• Proceedings of the Korea Concrete Institute Conference
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• 1996.10a
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• pp.358-365
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• 1996

Lightweight foamed concrete is a concrete which is lighter than normal concrete by mixing prefoamed foam in cement slurry. The objective of this study are to develop prefoamed optimal lightweight foamed concrete using polymer foam agent and to obtain its mechanical characteristics experimentally. This paper presents extensive test data on young's modulus, poisson's ratio, stress-strain curve, the characteristics of strength of the foamed concrete and also presents the mechanical characteristics of the foamed concrete according to foam sizes.

• Composites Research
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• v.31 no.4
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• pp.133-138
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• 2018

Polymer foams were used to fill the void in the structure in addition to flame retardant and heat insulation. Polymer foams such as polyurethane, polyisocyanurate, poly(vinyl chloride), polyethylene terephthalate were used to weight lighting materials. In this study, epoxy foam was used to improve mechanical properties of polymer foam. Acid anhydride type hardener reacts with polyol. Using this phenomenon, if blowing agent was added into epoxy resin using acid anhydride type hardener, formation and compressive properties of epoxy foam was studied. Formation of polymer foam was compared with type of blowing agent and concentration of blowing agent via compressive test. As these results, optimized condition of epoxy foam was found and epoxy foam had better compressive property than other polymer foam.

• Journal of Adhesion and Interface
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• v.13 no.4
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• pp.163-170
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• 2012

Although ${\beta}$-cyclodextrin (${\beta}$-CD) has been used as medicine, agrichemical, food, cosmetic, antioxidant, anti-volatile agent, anti-hygroscopic agent, fading-protecting agent, and emulsifier due to its ability to form inclusion complex by enclosing another molecule (guest molecule), it has been restricted in practical application because of its low solubility in water and organic solvent. In this study, ${\beta}$-CD derivative as a new polyol with inclusion characteristics against Bisphenol A and cyclopropane, foaming agent for polyurethane (PU), and with improved solubility was synthesized, characterized and used to formulate rigid PU foam with better thermal conductivity and compressive strength compared to that from commercial polyols.

• Magazine of the Korea Concrete Institute
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• v.9 no.1
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• pp.165-172
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• 1997

Lightweight foamed concrete is a concrete which is lighter than conventional concree by mixing ptetoamed foam in cement slurry. The objectives of this study are to develop optimal prefoarneti lightweight foamed concrete with high lightness. high flowability and enough strength fol special use of structural application by using the polymer foam agent. By mixing the admixtures such as silica-fume and fly-ash and the industrial by-product such as styrofoam for the purpose of practical use of industrial waste, lightweight foamed concrete shich has better lightness. flowability and strength than the conventional prefoamed lightweight foamed concrete is developed. This paper presents extensive data on characteristics of compressive strength and flowability of the concrete manufactured with the different factors in mix design and also presents optimum mix proportion.

• Polymer(Korea)
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• v.26 no.6
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• pp.759-766
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• 2002

Regular, spherical and isotropic open-microcellular foams having low density were prepared by the high internal phase emulsion (HIPE) polymerization mainly composed of styrene monomer and water The effects of Polymerization conditions. such as the content of water, divinylbenzene as a crosslinking agent and dodecane as a chain transfer agent, were investigated based on the tell size and foam properties. The microstructural morphology was observed using scanning electron microscopy (SEM) and the compression modulus of the foam was evaluated using compression test. The dropwise feeding of the aqueous phase into the oil phase was more effective than the batch feeding in producing the uniform and stable foam. Agitation speed and surfactant strongly influenced on the cell size and the window size between water droplets. Introduction of chain transfer agent increased the cell size, whereas it decreased the window size. Compression modulus increased with the crosslinking agent, but decreased with the chain transfer agent.

