• Title/Summary/Keyword: polymer pattern

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Development and Operation of 5kW-Class Polymer Electrolyte Membrane Fuel Cell System (5kW급 고분자 연료전지 시스템의 개발과 운전)

  • Chun, Y.G.;Peck, D.H.;Jeon, K.S.;Kim, C.S.;Shin, D.R.
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1876-1878
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    • 1999
  • Developed was a 5kW-class polymer electrolyte membrane fuel cell(PEMFC) system comprised of fuel cell stack, fuel processing, thermal and water management subsystems and ancillary equipments. Several large single cells have been fabricated with different gas flow field patterns and paths, and the gas flow field pattern for the stack has been determined based on the single cell performance of thin film membrane electrode assembly (MEA). The PEMFC stack was consisted of 100 cells with an electrode area of $300cm^2$, having serpentine flow pattern. Fuel processing was developed including an autothermal methanol reformer and two preferential CO oxidation reactors. The fuel processing was combined to PEMFC operation system consisted of air compressor and thermal and water management subsystems. The PEMFC stack showed performance of 5kW under the supply of $H_2$ and air, but its performance was lowered to 3.5kW under the supply of reformed gas.

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SU-8 Mold Fabrication with Low Internal Stress and High Aspect Ratio for UV LIGA Process (고 형상비 UV LIGA 공정을 위한 낮은 내부응력의 SU-8 도금틀 제작)

  • Jang, Hyeon-Gi;Kim, Yong-Gwon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.8
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    • pp.598-604
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    • 1999
  • This paper describes the research to minimize the film stress and maximize the aspect ratio of photoresist structure, especially about SU-8 for electroplating mold. UV LIGA process using SU-8 allows fabricating high aspect ratio polymer structures. However, it is hard to get fine patterns in the high aspect ratio structures because of high internal stress and difficulty of removing SU-8. The purpose of this paper is to setup the process condition for the obtainment of both low film stress and high aspect ratio and to find design rules that make the pattern be less dependent on stress problem. Firstly, the process of heat treatment and exposure of SU-8 are proposed. These two conditions control the amount of cross-linkage in polymer structure, which is the most important parameter of both pattern generation and remaining stress. Heat treatment is dealed with soft bake and post-exposure-bake. Temperature and time duration of each step are varied with heat treatment condition. Some test patterns are fabricated to evaluate the proposed process. Nickel electroplating is performed with the mold fabricated through the proposed process to confirm the SU-8 as a good electroplating mold.

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Electrochromic Pattern Formation by Photo Cross-linking Reaction of PEDOT Side Chains

  • Kim, Jeong-Hun;Kim, Yu-Na;Kim, Eun-Kyoung
    • Macromolecular Research
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    • v.17 no.10
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    • pp.791-796
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    • 2009
  • An electrochemically and photochemically polymerizable monomer, 2-((2,3-dihydrothieno[3,4-b] [1,4]dioxin-2-yl)methoxy)ethyl methacrylate (EDOT-EMA), was explored for patterning of poly(3,4-ethylenedioxythiophene) (PEDOT) via side chain cross-linking. The polymer from EDOT-EMA was deposited electrochemically to produce polymeric EDOT (PEDOT-EMA), which was directly photo-patterned by UV light as the side EMA groups of PEDOT-EMA were polymerized to give cross-linked EMA (PEDOT-PEMA). Absorption and FTIR studies of the UV-exposed film (PEDOT-PEMA) indicated that the photo-patterning mainly originated from the photo cross-linking of the methacrylates in the side-chain. After irradiation of the film, the conductivity of the irradiated area decreased from $5.6{\times}10^{-3}$ S/cm to $7.2{\times}10^{-4}$ S/cm, possibly due to bending of the conductive PEDOT channel as a result of the side chain cross-linking. The patterned film was applied to a solid state electrochromic (EC) cell to obtain micro-patterned EC cells with lines up to 5 ${\mu}m$ wide.

