• Title/Summary/Keyword: polymer modification

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Manufacturing of Organic Light Emitting Display by Polymer Inkjet Printing

  • Kim, Myong-Ki;Shin, Kwon-Yong;Lee, Sang-Ho;Hwang, Jun-Young;Kang, Heui-Seok;Kang, Kyung-Tae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1476-1478
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    • 2009
  • The characteristics of polymer inkjet printing were investigated systematically in this paper. PEDOT/PSS as a hole injection layer and MEH-PPV as a light emitting layer were used for inkjet printing experiment. Inkjet head controlling technology and surface modification technology were also applied for polymer inkjet printing. With the developed polymer inkjet printing technology, OLED(Organic Light Emitting Display) was successfully fabricated and demonstrated.

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Enhanced Hydrophilicity of Polyethersulfone Membrane by Various Surface Modification Methods (다양한 표면개질을 이용한 폴리에테르설폰 막의 친수성 향상)

  • Park, So Jung;Hwang, Jun Seok;Choi, Won-Kil;Lee, Hyung Keun;Huh, Kang Moo
    • Polymer(Korea)
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    • v.38 no.2
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    • pp.205-212
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    • 2014
  • Polyethersulfone (PES) membranes were modified by various physico-chemical modification methods to enhance the surface hydrophilicity for application as a separation membrane to separate and collect water vapor from the flue gas. Homogeneous PES flat-sheet membranes were prepared and modified by acid treatment, blending and plasma treatment for hydrophilic surface modification. The surface characteristics of the modified PES membranes were evaluated by ATR-FTIR, XPS, SEM and contact angle measurements. No significant change in hydrophilicity was observed for the PES membranes modified by acid treatment with sulfuric acid or blending with various compositions of poloxamer as an amphiphilic PEO-PPO-PEO tri-block copolymer. On the other hand, Ar plasma treatment led to a significant increase in the hydrophilicity of the surface, depending on the plasma treatment time. As a result, the PES membrane could be the most efficiently surface-treated by applying the plasma treatment for enhancing their surface hydrophilicity.

Effect of polymer addition on air void content of fine grained concretes used in TRCC

  • Daskiran, Esma Gizem;Daskiran, Mehmet Mustafa;Gencoglu, Mustafa
    • Computers and Concrete
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    • v.20 no.2
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    • pp.165-176
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    • 2017
  • Textile Reinforced Cementitious Composite (TRCC) became the most common construction material lately and have excellent properties. TRCC can be employed in the manufacture of thin-walled facade elements, load-bearing integrated formwork, tunnel linings or in the strengthening of existing structures. These composite materials are a combination of matrix and textile materials. There isn't much research done about the usage of polymer modified matrices in textile reinforced cementitious composites. In this study, matrix materials named as fine grained concretes ($d_{max}{\leq}1.0mm$) were investigated. Air entraining effect of polymer modifiers were analyzed and air void content of fine grained concretes were identified with different methods. Aim of this research is to study the effect of polymer modification on the air content of fine grained concretes and the role of defoamer in controlling it. Polymer modifiers caused excessive air entrainment in all mixtures and defoamer material successfully lowered down the air content in all mixtures. Latex polymer modified mixtures had higher air content than redispersible powder modified ones. Air void analysis test was performed on selected mixtures. Air void parameters were compared with the values taken from air content meter. Close results were obtained with tests and air void analysis test found to be useful and applicable to fine grained concretes. Air void content in polymer modified matrix material used in TRCC found significant because of affecting mechanical and permeability parameters directly.

Microstructure Properties of High Strength Concrete Utilizing EVA with Micro Particles (EVA 마이크로 입자를 활용한 고강도 콘크리트의 미세구조특성)

  • Kim, Young-Ik;Sung, Chan-Yong
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.97-101
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    • 2005
  • High strength concretes utilizing EVA with micro particles were prepared by varying polymer/binder mass ratio and curing conditions with a constant water/binder mass ratio of 0.3. The EVA modified concretes on the compressive and flexural strength, microstructure, ultrapulse modulus in curing condition(dry and water curing) were studied. Also, scanning electron microscope analysis(SEM) was performed to reveal the presence of polymer film and cement hydrates in the concrete. The compressive strength of the EVA modified concretes cured at water conditions ere higher than that of the EVA modified concretes cured at dry conditions. But, the flexural strength of the specimens cured at dry conditions were higher than that of the specimens cured at water conditions. Due to the interaction of the cement hydrates and polymer film, an interpenetrating network originated in which the aggregates were embedded. The curing of the polymer modified concrete involves two step of cement hydrates and polymer modification, and cement hydrates was promoted in water conditions and polymer film formation take place when water evaporates and was thereby was favored in dry conditions. By SEM analysis, influences of polymer modification was strengthening of the transition zone between the aggregate and the paste, and the porosity of transition zone decreases. By spring analysis, it could known that polymer film affects in porosity decrease and strengthening of transition zone.

