• Title/Summary/Keyword: polymeric particles

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The Filtrational Characteristics of Magnetic Fibrous Polymeric Filter as an Oil Filter for Automotive (자동차용 자성폴리머 오일필터의 여과특성 연구)

  • 안병길;최웅수;권오관;문탁진
    • Transactions of the Korean Society of Automotive Engineers
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    • v.4 no.5
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    • pp.179-186
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    • 1996
  • The magnetic fibrous polymeric oil filter for automotive was obtained by pneumoextrusion processing prepared from thermoplastic polymer(polyamide) containing magnetic particulate filer (Ba ferrite), and treated subsequently in a magnetic fields. Using an oil filter tester and particle quantifier, the dependence of filtrational characteristics of the magnetic oil filter on the parameters of mean pore sizes and magnetic properties were analyzed. Also experimental engine-bed test of oil filters was investigated. The magnetic fibrous polymeric filter was shown to possess a highly filtration efficiency in filtering the fine metal particles with increasing the magnetic force of filter element. In this study, we knew that efficiency of magnetic fibrous polymeric filter was dependent on the magnetic strength of the filter elements.

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Filtration Characteristics of Magnetic Fibrous Polymeric Filter Elements for Industrial Lub-systems (산업용 자성폴리머 필터소재의 여과특성 연구)

  • 안병길;최웅수;이용훈;정용진;권오관
    • Tribology and Lubricants
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    • v.12 no.3
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    • pp.39-47
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    • 1996
  • The magnetic fibrous polymeric oil filter elements for industrial lub-systems were obtained by pneumoextrusion processing prepared from thermoplastic pqlymer (polyamide) containing a magnetic particulate filler (Ba ferrite), and treated subsequently in a magnetic fields. Using the standard laboratory oil filtration test rig, metallic particle quantifier and image analyser system, the dependence of filtration charateristics of the magnetic filter media on the parameters of porosity and magnetic properties was investigated. The pressure drops and efficiencies of lubricating filter elements were measured on the packing density and magnetised filler content of filter element. Also, the industrial lub-systems such as lubricant filters for gear test rig and electric discharge processing machine were used for testing the flitrational characteristics of tl, c magnetised filter elements. The magnetic fibrous polymeric filter material was shown to possess a highly filtration efficiency in filtering the fine ferrous particles with increasing the magnetic force of filter element. Therefore, it is expected that the magnetic fibrous polymeric filter material should be used for effective oil filrers on the industrial lub-systems.

Investigation on Flocculi-floc Interaction and Flocculation in Extracellular Polymeric Substances, Ionic Species and Clay-containing Suspension (생체고분자물질 농도와 이온강도에 따른 점토입자 현탁액의 응집핵-응집체 이군집 응집 특성 연구)

  • Kim, Jae In;Lee, Byung Joon
    • Journal of Korean Society on Water Environment
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    • v.36 no.3
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    • pp.185-193
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    • 2020
  • Bimodal flocculation describes the aggregation and breakage processes of the flocculi (or primary particles) and the flocs in the water environment. Bimodal flocculation causes bimodal size distribution with the two separate peaks of the flocculi and the flocs. Extracellular polymeric substances and ionic species common in the water environment increase the occurrence of bimodal flocculation and flocculi-floc size distribution, under the flocculation mechanisms of electrostatic attraction and polymeric bridging. This study investigated bimodal flocculation and flocculi-floc size distribution, with respect to the extracellular polymeric substance concentration and ionic strength in the kaolinite-containing suspension. The batch flocculation tests comprising 0.12 g/L of kaolinite showed that the highest flocculation potential occurred at the lowest xanthan gum (as extracellular polymeric substances) concentration, under all the ionic strengths of 0.001, 0.01, and 0.1 M NaCl. Also, it was important to note that the higher ionic strength resulted in the higher flocculation potential, at all the xanthan gum concentrations. The bimodal flocculation and flocculi-floc size distribution became apparent in the experimental conditions, which had low and intermediate flocculation potential. Besides the polymeric bridging flocculation, steric stabilization increased the flocculi mass fraction against the floc mass fraction, thereby developing the bimodal size distribution.

