• Title/Summary/Keyword: polymer substrate

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Comparison of Adhesion Performance According to Concrete Moisture Content of Primer Mixed with Cement and Modified Polymer (시멘트와 변성 폴리머를 혼합한 프라이머의 콘크리트 함수율에 따른 부착성능 비교)

  • Kang, Hyo-Jin;An, Ki-Won;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.231-232
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    • 2019
  • In this study, primers were prepared by mixing cement and modified polymer, and the adhesion to the substrate surface was enhanced by using cement which is the same material as the basement outer wall. The improved primer is used to verify the adhesion performance of the substrate in wet concrete environments.

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The Effect of Curing condition on Adhesion in Tension of Polymer-Modified Mortars (양생존건이 폴리머 시멘트 모르터의 접착강도에 미치는 영향)

  • 전우성;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.04a
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    • pp.349-356
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    • 1997
  • The purpose of this study is to evaluate the effect of curing conditions on adhesion in tension of polymer-modified mortar to cement mortar substrate in comparision with ordinary cement mortar. The polymer-modifies mortars using two polymer dispersions and a redispersible polymer power are prepared with various polymer-cement ratios, and tested for the adhesion in tension of the specimens subjected to five curing conditions. From the test results, the adhesion in tension of polymer-modified mortars tends to increase with increasing polymer-cement ratio irrespective of the polymer types and curing conditions. It is apparent that adhesion in tension of polymer-modified mortars is considerably influenced by curing conditions.

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Growth Responses of Eggplant (Solanum melongena) to Hydrophilic Polymer Mixture Ratio in Growing Medium for Lower Maintenance Urban Agriculture via Green Roofs (옥상 내 저관리 도시농업에서 친수성 중합체 배합비에 따른 가지(Solanum melongena)의 생육반응)

  • Ju, Jin-Hee;Kim, Won-Tae;Xu, Hui;Yoon, Young-Han;Choi, Eun-Young
    • Journal of Environmental Science International
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    • v.25 no.5
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    • pp.625-633
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    • 2016
  • This study was conducted to investigate the influence of hydrophilic polymer (HP) mixture ratio (Control, 1.0%, 2.5%, 5.0%, and 10.0%) on growth of eggplant (Solanum melongena) for lower maintenance urban agriculture via green roofs. Although it was not statistically significant (p > 0.05), substrate temperature was decreased as hydrophilic polymer mixture ratio were increased. High substrate water content (95%) was found consistently in growing media under elevated hydrophilic polymer mixture ratio at over 5% during the entire growing period. Substrate electronic conductivity was increased as hydrophilic polymer mixture ratio were increased. Growth index was decreased as hydrophilic polymer mixture ratio was increased. It was reduced about 1/3 and 1/5 compared to that of Control in HP5.0 and HP10.0 treatment plants, respectively. Number of leaves, leaf length, and leaf width were decreased in following order: Control> HP1.0> HP2.5> HP5.0> HP10.0 treatments. There numbers were significantly lower in HP5.0 and HP10.0 treatment plants. Dry weight of shoot and root were decreased as hydrophilic polymer mixture ratio was increased. They were reduced by 1/4 compared to those of Control treatment plants. In addition, visual value was decreased as hydrophilic polymer mixture ratio was increased. Plants grown in HP1.0, HP2.5, and HP5.0 treatments all survived. However, plants grown in the HP10.0 treatment had the lowest survival rate (56%) after 3 months of growing. These results indicate that the advantage of adding hydrophilic polymer to green roof growing media may greater during dry periods. However, the proper mixture proportion of hydrophilic polymer should be determined according to different characteristics of growing media and plant species.

Bond Performance of Magnesium Potassium Phosphate Cement Mortar according to Moisture Condition of Substrate (바탕면 함수조건에 따른 마그네시아 인산칼륨 시멘트 모르타르의 부착성능)

  • Kang, Suk-Pyo;Kim, Jae-Hwan
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.1
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    • pp.15-22
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    • 2017
  • This study focuses on the investigation of bond strength of magnesium potassium phosphate cement mortar(MKPC) according to moisture condition of substrate. Tensile bond test, shear bond test and interfacial bond test are adopted for evaluating the adhesion characteristics of MKPC to conventional cement mortar substrate. The main experimental variables are test methods and moisture levels of substrate. Because the moisture condition of the substrate may be critical to achieving bond, optimum moisture condition for a conventional concrete substrate has evaluated in this study. The results are as follows ; The effects of moisture condition at substrate into the bonding of MKPC are less different than polymer cement mortar and epoxy mortar. But the saturated and surface dry condition is the most appropriate moisture level among the considered, followed by saturated condition and wet condition. Thus, an adequate moisture level of substrate for MKPC is essential for good bond strength.

