• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2002.04a
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• pp.22-27
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• 2002

The existing compressor steel seal used in automotive air-conditioner has the problem of oil leakage and the deterioration in shielding performance, due to the abrasion and the corrosion of the material. A new type of polymer resin seal is studied in the research. The polymer resin seal has the characteristics of high anti-abrasiveness and anti-corrosiveness, which can overcome the deflects of the steel seal. In addition, the seal needs lower manufacturing cost and is appropriate to mass production, because it is made by the injection molding method requiring no mechanical processing. The profile generation program for seal mold has been developed using the gradient method, and the molding characteristics of the seal have analyzed through the flow analysis and the warpage analysis. The program has been verified by comparing the analysis results with the measured data of the test product. The research might be said to provide the basic method to produce the polymer resin seals with various types and dimensions.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.136-136
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• 2016

Commonly used oil-based polymer resin has environmental and safety issues. Many researches for replacing the harmful solvent-borne resins to water-borne resins have been investigated to purify harmful environmental resources and follow the export and import of hazardous materials regulations. In this research, ultrasonic spray coatings of aqueous polymer resin were studied to fabricate thin insulating layer (${\sim}{\mu}m$) on the rectangular copper wire. It needs to have appropriate wettability between resin and substrate during the ultrasonic spray coating process to coat aqueous polymer uniformly. Furthermore, stabilities of coating solution and fabricating process are required to form thin insulating layer on the substrate. In here, physical characteristics such as viscosity of 6 types of commercial polymer dispersions and emersions were analyzed to confirm compatibility for ultrasonic spray coating process. These resins were dissolved in isopropyl alcohol, used for true solvent, and were diluted with ethanol, utilized for diluent. Also, solubilities, dispersion characteristics, and viscosities of these diluted polymer resin solutions were confirmed. Dispersion characteristic and viscosity of coating solution affects jetting of ultrasonic spray coating and these jetting characteristics influence morphologies of insulating layer. In conclusion, we have known that aqueous polymer solution should have outstanding dispersion characteristic and certain range of viscosity to fabricate thin polymer insulating layer uniformly with ultrasonic spray coating.

• Polymer(Korea)
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• v.25 no.1
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• pp.71-77
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• 2001

Unsaturated polyester(UP) resin is one of the major thermosetting resins. It is very useful as the matrix resin of the composite material because of its low viscosity. The polymer resin, however, has several drawbacks; The volume shrinkage occurs during the crosslinking reaction of the UP resin with styrene monomer and the resulting polymer is weak to the alkali and also brittle. The mechanical properties of UP resin can be improved by blending various materials. In this study, polyurethane(PU) was used as a modifier in order to enhance the toughness of the UP resin. The goal of the research is to study the effect of the polyol molecular weight as a PU soft segment and the PU contents on the toughness of PU-modified UP resins. UP/PU polymer network may occur through the reaction between isocyanate group in the methyldiisocyanate(MDI) and hydroxyl group in the UP molecules. The maximum toughness value was shown at 2 wt% of the PU content. This effect results from the incorporation of the PU segment into the UP resin.

• Journal of The Korean Society of Agricultural Engineers
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• v.59 no.6
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• pp.19-27
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• 2017

This study investigated to predict the compressive strength of unsaturated polyester resin based polymer concrete using the maturity method. The test results show that the development of the compressive strength increased exponentially until an age of 24 hours. After 24 hours, the development of the compressive strength just increased gradually. This test result shows that the strength of unsaturated polyester resin based polymer concrete was developed mainly at the early age. Estimated datum temperature of unsaturated polyester resin based polymer concrete was $-20.67^{\circ}C$ which was much lower than of datum temperature ($-10^{\circ}C$) of Portland cement concrete. Also, this study result shows that the existing maturity index associated with Portland cement concrete was not applicable for polymer concrete because curing time of Portland cement concrete is different clearly with curing time of polymer concrete. The cause of different curing time was that there were different curing mechanisms between Portland cement concrete and polymer concrete. In order to best apply the experimental data to a model, CurveExpert Professional, the commercial software, was used to determine the predictive model regarding the compressive strength of unsaturated polyester resin based polymer concrete. As a result, Gompertz Relation or Weibull Model was an appropriate model as a predictive model. The proposed model can be used to predict the compressive strength, especially, it is more useful when the maturity is in the range between $40^{\circ}C{\cdot}h^{0.4}$ and $900^{\circ}C{\cdot}h^{0.4}$.