Preparation and Surface Properties of Polysulfone/Organophilic Layered Silicate Nanocomposites (폴리설폰/친유기화 층상실리케이트 나노복합체의 제조 및 표면 특성)

  • Sul, Kyung-Il;Ma, Seung Lac;Kim, Yong Seok;Lee, Jae Heung;Won, Jong Chan
    • Journal of Adhesion and Interface
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    • v.4 no.4
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    • pp.15-21
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    • 2003
  • Polysulfone/organophilic layered silicate nanocomposites were prepared in the range of 0.25 to 9 wt% of organophilic-layered silicate by solution blend. Nano-hybridized films were cast from the blend solution. Exfoliation and intercalation of the polysulfone/organophiliclayered silicate nanocomposite films were confirmed by an X-ray diffractometer and a transmission electron microscope. Surface morphologies of polysulfone/organophilic layered silicate nanocomposite films were determined by a scanning electronic microscope and an atomic force microscope. When the organophilic layered silicate was added more than 1.5 wt%, the surface roughness (RMS) was rapidly increased because clusters of intercalated organophilic layered silicate particles existed on the polysulfone/organophilic-layered silicate film surface. Surface tension revealed an upward tendency over the contents of 1.5 wt% organophilic layered silicate in polysulfone/organophilic layered silicate nanocomposite. The change of surface morphology in polysulfone/organophilic layered silicate nanocomposite were affected by nano scale dispersed and intercalated organophilic layered silicate particles.

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Synthesis of spherical phosphors (Y,Gd)$BO_3$:Eu from Precursors in Polymeric Form by Aerosol Pyrolysis

  • Jeoung, Byung-Woo;Yoo, Won-Tae;Hong, Gun-Young;Yoo, Jae-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.788-791
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    • 2002
  • The phosphors of high luminous efficiency for PDP application must have high purity, single phase, and dense surface. In this work, the polymeric reaction was applied to preparation of spherical phosphor by aerosol pyrolysis in order to enhance mechanical and optical characteristics. The red phosphor of (Y,Gd)$BO_3$:Eu was prepared from polymeric precursor, in which citric acid and ethylene glycol were used as ion carriers, i.e monomers. For enhancing the luminescence intensity and mechanical characteristics. optimum synthesizing condition were investigated through concentration of monomers, synthetic temperature. doped activator concentrations, and annealing process. The phosphors synthesized with monomers showed quite different morphology from those without monomers. It was observed that polymeric precursor made an effect on particle formation mechanism and status of particles surface. The resultant spherical phosphors show the comparable luminescent properties to the commercial product (product by Nichia co.). Also, they were observed to have the rigid surface.

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Effect of Fluorination on Electrical Behaviors of Carbon Blacks-filled HDPE Polymeric Switch

  • Seo, Min-Kang;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1337-1340
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    • 2009
  • Electrical properties of a fluorinated carbon black (CB)-filled high-density polyethylene (HDPE) polymeric switch were investigated as a function of fluorination pressure at 0.1 ~ 0.4 MPa. From the FT-IR results, the absorption spectra of the fluorinated CB show an absorption band at 1400 ~ 1000 $cm^{-1}\;for\;{\nu}_{C-F}$ and the peak intensity increased with increasing fluorination pressure. Also, the analysis of XPS spectra of the fluorinated CB indicated that fluorine content increased with increasing fluorination pressure. Meanwhile, the surface free energy of the fluorinated CB decreased with increasing fluorination pressure. Consequently, the increase of fluorine contents of CB made a disappearance of negative temperature coefficient (NTC) behavior of the polymeric switch, which was probably due to the reduction of CB reaggregation after melting point of the HDPE, resulted from the decreasing of London dispersive component of the surface free energy for CB particles.

