• 제목/요약/키워드: polymer substrates

검색결과 340건 처리시간 0.035초

전사방법을 이용한 폴리머 필름에 내재된 실리콘 나노구조물 어레이 제작 (Fabrication of a Silicon Nanostructure Array Embedded in a Polymer Film by using a Transfer Method)

  • 신호철;이동기;조영학
    • 한국생산제조학회지
    • /
    • 제25권1호
    • /
    • pp.62-67
    • /
    • 2016
  • This paper presents a silicon nanostructure array embedded in a polymer film. The silicon nanostructure array was fabricated by using basic microelectromechanical systems (MEMS) processes such as photolithography, reactive ion etching, and anisotropic KOH wet etching. The fabricated silicon nanostructure array was transferred into polymer substrates such as polymethyl methacrylate (PMMA), polyethylene terephthalate (PET), and polycarbonate (PC) through the hot-embossing process. In order to determine the transfer conditions under which the silicon nanostructures do not fracture, hot-embossing experiments were performed at various temperatures, pressures, and pressing times. Transfer was successfully achieved with a pressure of 1 MPa and a temperature higher than the transition temperature for the three types of polymer substrates. The transferred silicon nanostructure array was electrically evaluated through measurements with a semiconductor parameter analyzer (SPA).

Tetrapyrazinoindoloporphyrazine Langmuir-Blodgett Films

  • Kim, Jong-Min;Jaung, Jae-Yun;Ahn, Hee-Joon
    • Macromolecular Research
    • /
    • 제16권4호
    • /
    • pp.367-372
    • /
    • 2008
  • We fabricated tetra(5-n-nonyl-8-tert-butyl-2,3-pyrazino[2,3-b]indolo)porphyrazinato copper(II) (Cu-Pc-$C_8$) Langmuir-Blodgett (LB) films. We further investigated the influence of arachidic acid (AA) as a transfer promoter, as well as the effect of dipping speed, on the deposition of the films on hydrophilic and hydrophobic substrates. In the case of pure Cu-Pc-$C_8$ LB deposition on a hydrophilic substrate, the transfer ratio was close to one for up-stroke depositions, but the previously deposited film was peeled off and re-spread onto water at down-stroke depositions. Whereas the stability of the Cu-Pc-$C_8$ LB films was not improved by AA addition on hydrophilic substrates, the deposition of Cu-Pc-$C_8$ was significantly improved by the presence of AA on a hydrophobic substrate. The AA-assisted deposition had transfer ratio of close to 1 and was essentially stable up to 10-layer depositions. Comparison of the UV-visible spectrum of a Cu-Pc-$C_8$/AA LB film with that of Cu-Pc-$C_8$/AA solution in dichloroethane revealed that the Soret and Q bands for the Cu-Pc-$C_8$/AA LB film were broadened and red-shifted due to the aggregation of phthalocyanines upon assembly in the LB film.

Bendable Photoelectrodes by Blending of Polymers with $TiO_2$ For Low Temperature Dye-sensitized Solar Cells

  • 유기천;리위롱;이도권;김경곤;고민재
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
    • /
    • pp.319-319
    • /
    • 2010
  • Dye-sensitized solar cells (DSSCs) based on plastic substrates have attracted much attention mainly due to extensive applications such as ubiquitous powers, as well as the practical reasons such as light weight, flexibility and roll-to-roll process. However, conventional high temperature fabrication technology for glass based DSSCs, cannot be applied to flexible devices because polymer substrates cannot withstand the heat more than $150^{\circ}C$. Therefore, low temperature fabrication process, without using a polymer binder or thermal sintering, was required to fabricate necked $TiO_2$. In this presentation, we proposed polymer-inorganic composite photoelectrode, which can be fabricated at low temperature. The concept of composite electrode takes an advantage of utilizing elastic properties of polymers, such as good impact strength. As an elastic material, poly(methyl methacrylate) (PMMA) is selected because of its optical transparency and good adhesive properties. In this work, a polymer-inorganic composite electrode was constructed on FTO/glass substrate under low temperature sintering condition, from the mixture of PMMA and $TiO_2$ colloidal solution. The effect of PMMA composition on the photovoltaic property was investigated. Then, the enhanced mechanical stability of this composite electrode on ITO/PEN substrate was also demonstrated from bending test.

  • PDF

Preparation and Properties of Polyolefin Graft Polymer available as a Primer for Polyurethane Adhesive (I) Synthesis of polyolefins with cyclic acid anhydride by free radical graft polymerization

  • Ryu, Ki Jung;Kim, Min Jung;Min, Seong Kee;Lee, Won Kee;Park, Chan Young
    • Elastomers and Composites
    • /
    • 제50권2호
    • /
    • pp.119-125
    • /
    • 2015
  • Because of their low surface free energy and absence of polar groups at the surface, polyolefins are substrates whose wetting and adhesion are very difficult. Free radical grafting of monomers to backbone polymer is one of the most attractive ways for the chemical modification of polymers. Synthesis of graft copolymer through graft polymerizations of PE and/or PP with phthalic anhydride (PhAn) was made and FTIR spectra of the graft polymer were the examined. And also the effects of phthalic anhydride content on the grafting ratio, thermal properties and contact angle of the graft polymer were examined.

