• Title/Summary/Keyword: polymer fibers

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Effect of Molecular weight of Atactic Poly(vinyl alcohol) (PVA) on the Polarizing Efficiency of PVA/Azo Dye Polarizer (PVA/아조염료계 편광필름의 편광효율에 따른 혼성배열 폴리비닐알코올의 분자량 효과)

  • Park, Joo-Min;Kim, Sam-Soo;Lyoo, Won-Seok
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.104-107
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    • 2003
  • Poly(vinyl alcohol) (PVA) obtained by the saponification of poly(vinyl ester) like poly(vinyl acetate) o. poly(vinyl pivalate) is a linear semicrystalline polymer, which has been widely used as fibers for clothes and industries, films, membranes, medicines for drug delivery system, and cancer cell-killing embolic materials[1-3]. PVA fibers and films have high tensile and compressive strengths, high tensile modulus, and good abrasion resistance due to its highest crystalline lattice modulus. (omitted)

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Characterization of Surfaces by Contact Angle Goniometry - II . Effect of Curvature on Contact Angle - (접촉각 측정에 의한 표면의 특성연구( II ) -섬유나 막대의 직경이 접촉각에 미치는 영향-)

  • Park Chung Hee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.15 no.4 s.40
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    • pp.437-445
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    • 1991
  • The effect of diameter of rods or fibers on contact angle was studied in a vertical rod configuration. A contact angle measuring device described in the previous paper was optimized for the measurement of small-diameter fibers. It was shown that contact angles of water and hexadecane on nylon 6 monofilsments and glass rods increased with decrease of diameter below a critical diameter, which varied from one system to another. Beyond the critical value, contact angle of the liquid on the vertical glass rod reached to an equilibrium value which is equal to the unique value of the contact angle of the liquid drop on the horizontal glass plate.

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Effect of Compatibilizers on Mechanical Properties of Wood-Plastic Composites Using Styrene Polymers as Matrix Polymers (스티렌계 수지(樹脂)를 매트릭스로 사용한 목재 - 플라스틱 복합체(複合體)의 물성(物性)에 미치는 상용화제(相溶化劑)의 효과(效果))

  • Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
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    • v.21 no.2
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    • pp.31-37
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    • 1993
  • Composites of styrene polymers with woody fibers were prepared, and the effect of compatibilizers on their mechanical properties was evaluated. To improve the compatibility of wood fibers and the matrix polymers, styrene-maleic anhydride copolymer(SMA) and maleic anhydride-modified polymers were used as compatibilizers. As results, maleic anhydride-modified polystyrene and SMA were proved to improve the tensile strength of the molded composites, and also were evaluated as good compatibilizers for the wood fiber polystyrene composite. Cellulosic fiber (dissolving pulp) provided better reinforcement than lignocellulosic fiber(thermomechanical pulp). On the contrary in the case of the composite of wood fiber and acrylonitrile-butadiene styrene copolymer(ABS), SMA and maleic anhydride-modified acrylonitrile-butadiene-styrene copolymer(MABS) did not act as compatibilizers. However, MABS was evaluated as a good polymer matrix to make wood fiber reinforced composite. The tensile properties of the composites of wood fiber and MABS were superior than those of wood fiber-ABS composites.

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Mechanical Properties of Sisal Fiber Reinforced Composites on Surface Treatment and Temperature (사이잘섬유강화 복합재료의 표면처리와 환경온도에 따른 기계적 특성)

  • Song, Jun Hee;Kim, Yonjig
    • Korean Journal of Metals and Materials
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    • v.46 no.8
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    • pp.471-476
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    • 2008
  • There has been a growing interest for the use of natural fibers in composite applications due to their low cost, environmental friendliness, and good mechanical properties. It was demonstrated to determine the characteristic of tensile behaviors under the variation of test temperature on sisal fiber reinforced polymer composites by RTM process. Especially, the permanganate-treated-fibers improved tensile strength by increasing the coherence with matrix. Material deformation is restricted to increment of cohesion for surface treatment of fiber and then elongation decreas.

