• Bulletin of the Korean Chemical Society
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• 제35권9호
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• pp.2694-2698
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• 2014

A multisegmented polystyrene (PS) with pH-cleavable ester and carbamate linkages was successfully synthesized by a combination of atom transfer radical polymerization (ATRP) and Cu(I)-catalyzed 1,3-dipolar cycloaddition of azide and alkynes (click chemistry). ATRP was employed to synthesize polystyrene from hydroxyl-terminated initiator using CuBr/N,N,N',N",N"-pentamethyldiethylenetriamine (PMDETA) as the catalyst. The reaction of the resulting PS with sodium azide yielded the azido-terminated polymer. The hydroxyl group in the other end of the polymer was reacted with 4-nitrophenyl chloroformate (NPC), followed by reaction with propargylamine to produce an alkyne end group with a carbamate linkage. The PS with an alkyne group in one end and an azide group in the other end was then self-coupled in the presence of CuBr/2,2'-bipyridyl (bpy) in DMF to yield a desired multisegmented PS. Molecular weight and molecular weight distribution of the self-coupled polymer increased with time, as in the typical step-growth-type polymerization processes. Finally, we demonstrated that the ester and carbamate linkages of the multisegmented PS were hydrolyzed in the presence of HCl to yield individual PS chains.

• 공업화학
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• 제22권4호
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• pp.444-446
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• 2011

계면활성제(polyvinylpyrrolidone, PVP)와 개시제(benzoyl peroxide, BPO)를 95% 알코올을 용매 속에 첨가하여 styrene monomer로부터 나노 크기의 균일한 분포 영역을 갖는 polystyrene (PS)을 제조하였다. Emulsion polymerization방법을 사용하였으므로 중합과정에서 PS입도 크기에 많은 변수가 영향을 미칠 수 있다. 본 연구에서는 단량체, 계면활성제 및 개시제 등의 농도 영향은 배제하고 가장 큰 변수들로 고려되는 교반 속도와 초음파 조사시간의 영향을 주로 연구하였다. 초음파 조사시간을 조절한 결과 400 nm의 나노 크기를 갖는 PS 입자를 제조할 수 있었다.

• Korea-Australia Rheology Journal
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• 제21권3호
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• pp.185-191
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• 2009

Polystyrene/multi-walled carbon nanotube (PS/MWCNT) composites were prepared by the use of latex technology. The monodisperse PS latex was synthesized by an emulsifier-free emulsion polymerization from styrene/potassium persulfate/water system in the presence of ethanol. The MWCNTs were first treated with acid mixture to eliminate impurities, dispersed in deionized water driven by ultrasonicator, and then mixed with the PS latex. From these mixtures, PS/MWCNT composites were prepared by freeze-drying and subsequent compression molding. In the small-amplitude oscillatory shear experiments, both complex viscosity and storage modulus increased with increasing MWCNT content. A pronounced effect of MWCNT content was observed, resulting in larger storage modulus and stronger yield behavior at low frequencies when compared to unmodified PS. It showed a transition from viscous to elastic behavior with increasing MWCNT content. Over the MWCNT content of 3 wt%, the storage modulus was higher than the loss modulus across all frequencies.

• 공업화학
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• 제3권2호
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• pp.247-255
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• 1992

Macroazoinitiator를 이용하여 Polystyrene-poly(caprolactone) (PS-PCL) 블록공중합체를 합성하고, poly(2, 6-dimethyl-1, 4-phenylene oxide) (PPO)/poly(styrene-co-acrylonitrile) (SAN, acrylonitrile의 함량이 25wt%) 블렌드에서의 상용화 효과를 조사하였다. 공중합체 중 PS블록과 PCL블록은 각각 PPO, SAN과 상용성을 가졌으며, 블록공중합체는 SAN의 PPO 영역으로의 용해 정도를 증가시킴을 관찰할 수 있었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.221-221
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• 2013

Striving to replace the well known silicon nanocrystals embedded in oxides with solution-processable charge-trapping materials has been debated because of large scale and cost effective demands. Herein, a silicon quantum dot-polystyrene nanocomposite (SiQD-PS NC) was synthesized by postfunctionalization of hydrogen-terminated silicon quantum dots (H-SiQDs) with styrene using a thermally induced surface-initiated polymerization approach. The NC contains two miscible components: PS and SiQD@PS, which respectively are polystyrene and polystyrene chains-capped SiQDs. Spin-coated films of the nanocomposite on various substrate were thermally annealed at different temperatures and subsequently used to construct metal-insulator-semiconductor (MIS) devices and thin film field effect transistors (TFTs) having a structure p-$S^{++}$/$SiO_2$/NC/pentacene/Au source-drain. C-V curves obtained from the MIS devices exhibit a well-defined counterclockwise hysteresis with negative fat band shifts, which was stable over a wide range of curing temperature ($50{\sim}250^{\circ}C$. The positive charge trapping capability of the NC originates from the spherical potential well structure of the SiQD@PS component while the strong chemical bonding between SiQDs and polystyrene chains accounts for the thermal stability of the charge trapping property. The transfer curve of the transistor was controllably shifted to the negative direction by chaining applied gate voltage. Thereby, this newly synthesized and solution processable SiQD-PS nanocomposite is applicable as charge trapping materials for TFT based memory devices.