Interfacial Sensing and Evaluation of Carbon and SiC Fibers/Epoxy Composites with Different Embedding Angle using Electro-Micromechanical Technique (Electro-Micromechanical Technique을 이용한 각의 변화에 따른 Carbon과 SiC Fiber/Epoxy Composites의 계면감지능 및 평가)

  • Lee, Sang-Il;Kong, Jin-Woo;Park, Joung-Man
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.05a
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    • pp.199-202
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    • 2002
  • Interfacial properties and electrical sensing for fiber fracture in carbon and SiC fibers/epoxy composites were investigated by the electrical resistance measurement and fragmentation test. As fiber-embedded angle increased, interfacial shear strength (IFSS) of two-type fiber composites decreased, and the elapsed time was long to the infinity in electrical resistivity. The initial slope of electrical resistivity increased rapidly to the infinity at higher angle, whereas electrical resistivity increased gradually at small angle. Furthermore, both fiber composites with small embedded angle showed a fully-developed stress whitening pattern, whereas both composites with higher embedded angle exhibited a less developed stress whitening pattern. As embedded angle decreased, the gap between the fragments increased and the debonded length was wider for both fiber composites. Electro-micromechanical technique can be a feasible nondestructive evaluation to measure interfacial sensing properties depending on the fiber-embedded angle in conductive fiber reinforced composites.

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Fatigue damage monitoring and evolution for basalt fiber reinforced polymer materials

  • Li, Hui;Wang, Wentao;Zhou, Wensong
    • Smart Structures and Systems
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    • v.14 no.3
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    • pp.307-325
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    • 2014
  • A newly developed method based on energy is presented to study the damage pattern of FRP material. Basalt fiber reinforced polymer (BFRP) is employed to monitor the damage under fatigue loading. In this study, acoustic emission technique (AE) combined with scanning electronic microscope (SEM) technique is employed to monitor the damage evolution of the BFRP specimen in an approximate continuous scanning way. The AE signals are analyzed based on the wavelet transform, and the analyses are confirmed by SEM images. Several damage patterns of BFRP material, such as matrix cracking, delamination, fiber fracture and their combinations, are identified through the experiment. According to the results, the cumulative energy (obtained from wavelet coefficients) of various damage patterns are closely related to the damage evolution of the BFRP specimens during the entire fatigue tests. It has been found that the proposed technique can effectively distinguish different damage patterns of FRP materials and describe the fatigue damage evolution.

A Viscoelasitc Finite Element Analysis of Thermal Nanoimprint Lithography Process (열-나노임프린트 공정의 점탄성 유한요소해석)

  • Kim, Nam-Woong;Kim, Kug-Weon;Sin, Hyo-Chol
    • Journal of the Microelectronics and Packaging Society
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    • v.14 no.4
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    • pp.1-7
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    • 2007
  • Nanoimprint lithography (NIL) is an emerging technology enabling cost-effective and high-throughput nanofabrication. To successfully imprint a nano-sized pattern, the process conditions such as temperature, pressure, and time should be appropriately selected. This starts with a clear understanding of polymer material behavior during the NIL process. In this work, the squeezing of thin polymer films into nanocavities during the thermal NIL has been investigated based upon a two-dimensional viscoelastic finite element analysis in order to understand how the process conditions affect a pattern quality. The simulations have been performed within the viscoelastic plateau region and the stress relaxation effect has been taken into account.

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Development of Air Force Winter Service Uniform Slacks Pattern and Automatic Pattern Drafting Program for Mass Customization (대량 맞춤 생산을 위한 공군 동약정복 바지 패턴 제도법 및 자동 제도 프로그램 개발)

  • Kim, In Hwa;Nam, Yun Ja;Kim, Sung Min
    • Fashion & Textile Research Journal
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    • v.15 no.2
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    • pp.256-267
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    • 2013
  • This study is conducted to improve the fitness of Air Force winter service uniforms pants through the development of a pants pattern drafting method and automatic pattern drafting program for mass customization. The initial study pattern drafting method is formed through an analyses of 4 kinds of conventional pants pattern drafting methods for education and 3 kinds of conventional pants patterns of Air Force apparels. The initial study pattern drafting method is converted into the final study pattern drafting method after twice conducting a wearing test. To verify the final study pants pattern, a motion adaptability evaluation, an ease amount evaluation and an appearance evaluation are conducted. The results of the final study patterns were better than conventional winter service uniforms in the motion adaptability evaluation and the appearance evaluation. However, the results show similar values between the final study patterns and conventional winter service uniform patterns in the ease amount evaluation. An automatic pattern drafting program was developed based on the final study pattern drafting method. The program allowed the achievement of customized pants patterns through the placement of customer body sizes into the size input window. It also provided two kinds of ease amount and two kinds of waist belt level options.