• Magazine of the Korea Concrete Institute
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• v.9 no.1
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• pp.173-181
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• 1997

The objective of this study is to obtain the mechanical characteristics of prefoarmed lightweight foamed concrete using the polymer ham agent which has high lightness. flowability and strength. For this purpose, the prefoarmed lightweight foamed concrete which was developed to have flow value over 180mm. unit weight between 0.38t/$m^3$ and 0.64t/$m^3$, and compressive strength about 30kg/$cm^2$ was used. This paper presents extensive test data on Young's modulus. Poisson's ratio, stress-strain curve, the characteristics of strength of the foamed concrete and also presents the mechanical characteristics of the foamed concrete with different foam sizes. It is expected that this study provides an importance guide to design and manufacture lightweight foam concrete, so that it helps to expand its structural use.

• Polymer(Korea)
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• v.24 no.4
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• pp.538-544
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• 2000

The characteristics of cell growth and foamed cell structures of PP were investigated by a continuous foaming process. The operating parameters were the contents of blowing agent and nucleating agent, nucleating agent contents, die temperatures and die dimensions. The foaming cells grew without collapse at less than 14.5 wt% of blowing agent, isopentane. But the cells were collapsed when the blowing agent content was more than 14.5 wt%. The foam density dramatically decreased when a very small amount of the nucleating agent, 1 wt%, was added. After the nucleating agent was added, the cell's weight plummeted to one-seventh of its previous weight. Stable foam cell structures were formed at the die temperature of 17$0^{\circ}C$. However, the effects of the pressure drop rate on the cell morphology were not serious.

• Macromolecular Research
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• v.16 no.3
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• pp.218-223
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• 2008

In order to obtain crosslinked poly(butylene succinate) (PBS) foams with a closed-cell structure, a commercial-grade PBS was first modified in the melt using two different branching agents to increase the melt viscosity. The rheological properties of the branched and crosslinked PBS were examined by varying the amount of the branching agents. The complex viscosity of the crosslinked PBS increased with increasing amount of the branching agent. However, it decreased with increasing frequency. When 2 phr of the branching agent was added to PBS, the storage modulus (G') was higher than the loss modulus (G") throughout the entire frequency range, showing that the addition of a branching agent increases the melt viscosity and elasticity of PBS effectively. Closed-cell PBS foams were prepared by mixing the chemical blowing agent with the crosslinked PBS. The effect of the foaming conditions such as temperature and time, and the amount of the crosslinking agent on the structure of the expanded PBS foams were also investigated.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.06a
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• pp.1367-1370
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• 2005

Microcellular foam processing of polymers requires a nucleated cell density greater than $10^9\;cells/cm^3$ so that the fully grown cells are smaller than 10 mm. A microcellular foam can be developed by first saturating a polymer sample with a volatile blowing agent, followed by rapidly decreasing its solubility in the polymer. In general, the cellular structure of crystalline polymer foams is difficult to control, compared to that of amorphous polymer foams. Since the gas does not dissolved in the crystallites, the polymer/gas solution formed during the microcellular processing is nonuniform. Moreover, the bubble nucleation is nonhomogeneous because of the heterogeneous nature of the crystalline polymer. In this paper, the effects of the crystallinity and morphology of crystalline polymers on the microcellular foam processing and on reflectivity of products are investigated. First, polymer specimens with various morphology and amount of solved blowing agent were prepared by varying the saturation pressure, saturation time and foaming condition. Then, cell morphologies according to several conditions were studied. The specimens with differing gas amount of solved and morphologies were foamed and their cellular structures were compared. The experimental results of reflectivity are compared to raw specimen and another specimen of different experimental conditions. After the experiments, recognize whether how reflectivity changes according to solved gas amount. And the effect of cell density and cell size on reflectivity is studied

• Macromolecular Research
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• v.16 no.5
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• pp.467-472
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• 2008

Rigid polyurethane foams (RPUFs) were fabricated from crude MDI (CMDI) and polypropylene glycols (PPGs) of various isocyanate indices with a physical blowing agent (HFC 365mfc). There was a tendency for the gel time to decrease and the tack-free time to increase with increasing index value. With increasing index value the foam density and compression strength decreased and the glass transition temperature, dimension stability and thermal insulation increased, while the cell size and closed cell content were virtually unchanged. Allophanate crosslinks and condensation reactions between the isocyanate groups, which are favored with a high index value, exerted significant effects on the properties of RPUFs.