• 제목/요약/키워드: polymer pattern

검색결과 478건 처리시간 0.024초

5kW급 고분자 연료전지 시스템의 개발과 운전 (Development and Operation of 5kW-Class Polymer Electrolyte Membrane Fuel Cell System)

  • 전영갑;백동현;전광선;김창수;신동렬
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1999년도 하계학술대회 논문집 D
    • /
    • pp.1876-1878
    • /
    • 1999
  • Developed was a 5kW-class polymer electrolyte membrane fuel cell(PEMFC) system comprised of fuel cell stack, fuel processing, thermal and water management subsystems and ancillary equipments. Several large single cells have been fabricated with different gas flow field patterns and paths, and the gas flow field pattern for the stack has been determined based on the single cell performance of thin film membrane electrode assembly (MEA). The PEMFC stack was consisted of 100 cells with an electrode area of $300cm^2$, having serpentine flow pattern. Fuel processing was developed including an autothermal methanol reformer and two preferential CO oxidation reactors. The fuel processing was combined to PEMFC operation system consisted of air compressor and thermal and water management subsystems. The PEMFC stack showed performance of 5kW under the supply of $H_2$ and air, but its performance was lowered to 3.5kW under the supply of reformed gas.

  • PDF

고 형상비 UV LIGA 공정을 위한 낮은 내부응력의 SU-8 도금틀 제작 (SU-8 Mold Fabrication with Low Internal Stress and High Aspect Ratio for UV LIGA Process)

  • 장현기;김용권
    • 대한전기학회논문지:전기물성ㆍ응용부문C
    • /
    • 제48권8호
    • /
    • pp.598-604
    • /
    • 1999
  • This paper describes the research to minimize the film stress and maximize the aspect ratio of photoresist structure, especially about SU-8 for electroplating mold. UV LIGA process using SU-8 allows fabricating high aspect ratio polymer structures. However, it is hard to get fine patterns in the high aspect ratio structures because of high internal stress and difficulty of removing SU-8. The purpose of this paper is to setup the process condition for the obtainment of both low film stress and high aspect ratio and to find design rules that make the pattern be less dependent on stress problem. Firstly, the process of heat treatment and exposure of SU-8 are proposed. These two conditions control the amount of cross-linkage in polymer structure, which is the most important parameter of both pattern generation and remaining stress. Heat treatment is dealed with soft bake and post-exposure-bake. Temperature and time duration of each step are varied with heat treatment condition. Some test patterns are fabricated to evaluate the proposed process. Nickel electroplating is performed with the mold fabricated through the proposed process to confirm the SU-8 as a good electroplating mold.

  • PDF

Electrochromic Pattern Formation by Photo Cross-linking Reaction of PEDOT Side Chains

  • Kim, Jeong-Hun;Kim, Yu-Na;Kim, Eun-Kyoung
    • Macromolecular Research
    • /
    • 제17권10호
    • /
    • pp.791-796
    • /
    • 2009
  • An electrochemically and photochemically polymerizable monomer, 2-((2,3-dihydrothieno[3,4-b] [1,4]dioxin-2-yl)methoxy)ethyl methacrylate (EDOT-EMA), was explored for patterning of poly(3,4-ethylenedioxythiophene) (PEDOT) via side chain cross-linking. The polymer from EDOT-EMA was deposited electrochemically to produce polymeric EDOT (PEDOT-EMA), which was directly photo-patterned by UV light as the side EMA groups of PEDOT-EMA were polymerized to give cross-linked EMA (PEDOT-PEMA). Absorption and FTIR studies of the UV-exposed film (PEDOT-PEMA) indicated that the photo-patterning mainly originated from the photo cross-linking of the methacrylates in the side-chain. After irradiation of the film, the conductivity of the irradiated area decreased from $5.6{\times}10^{-3}$ S/cm to $7.2{\times}10^{-4}$ S/cm, possibly due to bending of the conductive PEDOT channel as a result of the side chain cross-linking. The patterned film was applied to a solid state electrochromic (EC) cell to obtain micro-patterned EC cells with lines up to 5 ${\mu}m$ wide.

