• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.269-269
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• 2006

The molecular structure of poly(2,6-dimethyl-4,4' -phenylene oxide)-g-poly (styrenesulfonic acid) (PPO-g-PSSA) graft copolymer was designed, and synthesized via living radical polymerization. Obtained graft copolymers were transformed into proton exchange membranes for direct methanol fuel cell (DMFC) application. The performance of the membranes was measured in terms of water uptake, proton conductivity, methanol permeability, and thermal stability. Very low methanol permeability and good proton conductivity were observed by adjusting grafting frequency and PSSA block content.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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• pp.1568-1570
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• 2008

In this paper, fabrication of a $60{\times}48$ polymer TFT array with a top-gate structure on plastic substrates using a low temperature printing process will be presented and the device structure and manufacturing processes will be discussed. The polymer TFT array showed excellent air stability and uniform electrical characteristics over a large area. Finally, a 1.5 inch EPD display with 50 dpi resolution using the polymer TFT array will be demonstrated for e-film device applications.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2007년도 춘계학술논문 발표대회
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• pp.59-62
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• 2007

Nowadays, polymer-cement mortars are widely used in construction field(floorings and pavements, water-proofings, adhesives, repair materials, deck coverings, anti-corrosive linings) Because of excellent performance such as high tensile and flexural strength, waterproofness, excellent adhesion, good durability, improved wear and chemical resistances. This article presents the results of experimental study that investigates the effect of ambient temperature on the strength properties of polymer-modified cement mortar. Results show that when increasing the polymer proportion in mortar on different ambient temperature, the compressive strength and flexural strength are decreased, and also alkali resistance is decreased.

• Macromolecular Research
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• 제15권3호
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• pp.225-233
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• 2007

To improve the poor mechanical and low-temperature properties of glycidyl azide polymer (GAP)-based propellants, the addition of binders was investigated using GAP and flexible polymer backbone-structural polycaprolactone (PCP) at various weight(wt) ratios, and varying the ratio of Desmodur N-100 pluriisocyanate (N-100) to isophorone diisocyanate (IPDI). Using Gee's theory, the solubility parameter of the PCP network was determined, in order to elucidate the physical and chemical interaction between GAP and PCP. The structure of the binder networks was characterized by measuring the cross-link densities and molecular weights between cross-links ($M_c$) obtained by a swelling experiment using Flory-Rhener theory. The thermal and mechanical properties of the segmented block copolyurethane (GAP-b-PCP) binders prepared by the incorporation of PCP into the binder recipes were investigated, along with the effect of the different curatives ratios.

• Macromolecular Research
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• 제14권4호
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• pp.449-455
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• 2006

Ionic cluster mimic, polymer electrolyte membranes were prepared using polymer composites of crosslinked poly(vinyl alcohol) (PVA) with sulfated-${\beta}$-cyclodextrins (${\beta}-CDSO_3H$) or phosphated-${\beta}$-cyclodextrins (${\beta}-CDPO(OH)_2$). When Nafion, developed for a fuel cell using low temperature, polymer electrolyte membranes, is used in a direct methanol fuel cell, it has a methanol crossover problem. The ionic inverted micellar structure formed by micro-segregation in Nafion, known as ionic cluster, is distorted in methanol aqueous solution, resulting in the significant transport of methanol through the membrane. While the ionic structure formed by the ionic sites in either ${\beta}-CDSO_3H$ or ${\beta}-CDPO(OH)_2$ in this composite membrane is maintained in methanol solution, it is expected to reduce methanol transport. Proton conductivity was found to increase in PVA membranes upon addition of ionized cyclodextrins. Methanol permeability through the PVA composite membrane containing cyclodextrins was lower than that of Nafion. It is thus concluded that the structure and fixation of ionic clusters are significant barriers to methanol crossover in direct methanol fuel cells.