• 유변학
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• 제9권3호
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• pp.89-96
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• 1997

PS/PPO 블렌등의 동적 탄성율 E*($\omega$)와 동적 스트레인-광학계수 O*($\omega$)을 유리전이 영역에서 동시에 측정하여, PS/PPO 3종류조성블렌드의 E*($\omega$)와 O*($\omega$)완화거동을 조성 단 일 중합체와 비교고찰하였다. PS/PPO 블렌드의 $\alpha$-분산 점탄성 거동은 조성에 관계없이 거 의 유사하여 조성 고분자가 상호 협동적으로 완화하는 것을 알수 있었다. 그러나 광학적 완 화 스펙트럼 O*($\omega$)는 정성적으로 명확히 다른 거동을 보였다. 단일 PS와 PPO의 O*($\omega$)는 전 영역에 걸쳐 상반된 부로를 나타냈으며 두 고분자의 블렌드는 조성고분자의 반대부호를 상호보상으로 인하여 복굴절이 감소하였다. 3종류블렌드는 PPO의 조성이 증가함에 따라 상 호보상에 의해 O*($\omega$)의부호가 순차적으로 변하여 반전하였으며, 저 복굴절 PS/PPO 블렌드 의 PS조성이 65-80wt% 범위내에 있음을 추정할수 있었다. 상이한 부호를 갖는 복굴절 특 성으로 인하여 블렌드 내에서 각 성분 고분자의 완화 기여를 다순 가성법칙에 의해 정량적 으로 계산하는 것이 가능하였다. 또한 PS/PPO 블렌드의 상용성을 광학적 부분 기여 파라메 터를 사용하여 고찰하였다.

• 한국분말재료학회지
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• 제23권4호
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• pp.276-281
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• 2016

Carbonyl iron (CI) is successfully incorporated as an additive into a polystyrene (PS) matrix via a highenergy ball milling method, under an n-hexane medium with volume fractions between 1% and 5% for electromagnetic interference shielding applications by the combination of magnetic CI and an insulating PS matrix. The morphology and the dispersion of CI are investigated by field emission scanning electron microscopy, which indicates a uniform distribution of CI in the PS matrix after 2 h of milling. The thermal behavior results indicate no significant degradation of the PS when there is a slight increase in the onset temperature with the addition of CI powder, when compared to the as-received PS pellet. After milling, there are no interactions between the CI and the PS matrix, as confirmed by Fourier transformed infrared spectroscopy. In this study, the milled CI-PS powder is extruded to make filaments, and can have potential applications in the 3-D printing industry.

• 폴리머
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• 제27권6호
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• pp.603-608
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• 2003

신디오탁틱 폴리스티렌 (5-PS)는 시료의 처리 조건에 따라 여러 구조를 가지며 열처리에 따른 고체상의 구조 전이현상을 보여준다 서로 다른 s-PS 사슬 및 결정 구조를 가지는 시료들을 상온에서 220 $^{\circ}C$까지 온도를 올려가며 열처리하여 준비한 후 FTIR과 FT-Raman 분광계를 이용하여 구조의 변화를 조사하였다. 빠른 결정화 속도 때문에 DSC 실험으로 측정하기 힘든 x-PS 시료의 열처리 시간에 따른 결정화도 변화를 결정 부분과 비결정 부분 infrared특성피크 세기에 따라 측정한 후 Beer-Lambert 법칙에 적용하여 조사할 수 있었다.

• Macromolecular Research
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• 제15권4호
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• pp.285-290
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• 2007

Ag nanoparticles were distributed onto polystyrene nanoparticle (PS-Ag) beads using two synthetic methodologies. In the first methodology, polystyrene (PS) beads were prepared via emulsion polymerization, with Ag nanoparticles subsequently loaded onto the surface of the PS beads. The polymerization of styrene was radiolytically induced in an ethanol (EtOH)/water medium, generating PS beads. Subsequently, Ag nanoparticles were loaded onto the PS beads via the reduction of Ag ions. The results from the morphological studies, using field emission transmission electron microscopy (FE-TEM), reveal the PS particles were spherical and nanosized, and the average size of the PS spherical particles decreased with increasing volume % of water in the polymerization medium. The size of the PS spherical particles increases with increasing radiation dose for the polymerization. Also, the amount of Ag nanoparticle loading could be increased by increasing the irradiation dose for the reduction of the Ag ions. In the second methodology, the polymerization of styrene and reduction of Ag ions were simultaneously performed by irradiating a solution containing styrene and Ag ions in an EtOH/water medium. Interestingly, the Ag nanoparticles were preferentially homogeneously distributed within the PS particles (not on the surface of the PS particles). Thus, Ag nanoparticles were distributed onto the surface of the PS particles using the first approach, but into the PS clusters of the particles via the second. The antimicrobial efficiency of a cloth coated with the Ag-PS composite nanoparticles was tested against bacteria, such as Staphylococcus aureus and Klebsiella pneumoniase, for 100 water washing cycles.

• Transactions on Electrical and Electronic Materials
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• 제11권6호
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• pp.285-287
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• 2010

This paper introduces homogeneous liquid crystal (LC) orientations on chemically modulated polystyrene (PS) surfaces using various ion beam (IB) exposure times. Transparent PS was replaced with conventional polyimide material. As a non-contact process, the IB bombardment process induced LC orientation parallel to the IB process. Through x-ray photoelectron spectroscopy, it was shown that the chemical compositional changes of the IB-irradiated PS surfaces were determined as a function of IB exposure time. Using this analysis, the optimal IB bombardment condition was determined at an IB exposure time of up to 15 seconds. Moreover, thermal stability on IB-irradiated PS surfaces were carried out which showed that a relatively high IB exposure time induced a thermally stable LC alignment property.