Electro-Micromechanical Technique을 이용한 각의 변화에 따른 Carbon과 SiC Fiber/Epoxy Composites의 계면감지능 및 평가 (Interfacial Sensing and Evaluation of Carbon and SiC Fibers/Epoxy Composites with Different Embedding Angle using Electro-Micromechanical Technique)

  • Lee, Sang-Il;Kong, Jin-Woo;Park, Joung-Man
    • 한국복합재료학회:학술대회논문집
    • /
    • 한국복합재료학회 2002년도 춘계학술발표대회 논문집
    • /
    • pp.199-202
    • /
    • 2002
  • Interfacial properties and electrical sensing for fiber fracture in carbon and SiC fibers/epoxy composites were investigated by the electrical resistance measurement and fragmentation test. As fiber-embedded angle increased, interfacial shear strength (IFSS) of two-type fiber composites decreased, and the elapsed time was long to the infinity in electrical resistivity. The initial slope of electrical resistivity increased rapidly to the infinity at higher angle, whereas electrical resistivity increased gradually at small angle. Furthermore, both fiber composites with small embedded angle showed a fully-developed stress whitening pattern, whereas both composites with higher embedded angle exhibited a less developed stress whitening pattern. As embedded angle decreased, the gap between the fragments increased and the debonded length was wider for both fiber composites. Electro-micromechanical technique can be a feasible nondestructive evaluation to measure interfacial sensing properties depending on the fiber-embedded angle in conductive fiber reinforced composites.

  • PDF

Fatigue damage monitoring and evolution for basalt fiber reinforced polymer materials

  • Li, Hui;Wang, Wentao;Zhou, Wensong
    • Smart Structures and Systems
    • /
    • 제14권3호
    • /
    • pp.307-325
    • /
    • 2014
  • A newly developed method based on energy is presented to study the damage pattern of FRP material. Basalt fiber reinforced polymer (BFRP) is employed to monitor the damage under fatigue loading. In this study, acoustic emission technique (AE) combined with scanning electronic microscope (SEM) technique is employed to monitor the damage evolution of the BFRP specimen in an approximate continuous scanning way. The AE signals are analyzed based on the wavelet transform, and the analyses are confirmed by SEM images. Several damage patterns of BFRP material, such as matrix cracking, delamination, fiber fracture and their combinations, are identified through the experiment. According to the results, the cumulative energy (obtained from wavelet coefficients) of various damage patterns are closely related to the damage evolution of the BFRP specimens during the entire fatigue tests. It has been found that the proposed technique can effectively distinguish different damage patterns of FRP materials and describe the fatigue damage evolution.

열-나노임프린트 공정의 점탄성 유한요소해석 (A Viscoelasitc Finite Element Analysis of Thermal Nanoimprint Lithography Process)

  • 김남웅;김국원;신효철
    • 마이크로전자및패키징학회지
    • /
    • 제14권4호
    • /
    • pp.1-7
    • /
    • 2007
  • 최근 나노임프린트 리소그래피 공정이 마이크로/나노스케일의 소자 개발에 있어서 경제적으로 대량 생산할 수 있는 기술로 주목 받고 있다. 나노 스케일의 패턴을 성공적으로 전사하기 위해서는 폴리머의 기계적 거동에 대한 이해를 바탕으로, 적절한 공정 조건 즉, 압력, 온도, 시간 등의 선택이 필요하다. 본 연구에서는 열-나노임프린트 공정에서의 충전과정을 해석하기 위하여 비선형 유한요소법을 이용하였으며, 폴리머의 거동을 점탄성으로 가정하여 재료의 응력완화 효과를 고려하였다. 해석을 통하여 온도 및 몰드의 패턴형상이 열-나노임프린트 공정에 미치는 영향을 살펴보았다.

  • PDF

대량 맞춤 생산을 위한 공군 동약정복 바지 패턴 제도법 및 자동 제도 프로그램 개발 (Development of Air Force Winter Service Uniform Slacks Pattern and Automatic Pattern Drafting Program for Mass Customization)

  • 김인화;남윤자;김성민
    • 한국의류산업학회지
    • /
    • 제15권2호
    • /
    • pp.256-267
    • /
    • 2013
  • This study is conducted to improve the fitness of Air Force winter service uniforms pants through the development of a pants pattern drafting method and automatic pattern drafting program for mass customization. The initial study pattern drafting method is formed through an analyses of 4 kinds of conventional pants pattern drafting methods for education and 3 kinds of conventional pants patterns of Air Force apparels. The initial study pattern drafting method is converted into the final study pattern drafting method after twice conducting a wearing test. To verify the final study pants pattern, a motion adaptability evaluation, an ease amount evaluation and an appearance evaluation are conducted. The results of the final study patterns were better than conventional winter service uniforms in the motion adaptability evaluation and the appearance evaluation. However, the results show similar values between the final study patterns and conventional winter service uniform patterns in the ease amount evaluation. An automatic pattern drafting program was developed based on the final study pattern drafting method. The program allowed the achievement of customized pants patterns through the placement of customer body sizes into the size input window. It also provided two kinds of ease amount and two kinds of waist belt level options.