방사선을 이용한 강화 복합 연료전지막 다공성 지지체용 PTFE-g-PAA 제조 및 특성 연구 (Radiolytic Fabrication and Characterization of PTFE-g-PAA as the Supporters for the Reinforced Composite Fuel Cell Membrane)

  • 손준용;박병희;송주명;이영무;신준화
    • 폴리머
    • /
    • 제37권5호
    • /
    • pp.649-655
    • /
    • 2013
  • 방사선 그래프팅 방법을 이용하여 다공성 PTFE 지지체에 친수성 고분자 사슬인 아크릴산 사슬을 도입시켜 강화 복합 연료전지막의 지지체로 사용하기 위한 PTFE 친수화 다공성 지지체를 제조하였고 FTIR을 이용하여 다공성 PTFE에 친수성 고분자가 성공적으로 도입되었음을 확인하였다. 제조된 지지체의 표면 친수화 정도를 관찰하기 위해 접촉각을 측정한 결과, 도입된 친수성 고분자 사슬이 증가할수록 소수성의 PTFE 표면 친수화도가 증가됨을 확인하였다. 또한 제조된 지지체의 물리화학적, 형태학적 특성은 FE-SEM, gurley number, 인장강도를 측정하여 관찰하였다.

CHEMISTRY, PHYSICS AND TECHNOLOGY FOR NEW LIQUID CRYSTAL DISPLAYS

  • Penterman, Roel;Klink, Stephen I.;Koning, Henk de;Vogels, Joost;Huitema, Edzer;Broer, Dirk J.
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
    • /
    • pp.273-276
    • /
    • 2003
  • Polymerization induced diffusion has been successfully applied to create new display components. Based on this principle a new technique to produce polymer covered liquid crystal layers on a single substrate, called photo-enforced stratification, allows cost-effective production of ultra-thin LCDs. The two-step photopolymerization-induced phase separation of a liquid crystal and a polymer precursor can be performed on a variety of substrates and provides freedom in display design.

  • PDF

Fabrication and electro optical properties of stressed liquid crystal cell

  • Lee, Jung-Min;Park, Jin-Seol;Kang, Dae-Seung
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
    • /
    • pp.681-682
    • /
    • 2009
  • We fabricated a stressed liquid crystal cell by mixing liquid crystal with a photo-polymer. By carefully choosing the mixing ratio between liquid crystal and the polymer, and by suitable mechanical shearing of the substrates, we demonstrated feasible electro optical properties for displays.

  • PDF

CNT 마이크로파 가열을 이용한 고분자 기판의 상온 접합 및 기계적 특성평가 (Room-temperature Bonding and Mechanical Characterization of Polymer Substrates using Microwave Heating of Carbon Nanotubes)

  • 손민정;김민수;주병권;이태익
    • 마이크로전자및패키징학회지
    • /
    • 제28권2호
    • /
    • pp.89-94
    • /
    • 2021
  • 최근 플렉시블 기기의 상용화를 위하여 기계적 신뢰성 연구가 활발히 진행되고 있으며 이를 고려하여 신뢰성 높은 다양한 접합부의 구현이 중요하다. 기기의 많은 부피를 차지하는 고분자 기판 또는 필름을 접합할 때에는 재료의 약한 내열성으로 접합공정 중 열 손상이 발생할 수 있으므로 신뢰성을 확보를 위해 상온 접합공정이 필요하다는 제약이 있다. 기존의 기판 접합을 위해 사용되는 에폭시 또한 고온 경화가 요구되는 경우가 많고, 특히 경화 접합 후 에폭시는 접합부 유연성 및 피로 내구성에서 한계를 보인다. 이를 해결하기 위하여 접착제 사용이 없는 저온 접합 공정의 개발이 필요한 상황이다. 본 연구에서는 마이크로파에 의한 탄소나노튜브 가열을 이용한 고분자 기판의 저온 접합공정을 개발하였다. PET 고분자 기판에 다중벽 탄소나노튜브 (MWNT)를 박막 코팅한 뒤 이를 마이크로파로 국부 가열함으로써 접합 기판 전체는 저온을 유지하며 CNT-PET 기계적 얽힘을 유도하는 방식이다. PET/CNT/PET 접합시편에 600 Watt 출력의 마이크로파를 10초간 조사함으로써 유연기판 접합에 성공하였고 매우 얇은 CNT 접합부를 구현하였다. 접합 시편의 기계적 신뢰성을 평가하기 위해 중첩 전단 강도 시험, 삼점 굽힘 시험, 반복 굽힘 시험을 수행하였으며 각 시험으로부터 우수한 접합강도, 유연성, 굽힘 내구성이 확인되었다.

Stability-Enhanced Liquid Crystal Mode for Flexible Display Applications

  • Jung, Jong-Wook;Jang, Se-Jin;Lee, You-Jin;Kim, Hak-Rin;Jin, Min-Young;Kim, Jae-Hoon
    • Journal of Information Display
    • /
    • 제6권2호
    • /
    • pp.1-6
    • /
    • 2005
  • We demonstrated stability-enhanced liquid crystal (LC) displays using pixel-isolated LC mode in which LC molecules are isolated in pixel by horizontal polymer layer and vertical polymer wall. The device shows good electro-optic properties against external point or bending pressure due to the polymer structures. The polymer wall acts as supporting structure from mechanical pressure and prevents the cell gap from bending. Moreover, the polymer layer acts as an adhesive to ensure a tight attachment of the two substrates. We present herein various methods for producing polymer structures by using an anisotropic phase separation from LC and polymer composites or patterned micro-structures for stable flexible liquid crystal displays.