• Title/Summary/Keyword: polymer material

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Ion Gel Gate Dielectrics for Polymer Non-volatile Transistor Memories (이온젤 전해질 절연체 기반 고분자 비휘발성 메모리 트랜지스터)

  • Cho, Boeun;Kang, Moon Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.12
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    • pp.759-763
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    • 2016
  • We demonstrate the utilization of ion gel gate dielectrics for operating non-volatile transistor memory devices based on polymer semiconductor thin films. The gating process in typical electrolyte-gated polymer transistors occurs upon the penetration and escape of ionic components into the active channel layer, which dopes and dedopes the polymer film, respectively. Therefore, by controlling doping and dedoping processes, electrical current signals through the polymer film can be memorized and erased over a period of time, which constitutes the transistor-type memory devices. It was found that increasing the thickness of polymer films can enhance the memory performance of device including (i) the current signal ratio between its memorized state and erased state and (ii) the retention time of the signal.

A Study on Electrochemical Properties of Acrylate-based Gel Polymer Electrolyte with Ethylene Oxide Group (Ethylene Oxide기를 갖는 Acrylate계 Gel Polymer Electrolyte의 전기화학적 특성에 관한 연구)

  • Kim, Hyun-Soo;Shin, Jung-Han;Moon, Seong-In;Oh, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.6
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    • pp.608-614
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    • 2004
  • The gel polymer electrolyte was prepared by radical polymerization using tetra(ethylene glycol) diacrylate and tri(ethylene glycol) dimethacrylate to investigate affect of the number of ethylene oxide. The gel polymer electrolyte showed good electrochemical stability up to 4.5 V vs. Li/Li and high ionic conductivity at various temperatures. The lithium-ion polymer batteries with the gel polymer electrolyte, tetra(ethylene glycol) diacrylate- and tri(ethylene glycol) dimethacrylate-based, also represented good electrochemical performances such as rate capability, low-temperature performances and cycleability. However, the cell with tri(ethylene glycol) dimethacrylate, which has three ethylene oxide, showed better electrochemical performance.

A Case Study of Paraffin Double-walled Microencapsulation Preparation Using Acrylic Polymer and Melamine Polymer for Thermal Energy Storage

  • Nguyen, Hang Vo-Minh;Kim, Chae-Hyun;Kim, Jong-Kuk
    • Journal of the Korean Solar Energy Society
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    • v.39 no.5
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    • pp.65-78
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    • 2019
  • In this study, we investigated the paraffin encapsulation using double-walled encapsulation technique. The first encapsulation used methyl methacrylic acid as the main component in acrylic polymer and the second encapsulation used melamine polymer. Particles size and distribution of the capsules were analyzed using scanning electron microscopy. In the first encapsulation, the stable capsules were obtained at 67% of phase change material ratio to methyl methacrylic acid monomer and the size of the capsule was from 0.2 to $0.3{\mu}m$. In the second encapsulation, the size of the capsules was almost the same with those capsules prepared in the first encapsulation. The particle size of single wall and double wall was about $0.3{\mu}m$. As a result of the encapsulation of paraffin using double-walled encapsulation technique, it was confirmed that the particle size was determined in the process of encapsulating using the acrylic polymer at the first wall material, and the physical and thermal stability of the capsules were imparted using melamine at the secondary wall material.

Tension Creep Model of Recycled PET Polymer Concrete with Flexural Loading (휨 하중을 받는 재생 PET 폴리머 콘크리트의 인장크리프 모델)

  • Chae, Young-Suk;Tae, Ghi-Ho
    • Journal of the Korean Society of Safety
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    • v.27 no.5
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    • pp.117-125
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    • 2012
  • In recent years, polymer concrete based on polyester resin have been widely generalized and the research of polymer concrete have been actively pursued by the technical innovations. Polymer concrete is a composite consisting of aggregates and an organic resin binder that hardens by polymerization. Polymer concrete are stronger by a factor of three or more in compression, a factor of four to six in tension and flexural and a factor of two in impact when compared with portland cement concrete. In view of the growing use of polymer concrete, it is important to study the physical characteristics of the material, emphasizing the short term properties as well as long term mechanical behavior. If polymer concrete is to be used in flexural load-bearing application such as in beam, it is imperative to understand the deformation of the material under sustained loading conditions. This study is proposed to empirical and mechanical model of polymer concrete tension creep using long-term experimental results and mathematical development. The test results showed that proposed model has been used successfully to predict creep deformations at a stress level that was 20 percent of the ultimate strength and viscoelastic behavior of recycled-PET polymer concrete is linear of stress level up to 30 percent. It is expected that the present model allows more realistic evaluation of varying stresses in polymer concrete structures with a constant loading.

Relation between Huggins Constant and Compatibility of Binary Polymer Mixtures in the Aqueous Ternary Systems

  • Isamu Inamura;Makoto Kittaka;Tatsuya Aikou;Kazuhiko Akiyama;Tomoyuki Matsuyama;Masatsugu Hiroto;Hirade, Ken-ichi;Yuji Jinbo
    • Macromolecular Research
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    • v.12 no.2
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    • pp.246-250
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    • 2004
  • We have classified a number of aqueous ternary systems containing two different polymers into three types by focusing on the deviation of the Huggins constant k'from the additivity line. Systems of type I have negative deviations of k'; the repulsive interaction between the two different polymers dominates. In systems of type II, k' almost follows the additivity relation; the repulsive and attractive interactions between the two different polymers are balancing. Type III systems have positive deviations of k'; the attractive interactions are relatively dominant. This classification of systems is supported by the fact that the positive and negative deviations of k' from the additivity line also correspond to the sign of interaction parameter between polymer 2 and 3, Δb$\_$23/. Furthermore, we have verified the relatively high compatibility between dextran and poly(vinyl alcohol) by determining the binodal concentration of a liquid-liquid phase separation for a water/dextran/poly(vinyl alcohol) system, which is classified as type III. Thus, we found that the compositional dependence of k' closely relates to the compatibility of binary polymer mixtures in aqueous ternary systems.

