korea Atomic Energy Research Institute Underground Research Tunnel (KURT). The established LIBD apparatus is based on the optical detection of a laser-induced plasma by means of a two-dimensional optical imaging method for determining the size of nanoparticle. Calibration curve for determining the size of nanoparticle was obtained from the polystyrene reference particles of a well-defined size. The first direct application was made at KURT for investigating the particle sizes in groundwater. By comparing the size of particles in groundwater with the sizes of reference particles, the mean particle size of approximately $108{\pm}26$ nm with the concentration lower than 50 ppb was determined.

Preparation of Void Latex Particles: Effects of Reaction Parameters on the Mean Particle Diameter and the Solid Content (중공 입자의 제조: 반응 인자가 평균 입자 크기와 고형분 함량에 미치는 영향)

  • Lee, Kee Jeung;Seo, Kyung Won;Mok, Young Il
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.758-762
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    • 1998
  • In preparing void latex particles by emulsion polymerization, the weight mean particle size of which is ranged $0.3{\mu}m{\sim}1.5{\mu}m$, reaction parameters were investigated in order to elucidate their effects on the size distribution and the solid content of emulsion polymer. Experimental results showed that the weight mean particle size of hydrophillic core polymer was reduced as the concentration of sodium dodecylbenzene sulfonate (SDS) increased. The size of void polymethyl-methacrylate-polystyrene composite latex particles became larger as the concentration of styrene monomer and the sodium persulfate increased. However, the size of void latex particles was reduced as the feeding rate of acrylic acid increased. The solid content of emulsion polymer was strongly dependent on the addition of stylene monomer. By increasing the concentration of styrene monomer the solid content of emulsion polymer increased linearly.

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Dielectric Properties of Ceramic/Polymer Composites at Microwave Frequencies

  • Kim, Eung-Su;Jeon, Chang-Jun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.19.1-19.1
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    • 2011
  • Effects of particle size, crystal structures and multilayer structures of $ATiO_3$, $ATa_2O_6$, $ANb_2O_6$, $AWO_4$, and $AMoO_4$ (A=Ni, Mg, Zn, Co) ceramic fillers on the dielectric properties of polystyrene (PS), polypropylene (PP) and polytetrafluoroethylene (PTFE) polymer matrices were investigated at microwave frequencies. The microwave dielectric properties of $ATiO_3$ (ilmenite), $ATa_2O_6$ (tri-rutile), $ANb_2O_6$ (columbite), AWO4 (wolframite), and AMoO4 (wolframite) ceramics were largely dependent on the structural characteristics of oxygen octahedra. The dielectric constant (K) of the composites was increased with the ceramic content. However, the dielectric loss (tan ${\delta}$) of the composites was affected by the type of ceramics and the crystallinity of polymers. For the composites with same amount of ceramics, the K was decreased and the tan ${\delta}$ was increased with the particle size of ceramics. Also, the dielectric properties of the composites were dependent on the multilayer structures with different arrangements. Several theoretical models have been employed to predict the effective dielectric properties of the composites. The frequency dependence of dielectric properties and the temperature coefficient of resonant frequency (TCF) of the composites were also discussed.

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Surface-modified Cellulose Nanofibril Surfactants for Stabilizing Oil-in-Water Emulsions and Producing Polymeric Particles (표면 개질된 나노피브릴화 셀룰로오스를 이용한 에멀젼 안정화 및 고분자 입자 제조)

  • Kim, Bo-Young;Moon, Jiyeon;Yoo, Myong Jae;Kim, Seonmin;Kim, Jeongah;Yang, Hyunseung
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.110-116
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    • 2021
  • In this work, the surface of hydrophilic cellulose nanofibrils (CNFs) was modified precisely by varying amounts of cetyltrimethylammonium bromide (CTAB) to produce CNF-based particle surfactants. We found that a critical CTAB density was required to generate amphiphilic CTAB-grafted CNF (CNF-CTAB). Compared to pristine CNF, CNF-CTAB was highly efficient at stabilizing oil-in-water Pickering emulsions. To evaluate their effectiveness as particle surfactants, the surface coverage of oil-in-water emulsion droplets was determined by changing the CNF-CTAB concentration in the aqueous phase. Furthermore, styrene-in-water stabilized by CNF-CTAB surfactants was thermally polymerized to produce CNF-stabilized polystyrene (PS) particles, offering a great potential for various applications including pharmaceuticals, cosmetics, and petrochemicals.

Effect of Particle Size and Velocity Ratio on the Flow Mixing Characteristics in the Secondary Combustor (덕티드 로켓의 이차 연소기 내에서 입자의 크기와 속도비가 유동 혼합에 미치는 영향)

  • Park, Jung Shin;Park, Soon Sang;Han, Doo-Hee;Shin, Jun-Su;Sung, Hong-Gye;Kwak, Jae Su;Choi, Ho-Jin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.18 no.1
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    • pp.1-7
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    • 2014
  • In this study, the effect of velocity ratio and particle size on the flow mixing characteristics in the secondary combustor was investigated. Both PIV(Particle Image Velocimetry) technique and LES(Large Eddy Simulation) were applied. Two sizes of Polystyrene PIV seeding particle of 5 and $50{\mu}m$, and three velocity ratios of 5, 3, and 1.5 were considered. Results showed that the mixing of two air streams created reattachment and recirculation regions. The size of the recirculation region was decreased as the velocity ratio increased. For the larger particle cases, due to the increased momentum by the larger particles, the size of the recirculating regions were larger than that of the smaller particle cases and the effect of the velocity ratio was not as significant as in the smaller particle case.