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Static Characteristic of Polyester Fiber by LT-Plasma Polymerization (저온플라즈마중합 처리한 폴리에스터 섬유의 대전특성)

  • 서은덕;강영립;박찬언
    • Textile Coloration and Finishing
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    • v.4 no.4
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    • pp.110-116
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    • 1992
  • For the modification of PET surface, Perfluoropropene and Methyl alcohol were LT-plasma polymerized on the PET fabrics as thin films by means of 13.56 MHz radio frequency generator. The surface properties of PET fabrics were modified from hydrophobic to hydrophilic by application of the postplasma reaction of thin films. The evidence of the modification was identified by observation of the presence of hydroxy group in IR spectrum and the evaluation of degree of hydrophilicity was performed by measuring frictional static voltage of PET fabric with cotton fabric. For the case of modification by PFP, the result performed at the condition of 25 W, 70 m torr has shown to be effective, and for MeOH, result performed at the condition of 25 W, 100 m torr effective. The effect of hydrophilic surface modification of MeOH plasma polymer was superior to that of PFP-plasma polymer.

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Physical Properties of Silicone Rubber/Clay Composites According to the Clay Type and Modification (Clay의 종류 및 표면처리가 silicone rubber/clay 복합체의 물성에 미치는 영향)

  • Yoon, Jin-San;Kim, Eung-Soo;Kim, Eun-Jeong;Lee, Tae-Hwa
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.260-268
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    • 2009
  • Modification of clay surface was attempted by treating the clay with bis[(3-triethoxysilylpropyl)tetra sulfide (TSS) to raise the hydrophobicity and to induce a chemical reaction between the clay and the high temperature vulcanization-type silicone rubber matrix with purpose of improving the compatibility between the components, and thereby Na-$MMTS_4$ and Fe-$MMTS_4$ were synthesized by treating Na-MMT and Fe-MMT with TSS, respectively. Silicone rubber/clay composites were prepared by compounding the clays with silicone rubber. Thermal stability and mechanical properties were evaluated as a function of the clay types and the surface modification.

Recent Advances in Polybenzimidazole (PBI)-based Polymer Electrolyte Membranes for High Temperature Fuel Cell Applications

  • Vijayakumar, Vijayalekshmi;Kim, Kihyun;Nam, Sang Yong
    • Applied Chemistry for Engineering
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    • v.30 no.6
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    • pp.643-651
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    • 2019
  • Polybenzimidazole (PBI), an engineering polymer with well-known excellent thermal, chemical and mechanical stabilities has been recognized as an alternative to high temperature polymer electrolyte membranes (HT-PEMs). This review focuses on recent advances made on the development of PBI-based HT-PEMs for fuel cell applications. PBI-based membranes discussed were prepared by various strategies such as structural modification, cross-linking, blending and organic-inorganic composites. In addition, intriguing properties of the PBI-based membranes as well as their fuel cell performances were highligted.

Polymer Surfaces for Cell Adhesion I. Surface Modification of Polymers and ESCA Analysis (세포적합성 고분자 표면에 관한 연구 I. 고분자 표면 개질과 ESCA 분석)

  • 이진호;강길선
    • Journal of Biomedical Engineering Research
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    • v.10 no.1
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    • pp.43-52
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    • 1989
  • We modified polymer surfaces, polyethylene, polystyrene and polyester, to improve cellcompatibility. For surface modification of the polymers, we used various surface treatment methods; physicochemical oxidation methods such as plasma discharge, corona discharge, sulfuric acid and chloric acid treatments, and biological methods such as adsorption of plasma protein and fibronectin onto the polymer surfaces. The treated polymer surfaces were characterized by electron spectroscopy for chemical analysis ( ESCA ). The physicochemically treated polymers showed different surface chemical structures depending on the treated methods. The sulfuric acid-treated surfaces showed greater carboxyl groups than those of plasma- or corona- treated surfaces, while the chloric acid-treated one showed high density of hydroxyl group on the surface. By the biological treatments, the surfaces were uniformly coated with proteins. The fibronectin adsorbed on the surface seems to have unique properties for cell binding.

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