A Study on the Mechanical Properties of Carbon Fiber Reinforced Cement Composite Impregnated in Polymer (폴리머 함침 탄소섬유보강 시멘트 복합체의 역학적 특성에 관한 연구)

  • ;;Lee, Burtrand. I.
    • Magazine of the Korea Concrete Institute
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    • v.4 no.1
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    • pp.107-118
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    • 1992
  • In order to examine the mechanical properties of carbon fiber reinforced cement composites with silica powder PAN - based carbon fiber and Pitch- based carbon fiber, and polymer impregnators experimental studies on CFRC impregnated in polymer were carried out. The effects of types, length, and content~i of carbon fibers and matrices of fresh and hardened CFRC impregnated in polymer were examined. The test results show that compressive, tensile, and flexural strength of CFRC impregnated in polymer were much more iriCreased than those of air cured and autodaved CFIIC CFRC impregnated in polymer was also considerably effective in improving toughness, freeze thaw resistance, loss of shrinkage, and creep resist ance, compared with air cured and autoclaved CFRC.

Synthesis of High Affinity Anion Exchanger Using Ultrafine Fibrous PPmb Nonwoven Fabric by Co60 Irradiation Method (방사선 조사에 의한 초극세 폴리프로필렌 섬유부직포를 이용한 고효율 음이온교환체의 합성)

  • Choi, Kuk-Jong;Lee, Choul-Ho;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.509-515
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    • 2008
  • The aminated polypropylene melt blown ion exchange fibers were synthesized with acrylic acid monomer onto polypropylene melt blown fibers by radiation-induced polymerization and subsequent amination. Degree of grafting was increased with increasing the acrylic acid monomer concentration and total dose. The highest degree of grafting was obtained 140% at a monomer concentration of 20 v/v% acrylic acid and total dose of 4 kGy. Optimum condition of Mohr's salt was 5.0 $\times10^{-3}$ M. Degree of amination was increased with increasing degree of grafting. Water content was about 1.5 times higher than that of trunk polymer. The maximum ion-exchange capacity was 7.3 meq/g which was 2$\sim$3 times higher than a commercial ion exchange fiber. The average pore size was decreased and BET surface area was increased in order of PPmb, PPmb- g- AAc and APPmb- g- AAc. The average pore size and BET surface area of synthesised fibers were $366.1\;{\AA},\;3.71m^2/g,\;143.3\;{\AA},\;4.94m^2/g,\;40.97\;{\AA},\;8.98m^2/g$, respectively.

Impact Fracture Behavior under Temperature Variation and Compressive·Flexural Strength of Cement Composites using VAE Powder Polymer and PVA Fiber (PVA 섬유와 VAE 분말 폴리머를 사용한 시멘트복합체의 압축·휨강도 및 온도변화에 따른 충격파괴거동)

  • Heo, Gwang-Hee;Park, Gong-Gun;Kim, Chung-Gil;Lee, Hyung-Joon;Choi, Won-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.1
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    • pp.102-112
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    • 2019
  • This paper studies impact fracture behavior under temperature variation and compressive flexural strength of cement composites using VAE(vinyl acetate ethylene) powder polymer and PVA(polyvinyl alcohol) fiber. Impact test were conducted in the temperature range selected for the $-35^{\circ}C$, $0^{\circ}C$ and $35^{\circ}C$. In this experimental study, impact test were carried out using a drop impact testing machine (Ceast 9350) to obtain such as displacement, time, and impact fracture energy of normal specimen and and cement composites specimen. As test results, the use of VAE powder polymer and PVA fiber were observed to enhance the flexural strength of mortar. The compressive strength of PVA fibers reinforced cement composites was slightly decreased at 28 days, but the flexural strength was observed to increase 24.4% of normal mortar strength. As a result of the drop impact tests, PVA fiber reinforced cement composites specimens showed microcracks due to energy dispersion and crack prevention with bridge effect of the fibers, and scabbing or perforation by impact was suppressed. On the other hand, the normal mortar and VAE powder polymer cement composites specimens were carried out to the perforation and macro crack. Most of normal mortar and the cement composites subjected to impact load on specimens shows mostly local brittle failure. The impact resistant performance of the specimen with PVA fiber was greatly improved due to the increase of flexure performance.