• Polymer Science and Technology
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• v.4 no.4
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• pp.247-257
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• 1993

• Polymer Science and Technology
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• v.4 no.4
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• pp.258-262
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• 1993

• Journal of The Korean Society of Agricultural Engineers
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• v.51 no.6
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• pp.97-103
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• 2009

This study was performed to evaluate the strength and durability properties of recycled polymer concrete using unsaturated polyester resin and recycled aggregates. Unsaturated polyester resin, natural and recycled aggregates and fly ash were used. The mix proportions were determined to satisfy the requirement for the workability and slump according to aggregate sizes (5-10 and 5-25 mm) and unit binder contents (10% and 12%). Tests for the compressive and flexural strength, freezing and thawing and durability for 20% sulfuric solution were performed. The compressive and flexural strength of recycled polymer concrete were in the range of 85~97 MPa and 17.9~20.8 MPa, respectively. The strengths of recycled polymer concrete using recycled aggregate have similar or slightly decreased compared to polymer concrete using natural aggregate. After 300 cycles of freezing and thawing, weight decrease ratio and durability factor of recycled polymer concrete were in the range of 0.13~1.42% and 94~99, respectively.

• Polymer(Korea)
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• v.38 no.2
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• pp.171-179
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• 2014

Low temperature cure prepregs are being developed for use in the preparation of large-structured fiber-reinforced polymer (FRP) composites with good performance. Cure behavior and chemorheology of low temperature cure epoxy resin system, based on epoxy resin, curing agent, and accelerators, were investigated to provide a matrix resin suitable for the prepreg preparation. Characteristics of cure reaction were studied in both dynamic and isothermal conditions by means of differential scanning calorimetry and rheometry. The low temperature cure epoxy resin system suggested in this study as a matrix resin was curable at $80^{\circ}C$ for 3 h, and showed the gel times of 120 and 20 min at 80 and $90^{\circ}C$, respectively. Thermal and mechanical properties of the cured sample were almost the same as high temperature cure counterparts.

• Elastomers and Composites
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• v.55 no.4
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• pp.289-299
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• 2020

Highly aromatic (HA) oils are common processing aids used in tire tread compounds. However, they often bleed and evaporate from the vulcanizates during tire use. Thus, the mechanical and dynamical properties of the tire decrease. To overcome this problem, we investigated nonfunctionalized liquid butadiene rubber (LBR-305, Kuraray) and center-functionalized liquid butadiene rubber (C-LqBR), polymerized by anionic polymerization. In addition to the liquid butadiene rubbers, p-tert-octylphenol (P-Resin) and C5 hydrocarbon (H-Resin) tackifier resins, which can induce entanglement of rubber compounds, were researched as a processing aid to solve the bleeding problem. Liquid butadiene rubbers have significantly reduced extraction loss by crosslinking with the main rubber chain. They have also increased the abrasion resistance and showed similar or better mechanical and dynamical properties against HA oils. However, resin compounds did not show differences in extraction loss compared to HA oil compounds; instead, they showed increased wet traction.

• Korean Journal of Materials Research
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• v.26 no.9
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• pp.472-477
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• 2016

Microstructure evolutions of thermosetting resin coating layers fabricated by electrostatic spray deposition (ESD) at various processing conditions were investigated. Two different typical polymer systems, a thermosetting phenol-formaldehyde resin and a thermoplastic polyvinylpyrrolidone (PVP), were employed for a comparative study. Precursor solutions of the phenol-formaldehyde resin and of the PVP were electro-sprayed on heated silicon substrates. Fundamental differences in the thermomechanical properties of the polymers resulted in distinct ways of microstructure evolution of the electro-sprayed polymer films. For the thermosetting polymer, phenol-formaldehyde resin, vertically aligned micro-rod structures developed when it was deposited by ESD under controlled processing conditions. Through extensive microstructure and thermal analyses, it was found that the vertically aligned micro-rod structures of phenol-formaldehyde resin were formed as a result of the rheological behavior of the thermosetting phenol-formaldehyde resin and the preferential landing phenomenon of the ESD method.