Concentration Effect of Silane Coupling Agents with Chloropropyl End Group on the Interfacial Characteristics of Glass/Nylon 6 Composites (유리섬유/나일론 6 복합재료의 계면특성에 미치는 Chloropropyl 말단기를 가진 실란결합체 농도의 영향)

  • Cho, Donghwan;Yun, Suk Hyang;Bang, Dae-Suk;Kim, Junkyung;Lim, Soonho;Park, Min
    • Journal of Adhesion and Interface
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    • v.5 no.1
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    • pp.21-28
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    • 2004
  • In this work, glass fiber/nylon 6 and woven glass fiber/nylon 6 composites have been fabricated using glass fiber reinforcements sized with 3-chloropropyltrimethoxysilane(CTMS) having a chloropropyl organo-functional group in the molecular chain end. The interfacial shear strength of glass fiber/nylon 6 composite was measured using a single fiber microbonding test and the interlaminar shear strength and the storage modulus of woven glass fabric/nylon 6 composites were measured using a short-warn shear test and a dynamic mechanical analysis, respectively, informing the effect of the concentration of CTMS on the properties. With increasing CTMS concentration, the interfacial properties of the composites were improved. The results on the interfacial shear strength, interlaminar shear strength, interlaminar failure pattern, and storage modulus with varying the CTMS concentration agree with each other.

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In-vitro Evaluation of a Bileaflet Polymer Valve and Preliminary Animal Tests (이엽식 고분자판막의 수력학적 특성평가 및 동물실험)

  • 김철생;박복춘;서수원;한동근;이규백;최진욱;김인영;김희찬;김영하
    • Journal of Biomedical Engineering Research
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    • v.13 no.3
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    • pp.225-234
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    • 1992
  • In order to use a low cost polymer valve in our total artificial heart and ventricular assist device, we have developed a slit-type bileaflet polymer valve[BPV 1. The aim of this study is to determine the hydrodynamic effectiveness of the newly-designed BPV and its feasibility for temporary use in the blood pumps. For hydrodynamic comparison, we investigated in-vitro the pressure drop across the valve, the leakage volume, the flow rate and the flow pattern of the BPV, two mechanical valves and a trileaflet polymer valve. We employed the ventriculo-pulmonary bypassing method for in-vivo tests of the BPV's together vilh our electrohydraulic left venIn ricular assist device in mongrel dogs. The BPV showed adquate gydrodynamic performances and in the preliminary animal bests, there was no xvi dence of thrombus formation on the valve leaflets and around the struts. Detailed results obtained from the animal tests will be separately reported. This report involves the design criteria, fabrication and hydrodynamic charateristics of she BPV, and the basic merits and demerits of the valve are dis- cussed from the hydrodynamic point of view.

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Chondrogenic Differentiation of Bone Marrow Stromal Cells in Transforming Growth $Factor-{\beta}_{1}$ Loaded Alginate Bead

  • Park, Ki-Suk;Jin Chae-Moon;Kim, Soon-Hee;Rhee John M.;Khang Gil-Son;Han, Chang-Whan;Yang, Yoon-Sun;Kim, Moon-Suk;Lee, Hai-Bang
    • Macromolecular Research
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    • v.13 no.4
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    • pp.285-292
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    • 2005
  • We developed alginate beads loaded with transforming growth $factor-{\beta}_{1}(TGF-{\beta}_{1})$ to examine the possible application of the scaffold and cytokine carrier in tissue engineering. In this study, bone marrow stromal cells (BMSCs) and $TGF{\beta}_{1}$ were uniformly encapsulated in the alginate beads and then cultured in vitro. The cell morphology and shape of the alginate beads were observed using inverted microscope, scanning electron microscope (SEM), histological staining and RT-PCR to confirm chondrogenic differentiation. The amount of the $TGF{\beta}_{1}$ released from the $TGF-{\beta}_{1}$ loaded alginate beads was analyzed for 28 days in vitro in a phosphate buffered saline (pH 7.4) at $37^{\circ}C$. We observed the release profile of $TGF-{\beta}_{1}$ from $TGF-{\beta}_{1}$ loaded alginate beads with a sustained release pattern for 35 days. Microscopic observation showed the open cell pore structure and abundant cells with a round morphology in the alginate beads. In addition, histology and RT-PCR results revealed the evidence of chondrogenic differentiation in the beads. In conclusion, these results confirmed that $TGF-{\beta}_{1}$ loaded alginate beads provide excellent conditions for chondrogenic differentiation.