• 제목/요약/키워드: polymer mechanics

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Resistance of concrete made of fibers in weight lifting slabs against impact in sports training

  • Zhi Li
    • Structural Engineering and Mechanics
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    • 제86권3호
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    • pp.325-336
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    • 2023
  • A significant component of many civil constructions such as buildings, reservoirs, bridges, and sports halls, concrete has become increasingly popular due to its versatile properties. Concrete's internal characteristics change due to the use of different types of fibers, including changes in its microstructure, volume, and hole dimensions. Additionally, the type, dimensions, and distribution of fibers in concrete can affect the results of flexural strength tests by affecting its compressive and tensile strength. Due to a lack of information, fiber concrete is a new composite material in the production industry that requires laboratory studies to determine its behavior. This study investigated the bending behavior of multilayer slabs made of concrete reinforced by polyamide-propylene fibers against impact in weight lifting exercises. Results showed that adding fibers to concrete slab samples improved the mechanical properties while replacing them hurt the mechanical properties and failure of polymer fiber-reinforced concrete. On the other hand, adding and replacing fibers increases durability and has a positive effect.

EPDM/PP/Ionomer 삼원 블렌드로 된 열가소성 가황체의 파괴 인성 (Fracture Toughness of the Thermoplastic Vulcanizates from EPDM/PP/Ionomer Ternary Blends)

  • 김영규;조원제;하창식;고진환
    • Elastomers and Composites
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    • 제31권5호
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    • pp.341-346
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    • 1996
  • The fracture mechanics investigation of the thermoplastic vulcanizates(TPV) from EPDM and PP/Ionomer ternary blends was performed in terms of the J-integral by measuring fracture energy via the locus method. The TPV from ternary blends consisting of EPDM, PP and ionomer were prepared in a laboratory integral mixer by blending and vulcanizing simultaneously. Vulcanization was performed with dicumyl peroxide (DCP) and the composition of EPDM and PP was fixed at 50/50 by weight. Two kinds of poly(ethylene-co-methacrylic acid) (EMA) lonomers were used. The J-integral values at crack initiation, Jc, of the dynamically vulcanized EPDM and PP/EMA Ionomer ternary blends were affected by the cation types $(Na^+\;or\;Zn^{2+})$ and contents(5-20wt%) of the added EMA Ionomers. The ternary blend containing 20wt% zinc-neutralized EMA Ionomer and 1.0phr DCP showed the highest Jc values of the blends.

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Molecular Modeling of Bisphenol-A Polycarbonate and Tetramethyl Bisphenol-A Polycarbonate

  • Kim, Sangil;Juwhan Liu
    • Macromolecular Research
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    • 제9권3호
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    • pp.129-142
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    • 2001
  • To efficiently demonstrate the molecular motion, physical properties, and mechanical properties of polycarbonates, we studied the differences between bisphenol-A polycarbonate(BPA-PC) and tetramethyl bisphenol-A-polycarbonate(TMBPA-PC) using molecular modeling techniques. To investigate the conformations of BPA-PC and TMBPA-PC and the effect of the conformation on mechanical properties, we performed conformational energy calculation, molecular dynamics calculation, and stress-strain curves based on molecular mechanics method. From the result obtained from conformational energy calculations of each segment, the molecular motions of the carbonate and the phenylene group in BPA-PC were seen to be more vigorous and have lower restriction to mobility than those in TMBPA-PC, respectively. In addition, from the results of radial distribution function, velocity autocorrelation function, and power spectrum, BPA-PC appeared to have higher diffusion constant than TMBPA-PC and is easier to have various conformations because of the less severe restrictions in molecular motion. The result of stress-strain calculation for TMBPA-PC seemed to be in accordance with the experimental value of strain-to-failure ∼4%. From these results of conformational energy calculations of segments, molecular dynamics, and mechanical properties, it can be concluded that TMBPA-PC has higher modulus and brittleness than BPA-PC because the former has no efficient relaxation mode against the external deformations.

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Solvent Effects on the Structure of Resorcinol Formaldehyde Resin

  • Park, Sung-Seen
    • Macromolecular Research
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    • 제8권2호
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    • pp.53-58
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    • 2000
  • Stabilities and structures of resorcinol formaldehyde resins (RF resins) and their dependence on solvent were studied by molecular mechanics and molecular dynamics. Dimers to decamers of the RF resins in the conditions of dielectric constant = 1.00, 21.01, 36.64, and 80.10 were calculated. The average distance between oxygen atoms in 1-hydroxyl groups of adjacent resorcinols of the resins became longer with increased dielectric constant of the environment. The number of intramolecular hydrogen bonds of the resins decreased by increasing the dielectric constant of the environment. The RF resin structure on the surface of fabric or steel cord was explained based on the present calculation.

