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Tetrapyrazinoindoloporphyrazine Langmuir-Blodgett Films  

Kim, Jong-Min (Department of Fiber and Polymer Engineering, Hanyang University)
Jaung, Jae-Yun (Department of Fiber and Polymer Engineering, Hanyang University)
Ahn, Hee-Joon (Department of Fiber and Polymer Engineering, Hanyang University)
Publication Information
Macromolecular Research / v.16, no.4, 2008 , pp. 367-372 More about this Journal
Abstract
We fabricated tetra(5-n-nonyl-8-tert-butyl-2,3-pyrazino[2,3-b]indolo)porphyrazinato copper(II) (Cu-Pc-$C_8$) Langmuir-Blodgett (LB) films. We further investigated the influence of arachidic acid (AA) as a transfer promoter, as well as the effect of dipping speed, on the deposition of the films on hydrophilic and hydrophobic substrates. In the case of pure Cu-Pc-$C_8$ LB deposition on a hydrophilic substrate, the transfer ratio was close to one for up-stroke depositions, but the previously deposited film was peeled off and re-spread onto water at down-stroke depositions. Whereas the stability of the Cu-Pc-$C_8$ LB films was not improved by AA addition on hydrophilic substrates, the deposition of Cu-Pc-$C_8$ was significantly improved by the presence of AA on a hydrophobic substrate. The AA-assisted deposition had transfer ratio of close to 1 and was essentially stable up to 10-layer depositions. Comparison of the UV-visible spectrum of a Cu-Pc-$C_8$/AA LB film with that of Cu-Pc-$C_8$/AA solution in dichloroethane revealed that the Soret and Q bands for the Cu-Pc-$C_8$/AA LB film were broadened and red-shifted due to the aggregation of phthalocyanines upon assembly in the LB film.
Keywords
arachidic acid; Langmuir-Blodgett; tetrapyrazinoindoloporphyrazine; transfer promoter;
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Times Cited By KSCI : 5  (Citation Analysis)
Times Cited By Web Of Science : 1  (Related Records In Web of Science)
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