Manufacturing and Mechanical Properties of Epoxy Fibers Spinning using Anhydride and Amine Hardeners (산 무수물계 및 아민계 경화제를 이용한 열경화성 에폭시 섬유 제조 및 물성)

  • Shin, Pyeong-Su;Kim, Jong-Hyun;Park, Ha-Seung;Baek, Yeong-Min;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.29 no.6
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    • pp.408-413
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    • 2016
  • Commonly-used polymers are manufactured as versatile forms. Furthermore, continuous polymer fibers are recently manufactured using nylon or aramid fiber. One of common epoxy was also used to make polymer fibers. Bisphenol-A type was used as base epoxy whereas amine and anhydride were used as hardeners. Epoxy fibers was cured by stepping up the temperature to maintain the shape of epoxy fiber. Surface energy was measured to confirm the degree of interfacial adhesion by modified static contact angle method. After mechanical properties were measured via fiber tensile test, the evaluation of fiber fracture was proceeded. Tensile strength of epoxy fiber using amine type hardener was higher as 138 MPa than anhydride case as 70 MPa. Fractured surface exhibited different failure patterns at the cross-section.

Thermomechanical Properties and Shape Memory Effect of PET-PEG Copolymers Cross-linked with Pentaerythritol

  • Shim, Yong-Shik;Chun, Byoung-Chul;Chung, Yong-Chan
    • Fibers and Polymers
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    • v.7 no.4
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    • pp.328-332
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    • 2006
  • Poly(ethylene terephthalate) (PET) and poly(ethylene glycol) (PEG) copolymers cross-linked with pentaerythritol, a four-way cross-linker, are prepared to compare their mechanical and shape memory properties with the one cross-linked by glycerol. Composition of PEG and pentaerythritol is varied to search for the one with the best mechanical and shape memory properties. The highest shape recovery rate is observed for the copolymer composed of 30 mol% PEG-200 and 2.5 mol% pentaerythritol. Four-way cross-linking by pentaerythritol significantly improves shape recovery rate and retention of high shape recovery rate after repeated use compared to the one cross-linked by glycerol, a three-way cross-linker, and difference and advantage of additional cross-linking point are discussed.

Interfacial Properties and Microfailure Degradation Mechanisms of Bioabsorbable Composites for Implant Materials using Micromechanical Technique and Acoustic Emission (Micromechanical시험법과 Acoustic Emission을 이용한 Implant용 생흡수성 복합재료의 계면물성과 미세파괴 분해메카니즘)

  • Kim, Dae-Sik;Park, Joung-Man;Kim, Sung-Ryong
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.05a
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    • pp.263-267
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    • 2001
  • The changes of interfacial properties and microfailure degradation mechanisms of bioabsorbable composites with hydrolysis were investigated using micromechanical test and acoustic emission (AE). As hydrolysis time increased, the tensile strength, the modulus and the elongation of PEA and bioactive glass fibers decreased, whereas those of chitosan fiber changed little. Interfacial shear strength (IFSS) of bioactive glass fiber/poly-L-lactide (PLLA) composite was significantly higher than that two other systems. The decreasing rate of IFSS was the fastest in bioactive glass fiber/PLLA composite, whereas that of chitosan fiber/PLLA composite was the slowest. With increasing hydrolysis time, distribution of AE amplitude was narrow, and AE energy decreased gradually.

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