Preparation of Polystyrene Beads by Suspension Polymerization with Hydrophobic Silica as a Stabilizer in Aqueous Solution (소수성 실리카를 안정제로 이용하는 수용액 상에서의 현탁중합법에 의한 폴리스티렌 입자 합성)

  • Park, Moon-Soo
    • Polymer(Korea)
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    • v.30 no.6
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    • pp.498-504
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    • 2006
  • A suspension polymerization of styrene In aqueous phase was employed to study if polystyrene particles ranging from 1 to $20{\mu}m$ can be produced. Hydrophobic silica was selected as a stabilizer and azo-bisisobutyronitrile (AIBN) as an initiator. Polymerization reaction was carried out at a selected temperature in the range of $65{\sim}95^{\circ}C$. Stabilizer concentration was varied from 0.17 to 3.33 wt% compared to the water while the concentration of the initiator was raised from 0.13 to 6.0 wt% compared to the monomer. Dispersion of hydrophobic silica into the water phase was achieved by precise control of pH. Optimum dispersion of silica was obtained at pH 10. Average particle diameter decreased with increasing amounts of stabilizer concentration initially, exhibiting the minimum average diameter at 1.67 wt% of stabilizer concentration, after which it started to Increase. It is speculated that an excessive presence of stabilizer encouraged a secondary reaction in the reaction medium, which led to particle agglomeration, and as a result an increase in average particle diameter. Molecular weight was found to be independent of stabilizer concentration between 0.13 and 1.00 wt% whereas, it increased when stabilizer concentration exceeded 1.67 wt%. Variation of molecular weight was probably caused by the reduced activity and efficiency of initiator due to the high concentration of silica, and the secondary reaction in the reaction medium, as well. An increase in the Initiator concentration and/or reaction temperature resulted in an increase in both reaction rate and particle diameter. Consequently, we have confirmed that spherical polystyrene particles with $1{\sim}20{\mu}m$ in diameter can be prepared by careful selection of the concentration of stabilizer, initiator, pH and reaction temperature.

Property of ion Exchange Resin having Tripropylamine as Functional Group for Development of Denitrogenation Process

  • Lee, Dong-Hwan;Lee, Yong-Hee;Lee, Kook-Eui;Roh, Jong-Su;Suh, Myung-Gyo
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2005.06a
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    • pp.355-358
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    • 2005
  • Nitrate-selective ion exchange resins involving bulky trialkyl amino as functional group were synthesized by the reaction of chloromethylated polystyrene-divinylbenzene copolymer and the corresponding tripropylamine in ethanol. Fundmental properties such as bulk density, water content, effeative diameter, uniformity coefficient, appearance index, exchange capacity and particle size distribution were fully measured. The synthesized resins appeared to be good for nitrate selection.

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Fabrication and Optical Characterization of Colloidal 3-D Photonic Crystals

  • N. Y. Ha;Y. Woo;Park, Byungchoo;J. W. Wu
    • Journal of the Korean Vacuum Society
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    • v.12 no.S1
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    • pp.15-16
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    • 2003
  • 3-D photonic band-gap structures are fabricated from dielectric colloidal polystyrene beads through a centrifuge method. The fabricated photonic crystals exhibit opalescent colors under white light and show a clear diffraction peak dependent on the incident angle of the light beam. Also the scanning electron microscope image was taken to verify the face-centered cubic crystal structure. Bragg's law and Snell's law are employed to describe the position of angle resolved diffraction peaks. It was shown that the optically deduced effective refractive index and lattice constants were in good agreement with the crystal structure identified by scanning electron microscope.

Opto-electrokinetic Technique for Microfluidic Manipulation of Microorganism (광-전기역학 기술을 이용한 미생물의 미세유체역학적 제어)

  • Kwon, Jae-Sung
    • Journal of the Korean Society of Visualization
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    • v.17 no.1
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    • pp.69-77
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    • 2019
  • This paper introduces microfluidic manipulation of microorganism by opto-electrokinetic technique, named rapid electrokinetic patterning (REP). REP is a hybrid method that utilizes the simultaneous application of a uniform electric field and a focused laser to manipulate various kinds and types of colloidal particles. Using the technique in preliminary experiments, we have successfully aggregated, translated, and trapped not only spherical polystyrene, latex, and magnetic particles but also ellipsoidal glass particles. Extending the manipulation target to cells, we attempted to manipulate saccharomyces cerevisiae (S. cerevisiae), the most commonly used microorganism for food fermentation and biomass production. As a result, S. cerevisiae were assembled and dynamically trapped by REP at arbitrary location on an electrode surface. It firmly establishes the usefulness of REP technique for development of a high-performance on-chip bioassay system.