Ethanol Gas Sensing Characteristics of Conducting Polymer Sensor Using Impedance (Impedance를 이용한 전도성고분자 센서의 에탄올 가스 감응특성)

  • Lee, Kyung-Mun;Yu, Joon-Boo;Jun, Hee-Kwon;Lee, Byung-Soo;Lee, Duk-Dong;Huh, Jeung-Soo
    • Korean Journal of Materials Research
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    • v.13 no.3
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    • pp.155-159
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    • 2003
  • The polypyrrole and polyaniline thin film sensors which were made by chemical polymerization were employed to detect ethanol gas. With a single sensor element we can obtain characteristic patterns of behaviour across a very wide frequency range when measuring either resistance or capacitance. Impedance spectroscopy was employed to study the gas sensing behavior of both capacitance and resistance based sensors with conducting polymer as the active sensing element.

Process for the Preparation of Conducting Polymer Composites (I) : Effect of the Porosity on the Conductivity (전도성 고분자 복합체 제조를 위한 신합성 연구 (I) : 다공성정도가 전도성 고분자 복합체의 전도도에 미치는 영향)

  • Son, Suk-Hye;Park, Young-Jun;Kim, Jung-Hyun
    • Applied Chemistry for Engineering
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    • v.7 no.2
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    • pp.393-400
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    • 1996
  • The conducting polymer composites were prepared by imbibing the porous particle with an $FeCl_3$ oxidant solution, drying the imbibed porous particle, and imbibing again with pyrrole solution for polymerization to take place in the pore. The conductivity of the porous composite particles, was higher than that of nonporous particles. Also, the conductivity of composite was increased with increasing specific surface area and pore specific volume of the host porous particles since the degree of formation of conducting polymer in the pore increased.

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A Study on Multi-Vehicle Control of Electro Active Polymer Actuator based on Embedded System using Adaptive Fuzzy Controller (Adaptive Fuzzy 제어기를 이용한 Embedded 시스템 기반의 기능성 고분자 구동체의 이중제어에 관한 연구)

  • 김태형;김훈모
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.307-310
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    • 1997
  • In case of environment requiring safety such as human body and requiring flexible shape, a conventional mechanical actuator system does not satisfy requirement. Therefore, in order to solve this problem, a research of various smart material such as EAP (Electro Active Polymer), EAC (Electro Active Ceramic) and SMA (Shape Memory Alloy) is in progress. Recently, the highest preferring material among various smart material is EP (Electrostictive Polymer), because it has very fast response time, poerful force and large displacement. The previous researches have been studied properties of polymer and simple control, but present researches are studied a polymer actuator. An EP (Electostrictive Polymer) actuator has properties which change variably as shape and environmental condition. Therefore, in order to coincide with a user's purpose, it is important not only to decide a shape of actuator and mechanical design but also to investigate a efficient controller. In this paper, we constructed the control logic with an adaptive fuvy algorithm which depends on the physical properties of EP that has a dielectric constant depending on time.

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Electrochemical Properties of $LiMnO_2$ Cathode as a Function of Addition of Electric Active Materials for Lithium Polymer Batteries (리튬 폴리머 전지용 $LiMnO_2$정극의 도전재에 따른 전기 화학적 특성)

  • 조영재;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.474-477
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    • 2001
  • The properties of LiMnO$_2$ was studied as a cathode active material for lithium polymer batteries. LiMnO$_2$ cathode active materials were synthesized by the reaction of LiOH . $H_2O$ and Mn$_2$O$_3$at various temperature under argon atmosphere. For lithium polymer battery applications, the LiMnO$_2$cell was characterized electrochemically by charge-discharge experiments and a.c. impedance spectroscopy. And the relationship between the characteristics of powders and electrochemical properties was studied in this research. A maximum discharge capacity of 160-170 mAh/g for ο-LiMnO$_2$ cell was achieved. Used that SP270 as electric active material in LiMnO$_2$, it is excellent than property of electric active material used Acetylene black or KS6 at charge/discharge capacity.

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Influences of Core Materials during Impact The Bulging Behavior of Sleeved Polymer Projectiles (슬리브드 폴리머 발사체의 충격시 벌징 거동 패턴에 미치는 코어 재료의 영향)

  • Shin, Hyung-Seop;Park, Sung-Taek;Jung, Yoon-Chul
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.198-203
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    • 2008
  • In the present study, the deformation behavior of both of metal and polymer combination on impact was investigated. They have showed a different deformation behavior when the co-axially combined projectile was impacted on rigid target. The theory according to Taylor's simplified approach assumes an ideally rigid-plastic material model exhibiting rate-independent behavior and simple one-dimensional wave propagation concepts that neglect radial inertia. In the case of impact with polymeric materials, elastic strain in general are not negligible compared with plastic strain; and the rigid-plastic material behavior assumed by Taylor for metallic materials cannot be applied any more. Since, the sleeve and the core materials have widely different mechanical properties, they will produce a significant difference of mechanical impedance with each other. Therefore these impedance mismatch influences on the deformation behavior sleeved polymer projectile on impact. As a result, sleeved projectiles will generate a very interesting impact behavior. Therefore, the according to sleeved metal material and core polymer material can see expected. The objective of this study was to investigate the factors which influences on deformation behavior pattern of sleeve materials surface.

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