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Rate-Dependence of Off-Axis Tensile Behavior of Cross-Ply CFRP Laminates at Elevated Temperature and Its Simulation

  • Takeuchi, Fumi;Kawai, Masamichi;Zhang, Jian-Qi;Matsuda, Tetsuya
    • Advanced Composite Materials
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    • 제17권1호
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    • pp.57-73
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    • 2008
  • The present paper focuses on experimental verification of the ply-by-ply basis inelastic analysis of multidirectional laminates. First of all, rate dependence of the tensile behavior of balanced symmetric cross-ply T800H/epoxy laminates with a $[0/90]_{3S}$ lay-up under off-axis loading conditions at $100^{\circ}C$ is examined. Uniaxial tension tests are performed on plain coupon specimens with various fiber orientations $[{\theta}/(90-{\theta})]_{3S}$ ($\theta$ = 0, 5, 15, 45 and $90^{\circ}C$) at two different strain rates (1.0 and 0.01%/min). The off-axis stress.strain curves exhibit marked nonlinearity for all the off-axis fiber orientations except for the on-axis fiber orientations $\theta$ = 0 and $90^{\circ}$, regardless of the strain rates. Strain rate has significant influences not only on the off-axis flow stress in the regime of nonlinear response but also on the apparent off-axis elastic modulus in the regime of initial linear response. A macromechanical constitutive model based on a ply viscoplasticity model and the classical laminated plate theory is applied to predictions of the rate-dependent off-axis nonlinear behavior of the cross-ply CFRP laminate. The material constants involved by the ply viscoplasticity model are identified on the basis of the experimental results on the unidirectional laminate of the same carbon/epoxy system. It is demonstrated that good agreements between the predicted and observed results are obtained by taking account of the fiber rotation induced by deformation as well as the rate dependence of the initial Young's moduli.

Stereo-digital image correlation in the behavior investigation of CFRP-steel composite members

  • Dai, Yun-Tong;Wang, Hai-Tao;Ge, Tian-Yuan;Wu, Gang;Wan, Jian-Xiao;Cao, Shuang-Yin;Yang, Fu-Jun;He, Xiao-Yuan
    • Steel and Composite Structures
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    • 제23권6호
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    • pp.727-736
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    • 2017
  • The application of carbon fiber reinforced polymer (CFRP) in steel structures primarily includes two categories, i.e., the bond-critical application and the contact-critical application. Debonding failure and buckling failure are the main failure modes for these two applications. Conventional electrometric techniques may not provide precise results because of the limitations associated with single-point contact measurements. A nondestructive full-field measurement technique is a valuable alternative to conventional methods. In this study, the digital image correlation (DIC) technique was adopted to investigate the bond behavior and buckling behavior of CFRP-steel composite members. The CFRP-to-steel bonded joint and the CFRP-strengthened square hollow section (SHS) steel column were tested to verify the suitability of the DIC technique. The stereo-DIC technique was utilized to measure continuous deformation. The bond-slip relationship of the CFRP-to-steel interface was derived using the DIC data. Additionally, a multi-camera DIC system consisting of four stereo-DIC subsystems was proposed and applied to the compressive test of CFRP-strengthened SHS steel column. The precise buckling location and CFRP delamination of the CFRP-strengthened SHS steel column were identified. The experimental results confirm that the stereo-DIC technique can provide effective measurements for investigating the behaviors of CFRP-steel composite members.

금속선 광 도파로를 이용한 장거리 표면-플라즈몬 파장가변 필터 (Tunable Wavelength Filters Based on Long-Range Surface-Plasmon-Polariton waveguides)

  • 김기철;송석호;원형식;이관수
    • 한국광학회지
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    • 제17권4호
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    • pp.371-380
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    • 2006
  • 금으로 된 금속선 광 도파로를 따라 속박되는 장거리 표면 플라즈몬을 이용하여 파장 가변 필터를 설계하고 제작하였다. 실리콘 기판 위에 제작된 금속선 도파로는 두 층의 열광학 폴리머 사이에 샌드위치 구조로 끼어 있도록 설계되었다. 도파로의 바로 윗면에는 유전체로 된 Bragg 회절격자가 적합한 주기로 제작되어, 중심 파장이 광통신 파장대 (1520$\sim$1570 nm)에 있으면서 높은 소광률($\sim$25 dB)을 갖는 파의 반사가 가능했고, 전체손실은 25 dB/cm 이하로 나타났다. 또한, 제작된 파장 가변 필터가 폴리머의 열-광학적 특성에 의해 파장가변 필터 소자로서의 응용이 가능함을 확인했으며, 금속선 광 도파로에 직접 연결된 전극 구조에 동시에 가해준 전류에 의해 파장이 가변 될 수 있음을 실험적으로 확인하였다.