Adhesive Properties of Acrylic Emulsion Pressure Sensitive Adhesives with Polymeric Emulsifier (고분자 유화제를 이용한 수성 아크릴 에멀션 점착제의 접착 물성)

  • 박명철;이명천
    • Polymer(Korea)
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    • v.27 no.6
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    • pp.596-602
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    • 2003
  • A Polymeric emulsifier was synthesized by solution polymerization with 2-ethylhexyl acrylate, n-butyl acrylate, and acrylic acid. A series of polymeric emulsifier have been used in the emulsion copolymerization of 2-ethylhexyl actryacrylate and n-butyl acrylate. The size of the synthesized latex particles was around 145 nm and its distribution was very narrow. Emulsion with polymeric emusifier showed no coagulum after 7 cycles of freeze-thaw test, while the emulsion with traditional emulsifier exhibited coagulum after 2 cycles. The adhesion tests showed that the initial tackiness and peel strength decreased as the molecular weight and acrylic acid content of polymeric emulsifier increased, whereas the holding power increased.

Synthesis of Silica Nanoparticles Having the Controlled Size and their Application for the Preparation of Polymeric Composites (크기가 제어된 실리카 나노입자 합성과 제조된 입자의 고분자계 복합재 응용)

  • Kim, Jong-Woung;Kim, Chang-Keun
    • Polymer(Korea)
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    • v.30 no.1
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    • pp.75-79
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    • 2006
  • Silica nanoparticles for polymeric dental restorative composites were prepared by Stober method, and then the effects of surface treatment of silica particles with Lmethacrylofpropyltrimethofsilane $(\gamma-MPS)$ on the dispersity of the silica particles in the organic matrix was investigated. Particles having various average size were prepared by using controlled amounts of tetraethylorthosilicate(TEOS), water, and catalyst and by changing solvent used for reaction. The site of particles prepared by using methanol as solvent was smaller than that prepared by using ethanol as solvent. In addition, the size of particles was increased by decreasing amounts of water and by increasing amounts of TEOS and catalyst. Hydrophobic silica nanoparticles was prepared by reacting hydrophilic nanoparticles with $\gamma-MPS$ to improve interfacial properties with organic matrix. Amounts of $\gamma-MPS$ per unit mass of the particles was increased by decreasing particle size. even though the amount of $\gamma-MPS$ per specific surface area were nearly the same regardless of the particle size. The dispersity of the silica particles in the organic matrix was improved when the surface treated silica particles were used for preparing the polymeric dental restorative composites.

Optimization of Emulsion Polymerization for Submicron-Sized Polymer Colloids towards Tunable Synthetic Opals

  • Kim, Seul-Gi;Seo, Young-Gon;Cho, Young-Jin;Shin, Jin-Sub;Gil, Seung-Chul;Lee, Won-Mok
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1891-1896
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    • 2010
  • Submicron-sized polymeric colloidal particles can self assemble into 3-dimensional (3D) opal structure which is a useful template for photonic crystal. Narrowly dispersed polymer microspheres can be synthesized by emulsion polymerization in water using water-soluble radical initiator. In this report, we demonstrate a facile and reproducible emulsion polymerization method to prepare various polymeric microspheres within 200 - 400 nm size ranges which can be utilized as colloidal photonic crystal template. By controlling the amount of monomer and surfactant, monodisperse polymer colloids of polystyrene (PS) and acrylates with various sizes were successfully prepared without complicated synthetic procedures. Such polymer colloids self-assembled into 3D opal structure exhibiting bright colors by reflection of visible light. The colloidal particles and the resulting opal structures were rigorously characterized, and the wavelength of the structural color from the colloidal crystal was confirmed to have quantitative relationship with the size of constituting colloidal particles as predicted by Bragg equation. The tunability of the structural color was achieved not only by varying the particle size but also by infiltration of the colloidal crystal with liquids having different refractive indices.