• Title/Summary/Keyword: polymethylmethacrylate (PMMA)

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Evaluation of Smoke Risk and Smoke Risk Rating for Combustible Substances from Fire (화재로부터 연소성 물질에 대한 연기위험성 및 연기위험성 등급 평가)

  • Chung, Yeong-Jin;Jin, Eui;You, Ji Sun
    • Applied Chemistry for Engineering
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    • v.32 no.2
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    • pp.197-204
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    • 2021
  • This study investigated the smoke risk assessment of woods and plastics for construction materials, focusing on the smoke performance index-V (SPI-V), smoke growth index-V (SGI-V), and smoke risk index-VI (SRI-VI) according to a newly designed methodology. Spruce, Lauan, polymethylmethacrylate (PMMA), and polycarbonate (PC) were used for test pieces. Smoke characteristics of the materials were measured using a cone calorimeter (ISO 5660-1) equipment. The smoke performance index-V calculated after the combustion reaction was found to be 1.0 to 3.4 based on PMMA. Smoke risk by smoke performance index-V was increased in the order of PC, Spruce, Lauan and PMMA. Lauan and PMMA showed similar values. The smoke growth index-V was found to be 1.0 to 9.2 based on PMMA. Smoke risk by smoke growth index-V increased in the order of PMMA, PC, Spruce, and Lauan. COpeak production rates of all specimens were measured between 0.0021 to 0.0067 g/s. In conclusion, materials with a low smoke performance index-V and a high smoke growth index-V cause a high smoke risk from fire. Therefore, it is understood that the smoke risk from fire is high. It is collectively summarized by the smoke risk index-VI.

Biomechanical Evaluation of PMMA Injection in Vertebroplasty (척추성형술 시술에서 PMMA주입에 대한 흉추의 생체역학적 평가)

  • 이준형;채수원;이태수;서중근;박정율;김상돈;이관행
    • Journal of Biomedical Engineering Research
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    • v.25 no.1
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    • pp.27-32
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    • 2004
  • In this study, method of PMMA injection is suggested for vertebroplasty in patients with osteoporotic compression fracture. The finite element analysis is used to investigate the vertebroplasty quantitatively. In order to improve previous works with simplified geometry of vertebral body more exact geometry has been constructed from CT image data with 1m thickness. An ideal method of PMMA delivery, with respect to location and amount of injectate, into vertebral body has been suggested based on evaluation of the insert positions and the insert shapes of injected PMMA. It is shown that vertebral body can be compensated most efficiently when PVIMA is highly concentrated on the top-front of trabecular bone of compressed vertebra.

The Optimization of RF Atmospheric Pressure Plasma Treatment Process for Improving the Surface Free Energy of Polymethylmethacrylate (PMMA) (Polymethylmethacrylate (PMMA) 표면개질을 위한 RF 대기압 플라즈마 처리공정의 최적화)

  • Nam, Ki-Chun;Myung, Sung-Woon;Choi, Ho-Suk
    • Journal of Adhesion and Interface
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    • v.6 no.3
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    • pp.1-9
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    • 2005
  • This study investigated the influence of atmospheric plasma factors such as RF power, treatment time, the gap distance between discharge and sample, and the gas flow rate of Ar on the surface property by using the design of experiment (DOE) method. The plasma treatment time (s), plasma power (W), gap distance (mm) between discharge and sample, and flow rate of Ar gas were in order of important factors for changing the surface free energy of PMMA plates. As a result, the most effective factor for improving the surface free energy of PMMA plates is the distance (mm) from discharge glow to sample plate. Because of the interaction between plasma power (W) and treatment time (s), the power dose (J) factor which multiply plasma power (W) by treatment time (s) should be significantly considered. The optimum condition for maximizing the surface free energy of PMMA plate was found at 1500J of power dose. Through XPS and AFM analysis, we also observed the change of chemical composition, surface morphology and roughness before and after plasma treatment. It is considered that the change of surface free energy of PMMA plate with plasma treatment is influenced by the introduction of polar functional group as well as the increase of surface roughness.

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Micro/Nano Rheological Characteristics of PMMA in Hot Embossing Process (핫엠보싱 공정에서 PMMA의 마이크로/나노 레올로지 특성)

  • Kim B. H.;Kim K. S.;Ban J. H.;Shin J. K.;Kim H. Y.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.05a
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    • pp.259-264
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    • 2004
  • The hot embossing process as a method for the fabrication of polymer is becoming increasingly important because of its simple process, low cost, high replication fidelity and relatively high throughput. In this paper, we carried out experimental studies and numerical simulations in order to understand the viscous flow of polymer film during hot embossing process. As the initial step of quantitating the hot embossing process, simple parametric studies for the embossing conditions have been carried out using high resolution masters which patterned by DRIE process. Under different embossing times and pressures, the viscous flow of PMMA films into micro/nano cavities has been investigated. Also, the viscous flow during the hot embossing process has been simulated by the continuum based FDM analysis considering micro/nano effect, such as surface tension and contact angle.