Modelling of tension-stiffening in bending RC elements based on equivalent stiffness of the rebar

  • Torres, Lluis;Barris, Cristina;Kaklauskas, Gintaris;Gribniak, Viktor
    • Structural Engineering and Mechanics
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    • 제53권5호
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    • pp.997-1016
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    • 2015
  • The contribution of tensioned concrete between cracks (tension-stiffening) cannot be ignored when analysing deformation of reinforced concrete elements. The tension-stiffening effect is crucial when it comes to adequately estimating the load-deformation response of steel reinforced concrete and the more recently appeared fibre reinforced polymer (FRP) reinforced concrete. This paper presents a unified methodology for numerical modelling of the tension-stiffening effect in steel as well as FRP reinforced flexural members using the concept of equivalent deformation modulus and the smeared crack approach to obtain a modified stress-strain relation of the reinforcement. A closed-form solution for the equivalent secant modulus of deformation of the tensioned reinforcement is proposed for rectangular sections taking the Eurocode 2 curvature prediction technique as the reference. Using equations based on general principles of structural mechanics, the main influencing parameters are obtained. It is found that the ratio between the equivalent stiffness and the initial stiffness basically depends on the product of the modular ratio and reinforcement ratio ($n{\rho}$), the effective-to-total depth ratio (d/h), and the level of loading. The proposed methodology is adequate for numerical modelling of tension-stiffening for different FRP and steel reinforcement, under both service and ultimate conditions. Comparison of the predicted and experimental data obtained by the authors indicates that the proposed methodology is capable to adequately model the tension-stiffening effect in beams reinforced with FRP or steel bars within wide range of loading.

Investigation of a fiber reinforced polymer composite tube by two way coupling fluid-structure interaction

  • Daricik, Fatih;Canbolat, Gokhan;Koru, Murat
    • Coupled systems mechanics
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    • 제11권4호
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    • pp.315-333
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    • 2022
  • Fluid-Structure Interaction (FSI) modeling is highly effective to reveal deformations, fatigue failures, and stresses on a solid domain caused by the fluid flow. Mechanical properties of the solid structures and the thermophysical properties of fluids can change under different operating conditions. In this study, we investigated the interaction of [45/-45]2 wounded composite tubes with the fluid flows suddenly pressurized to 5 Bar, 10 Bar, and 15 Bar at the ambient temperatures of 24℃, 66℃, and 82℃, respectively. Numerical analyzes were performed under each temperature and pressure condition and the results were compared depending on the time in a period and along the length of the tube. The main purpose of this study is to present the effects of the variations in fluid characteristics by temperature and pressure on the structural response. The variation of the thermophysical properties of the fluid directly affects the deformation and stress in the material due to the Wall Shear Stress (WSS) generated by the fluid flow. The increase or decrease in WSS directly affected the deformations. Results show that the increase in deformation is more than 50% between 5 Bar and 10 Bar for the same operating condition and it is more than 100% between 5 Bar and 15 Bar by the increase in pressure, as expected in terms of the solid mechanics. In the case of the increase in the temperature of fluid and ambient, the WSS and Von Mises stress decrease while the slight increases of deformations take place on the tube. On the other hand, two-way FSI modeling is needed to observe the effects of hydraulic shock and developing flow on the structural response of composite tubes.

Effect of aggregation on shear and elongational flow properties of acrylic thickeners

  • Willenbacher, N.;Matter, Y.;Gubaydullin, I.;Schaedler, V.
    • Korea-Australia Rheology Journal
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    • 제20권3호
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    • pp.109-116
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    • 2008
  • The effect of intermolecular aggregation induced by hydrophobic and electrostatic interactions on shear and elongational flow properties of aqueous acrylic thickener solutions is discussed. Complex shear modulus is determined at frequencies up to $10^4$ rad/s employing oscillatory squeeze flow. Extensional flow behavior is characterized using Capillary Break-up Extensional Rheometry. Aqueous solutions of poly(acrylic acid)(PAA)/poly(vinylpyrrolidone-co-vinylimidazole) (PVP-VI) mixtures exhibit unusual rheological properties described here for the first time. Zero-shear viscosity of the mixtures increases with decreasing pH and can exceed that of the pure polymers in solution by more than two orders of magnitude. This is attributed to the formation of complexes induced by electrostatic interactions in the pH range, where both polymers are oppositely charged. PAA/PVP-VI mixtures are compared to the commercial thickener Sterocoll FD (BASF SE), which is a statistical co-polymer including (meth) acrylic acid and ethylacrylate (EA) forming aggregates in solution due to "sticky" contacts among hydrophobic EA-sequences. PAA/PVP-VI complexes are less compact and more deformable than the hydrophobic Sterocoll FD aggregates. Solutions of PAA/PVP-VI exhibit a higher zero-shear viscosity even at lower molecular weight of the aggregates, but are strongly shear-thinning in contrast to the weakly shear-thinning solutions of Sterocoll FD. The higher ratio of characteristic relaxation times in shear and elongation determined for PAA/PVP-VI compared to Sterocoll FD solutions reflects, that the charge-induced complexes provide a much stronger resistance to extensional flow than the aggregates formed by hydrophobic interactions. This is most likely due to a break-up of the latter in extensional flow, while there is no evidence for a break-up of complexes for PAA/PVP-VI mixtures. These flexible aggregates are more suitable for the stabilization of thin filaments in extensional flows.