• Korean Chemical Engineering Research
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• 제46권1호
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• pp.88-93
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• 2008

지역규칙성 폴리3핵실티오펜과 용해성 플러렌 블렌드로 이루어진 벌크이종접합 고분자 태양전지를 제작하였다. 고분자 블렌드 필름에 대한 열처리 효과가 필름의 결정 구조와 자외선/가시광선 흡수스펙트럼에 주는 영향을 조사하였다. 그 후, 열처리에 의한 필름의 결정구조와 태양전지 효율의 상관관계를 연구하였다. 그 결과, $150^{\circ}C$에서 열처리한 필름이 분자간 상호작용 및 결정성측면에서 최적이었으며, 이 때, 고분자 태양전지의 에너지 전환 효율은 3.2 %이었다.

• Journal of Pharmaceutical Investigation
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• 제41권3호
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• pp.179-184
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• 2011

This study aimed to confirm the effect of molecular weight (MW) in solid dispersion of carvedilol with poly-vinylpyrrolidone (PVP) of various MW. Solid dispersion of carvedilol with PVP was prepared by spray-drying method. Scanning electron microscopy (SEM) was used to analyze the surface of solid dispersion samples. Differential scanning calorimetry (DSC) and X-ray diffraction (XRD) were used to analyze the crystalline of solid dispersion. Fourier transform infrared spectroscopy (FT-IR) was used to analyze the change of chemical structure characteristic of solid dispersion. DSC and XRD show that drug crystalline was changed. FT-IR revealed that chemical structure of solid dispersion comparing the chemical structure of drug was changed. The dissolution studies of solid dispersion presented at simulated gastric juice (pH 1.2). The dissolution rate of solid dispersion was dramatically enhanced than pure drug and the MW of PVP has an effect on the release property of carvedilol in solid dispersion. In conclusion, the present study has confirmed the effect of MW of PVP on release property of solid dispersion formulation of carvedilol with PVP.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2003년도 춘계학술대회 논문집
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• pp.113-116
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• 2003

To maximize the productivity in machining molds and dies, machine tools should operate at high speeds. During the high speed operation of moving frames or spindles, vibration problems are apt to occur if the machine tool structures are made of conventional steel materials with inferior damping characteristics. However, self-excited vibration or chatter is bound to occur during high speed machining when cutting speed exceeds the stability limit of machine tool. Chatter is undesirable because of its adverse effect on surface finish, machining accuracy, and tool lift. Furthermore, chatter is a major cause of reducing production rate because, if no remedy can be found, metal removal rates have to be lowered until vibration-free performances is obtained. Also, the resonant vibration of machine tools frequently occurs when operating frequency approaches one of their natural frequencies because machine tools have several natural frequencies due to their many continuous structural elements. However, these vibration problems are closely related to damping characteristics of machine tool structures. This paper presents the use of polymer concrete and sandwich structures to overcome vibration problems. The polymer concrete has high potential for machine tool bed due to its good damping characteristics with moderate stiffness. In this study, a polymer concrete bed combined with welded steel structure i.e., a hybrid structure was designed and manufactured for a high-speed gantry-type milling. Also. its dynamic characteristics were measured by modal tests.

• 전기화학회지
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• 제24권1호
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• pp.1-6
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• 2021

In this study, new morphology of NCA cathode material for lithium ion batteries was obtained through the electrospinning method. The prepared NCA nanofibers formed a nano-bush structure, and the primary particles were formed on the surface of the nanofibers. The embossing primary particles increased the surface area thus increasing the reactivity of lithium ions. The nano-bush structure could shorten the Li+ diffusion path and improve the Li+ diffusion coefficient. Scanning electron microscopy (SEM) revealed that the synthesized material consisted of nanofibers. The surface area of the nanofibers increased by primary particles was measured using atomic force microscopy (AFM). X-ray diffraction (XRD) analysis was carried out to determine the structure of the NCA nanofibers.

• 한국고분자학회지:고분자과학과기술
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• 제8권5호
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• pp.520-529
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• 1997