유리섬유/나일론 6 복합재료의 계면특성에 미치는 Chloropropyl 말단기를 가진 실란결합체 농도의 영향 (Concentration Effect of Silane Coupling Agents with Chloropropyl End Group on the Interfacial Characteristics of Glass/Nylon 6 Composites)

  • 조동환;윤숙향;방대석;김준경;임순호;박민
    • 접착 및 계면
    • /
    • 제5권1호
    • /
    • pp.21-28
    • /
    • 2004
  • 본 연구에서는 사슬말단에 chloropropyl 유기관능그룹을 가지고 있는 실란결합체인 3-chloropropyltrimethoxysilane(CTMS)을 사용하여 여러 농도에서 유리섬유 표면에 사이징 처리하여 유리섬유/나일론 6 및 유리직물/나이론 6 복합재료를 제조하였다. 단섬유 microbonding 시험에 의한 유리섬유/나일론 6 복합재료의 계면전단강도와 short-beam 전단시험과 동역학적 열특성 분석 방법을 통하여 유리직물/나일론 6 복합재료의 층간전단강도 및 저장탄성률에 미치는 결합체 농도의 영향을 각각 조사하였다. CTMS 결합제의 농도가 증가할수록 복합재료의 계면특성이 향상되었다. 결합제의 농도 변화에 대한 유리섬유강화 나일론 6 복합재료의 계면전단강도, 층간전단강도, 층간파단양상 그리고 저장탄성률 등 각 특성 변화의 경향이 서로 일치하였다.

  • PDF

이엽식 고분자판막의 수력학적 특성평가 및 동물실험 (In-vitro Evaluation of a Bileaflet Polymer Valve and Preliminary Animal Tests)

  • 김철생;박복춘;서수원;한동근;이규백;최진욱;김인영;김희찬;김영하
    • 대한의용생체공학회:의공학회지
    • /
    • 제13권3호
    • /
    • pp.225-234
    • /
    • 1992
  • In order to use a low cost polymer valve in our total artificial heart and ventricular assist device, we have developed a slit-type bileaflet polymer valve[BPV 1. The aim of this study is to determine the hydrodynamic effectiveness of the newly-designed BPV and its feasibility for temporary use in the blood pumps. For hydrodynamic comparison, we investigated in-vitro the pressure drop across the valve, the leakage volume, the flow rate and the flow pattern of the BPV, two mechanical valves and a trileaflet polymer valve. We employed the ventriculo-pulmonary bypassing method for in-vivo tests of the BPV's together vilh our electrohydraulic left venIn ricular assist device in mongrel dogs. The BPV showed adquate gydrodynamic performances and in the preliminary animal bests, there was no xvi dence of thrombus formation on the valve leaflets and around the struts. Detailed results obtained from the animal tests will be separately reported. This report involves the design criteria, fabrication and hydrodynamic charateristics of she BPV, and the basic merits and demerits of the valve are dis- cussed from the hydrodynamic point of view.

  • PDF

Chondrogenic Differentiation of Bone Marrow Stromal Cells in Transforming Growth $Factor-{\beta}_{1}$ Loaded Alginate Bead

  • Park, Ki-Suk;Jin Chae-Moon;Kim, Soon-Hee;Rhee John M.;Khang Gil-Son;Han, Chang-Whan;Yang, Yoon-Sun;Kim, Moon-Suk;Lee, Hai-Bang
    • Macromolecular Research
    • /
    • 제13권4호
    • /
    • pp.285-292
    • /
    • 2005
  • We developed alginate beads loaded with transforming growth $factor-{\beta}_{1}(TGF-{\beta}_{1})$ to examine the possible application of the scaffold and cytokine carrier in tissue engineering. In this study, bone marrow stromal cells (BMSCs) and $TGF{\beta}_{1}$ were uniformly encapsulated in the alginate beads and then cultured in vitro. The cell morphology and shape of the alginate beads were observed using inverted microscope, scanning electron microscope (SEM), histological staining and RT-PCR to confirm chondrogenic differentiation. The amount of the $TGF{\beta}_{1}$ released from the $TGF-{\beta}_{1}$ loaded alginate beads was analyzed for 28 days in vitro in a phosphate buffered saline (pH 7.4) at $37^{\circ}C$. We observed the release profile of $TGF-{\beta}_{1}$ from $TGF-{\beta}_{1}$ loaded alginate beads with a sustained release pattern for 35 days. Microscopic observation showed the open cell pore structure and abundant cells with a round morphology in the alginate beads. In addition, histology and RT-PCR results revealed the evidence of chondrogenic differentiation in the beads. In conclusion, these results confirmed that $TGF-{\beta}_{1}$ loaded alginate beads provide excellent conditions for chondrogenic differentiation.