Fabrication of Polymer Thin Films on Solid Substrates (고체 기판에 고분자 박막의 고정화)

  • Kim, Min Sung;Jeong, Yeon Tae
    • Applied Chemistry for Engineering
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    • v.21 no.2
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    • pp.200-204
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    • 2010
  • Surface properties are important for determining the functions and uses of materials. So modification of materials with polymer thin films has emerged as an important method to control the physical and chemical properties of the surface layer. We report a simple and effective method to photochemically attach thin polymeric layers to solid surface without chemical derivatization of the substrate and/or the polymer. The system is based on a photoreactive poly(4-vinylpyridine) (P4VP) thin film which is formed on the $SiO_{2}$ surface via spin coating. This substrate is then covered with another polymer film that is reacted with the benzyl radical moieties by UV irradiation. As a result of photochemical reaction, a thin layer of the later polymer is covalently bound to the surface of P4VP. Unbounded polymer is removed by sonication. The thickness of the attached film is a function of the irradiation time and the molecular weight of the polymer. Spatially defined polymer thin films can be fabricated by way of photolithography.

Effect of Polymer Coating on the Initial Microorganism Attachment and the Biofilm Growth (고분자 물질 도포가 미생물 부착과 생물막 성장에 미치는 영향)

  • 박영식;송승구
    • Journal of Environmental Health Sciences
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    • v.24 no.2
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    • pp.104-109
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    • 1998
  • The objective of this study was to examine the effect of polymer coating on the initial microorganism attachment and the biofilm growth. Such as nonion(polyacrylamine), anion(CMC-Na) and cation polymer coagulant(chitosan and PEI) were used for coating material of the support carrier(acryl plate). When polymer coagulant was coated with 5, 10, 20, 35, 50, 100 and 200 mg/l on the surface of acryl plate, initial microorganism attachment increased and optimum concentration for the attachment was 35 mg/l. Biofilm growth experiments were conducted with the substrate loading of 12.7gSCOD/$m^2\cdot$ day using RBC. The polymer coagulants such as CMC-Na, polyacrylamide, PEI and chitosan coating on the acryl plate facilitated the biofilm growth of microorganisms. Until the biofilm dry weight grows up to 0. 0038g/cm$^2$, biofilm growth on the plate coated with cation polymer like chitosan was better than that on the coated plate of nonion(polyacrylamine), anion(CMC-Na) polymer coagulant.

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Patterning of conducting polymer at micron- scale using a selective surface treatment

  • Lee, Kwang-Ho;Kim, Sang-Mook;Kim, Ki-Seok;Song, Sun-Sik;Kim, Eun-Uk;Jung, Hee-Soo;Kim, Jin-Ju;Jung, Gun-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.834-836
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    • 2008
  • We demonstrated micro-scale conducting polymer patterning based on a selective surface treatment. A substrate with a patterned photoresist was immersed into OTS (Octadecyltrichlosilnae) solution. The protected substrate areas were hydrophilic after removing the PR resist, where a conducting polymer solution was coated selectively by spin-coating method.

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Flow Behavior of Thin Polymer Film by various patterns in Spinning Coating Process of Blu-ray Disc Cover layer (블루레이 디스크의 커버레이어 스핀 코팅 시 다양한 패턴에 따른 최적화된 폴리머 거동에 관한 연구)

  • Cho K. C.;Park Y. H.;Kim H. Y.;Kim B. H.;Lee B. G.;Son S. G.;Shin H. K.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.10a
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    • pp.467-471
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    • 2005
  • In this paper, experimental methods about the flow behavior of thin polymer film by various edge patterns in the spin coating process for stable cover layer coating of a blu-ray disc is described. The blu-ray disc, a next-generation optical disc format over 25GB, consists of a 1.1m thick substrate and a 0.1mm tick cover layer. Generally, cover layer on the blu-ray disc is made by the polymer spin coating process. However, it is hard to secure sufficient coating uniformity around the rim on the cover layer. In order to get the uniform thickness deviation and to minimize the bead around the rim, the edge of the disc substrate can be modified into various patterns, such as normal plain, trench, step and chamfer pattern, etc, around the rim on the disc and experimented with various parameters, such as surface tension, viscosity, coating time, temperature and rotation speed, etc. And the optimal shape of the rim was tried to get by 3 dimensional computer simulation of the polymer expulsion process.

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Femtosecond Laser Ablation of Polymer Thin Films for Nanometer Precision Surface Patterning

  • Jun, Indong;Lee, Jee-Wook;Ok, Myoung-Ryul;Kim, Yu-Chan;Jeon, Hojeong
    • Journal of the Korean institute of surface engineering
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    • v.49 no.1
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    • pp.20-25
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    • 2016
  • Femtosecond laser ablation of ultrathin polymer films on quartz glass using laser pulses of 100 fs and centered at ${\lambda}=400nm$ wavelength has been investigated for nanometer precision thin film patterning. Single-shot ablation craters on films of various thicknesses have been examined by atomic force microscopy, and beam spot diameters and ablation threshold fluences have been determined by square diameter-regression technique. The ablation thresholds of polymer film are about 1.5 times smaller than that of quartz substrate, which results in patterning crater arrays without damaging the substrate. In particular, at a $1/e^2$ laser spot diameter of $0.86{\mu}m$, the smallest craters of 150-nm diameter are fabricated on 15-nm thick film. The ablation thresholds are not influenced by the film thickness, but diameters of the ablated crater are bigger on thicker films than on thinner films. The ablation efficiency is also influenced by the laser beam spot size, following a $w_{0q}{^{-0.45}}$ dependence.