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Preparation and Characterizations of Polymethylmethacrylate (PMMA)/Acrylate Rubber (ACM) Blend for Light Diffuser Applications

  • Lee, Byung Hwan;Chang, Young-Wook;Lim, Hyung Mi
    • Elastomers and Composites
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    • v.50 no.1
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    • pp.49-54
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    • 2015
  • Dynamically vulcanized PMMA/ACM (80 wt%/20 wt%) blend using DCP as a curing agent was prepared using internal mixer. The morphology, mechanical properties, optical properties, melt viscosity and die swell were characterized by using FE-SEM, tensile test, Izod impact test, dynamic mechanical analysis, ARES and capillary rheometer, respectively. The blends show a phase-separated morphology in which ACM are dispersed in PMMA matrix. Dynamically vulcanized blend exhibits higher mechanical properties, higher melt viscosity, and die swell as compared to simple blend. And, the dynamically vulcanized blend showed total transmittance of more than 75% and haze of higher than 90%, which enable it to find potential applications to fabricate an optical diffuser by extrusion process.

The Behavior of Shrinkage on PMMA in Injection Molding Compression Molding (사출압축성형시 PMMA 재료의 성형수축거동)

  • Choi, Y.S.;Han, S.R.;Jeong, Y.D.
    • Journal of Power System Engineering
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    • v.9 no.4
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    • pp.83-89
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    • 2005
  • Molding shrinkage is one of the problems to be solved in conventional injection molding. Despite many trying-out has been to solve it, intrinsic cause of shrinkage such as orientation and thermal exchange between melt and mold has not been solved yet. For reducing shrinkage and residual stress on molding, injection compression molding process was invented. In this study, experiments about effects of injection compression molding's parameters on shrinkage of PMMA molding were conducted and compared with conventional injection molding's shrinkage. Before the injection compression molding experiment, molding shrinkage rate was predicted by analyzing pvT diagram and was compared with the results of experiment. The shrinkage rate of injection compression molding was lower than convention injection molding's one which was different from the predicted shrinkage. The reason was observed that the experimental mold was not a proper type for injection compression, flowing backward of melt into nozzle and unreasonable mechanism of injection molding machine.

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Organic Compounds Vapor Detection Properties of MWCNT/PMMA Composite Film Detector (CNT/PMMA 복합막 검출기의 유기화합물 증기의 검출 특성)

  • Lim, Young Taek;Shin, Paik-Kyun;Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.11
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    • pp.727-730
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    • 2015
  • In this paper, we fabricated organic compounds detector using the MWCNT/PMMA (multi-walled carbon nanotube / polymethylmethacrylate) composite film. We used polymer film as a matrix material for the device framework, and introduced CNTs for reacting with the organic compounds resulting in changing electrical conductivity. Spray coating method was used to form the MWCNT/PMMA composite film detector, and pattern formation of the detector was done by shadow mask during the spray coating process. We investigated changes of electrical conductivity of the detector before and after the organic compounds exposure. Electrical conductivity of the detector tended to decrease after the exposure with various organic compounds such as acetone, tetrahydrofuran (THF), toluene, and dimethylformamide (DMF). Finally we conclude that organic compounds detection by the MWCNT/PMMA composite film detector was possible, and expect the feasibility of commercial MWCNT/PMMA composite film detector for various organic compounds.

Preparation of UV Cured Hard Coating Films Using Polysilazane on Plastic Substrates (플라스틱 기재 위에 polysilazane을 이용한 UV 경화형 하드코팅 도막 제조)

  • Yang, Jun Ho;Cho, Yong Ju;Song, Ki Chang
    • Korean Chemical Engineering Research
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    • v.56 no.2
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    • pp.162-168
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    • 2018
  • UV-curable hard coating solutions were prepared by mixing organic or inorganic polysilazane with urethane acrylate. UV-cured hard coating films were also obtained by flow coating, subsequently UV-curing on polymethylmethacrylate (PMMA) sheets. The effect of types and amounts of polysilazane was investigated on properties of obtained coating films. As a result, the coatings obtained by using organic polysilazane showed a high hydrophobic property with water contact angle of $95^{\circ}$, pencil hardness of 7H and high transparency of 92% in the visible wavelength range. On the other hand, the PMMA sheets made by using inorganic polysilazane exhibited a pencil hardness of as high as 8H, good adhesion to the substrate and water contact angle of $82^{\circ}$.

Application of Total Variation Algorithm in X-ray Phantom Image with Various Added Filter Thickness : GATE Simulation Study (다양한 두께의 부가 여과판을 적용한 X-선 영상에서의 Total Variation 알고리즘 적용 : GATE 시뮬레이션 연구)

  • Park, Taeil;Jang, Sujong;Lee, Youngjin
    • Journal of the Korean Society of Radiology
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    • v.13 no.5
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    • pp.773-778
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    • 2019
  • Images using X-rays are essential to diagnosis, but noise is inevitable in the image. To compensate for this, a total variation (TV) algorithm was presented to reduce the patient's exposure dose while increasing the quality of the images. The purpose of this study is to verify the effect on the image quality in radiographic imaging according to the thickness of the additional filtration plate through simulation, and to evaluate the usefulness of the TV algorithm. By using the Geant4 Application for Tomographic Emissions (GATE) simulation image, the actual size, shape and material of the Polymethylmethacrylate (PMMA) phantom were identical, the contrast to noise ratio (CNR) and coefficient of variation (COV) were compared. The results showed that the CNR value was the highest and the COV the lowest when applying the TV algorithm. In addition, we can acquire superior CNR and COV results with 0 mm Al in all algorithm cases.