• Title/Summary/Keyword: polymer expansion

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Fiber Loading Effect on the Interlaminar, Mechanical, and Thermal Properties of Novel Lyocell/Poly(butylene succinate) Biocomposites (새로운 라이오셀/poly(butylene succinate) 바이오복합재료의 층간전단, 기계적, 열적 특성에 미치는 섬유함량의 영향)

  • Lee, Jae Young;Kim, Jin Myung;Cho, Donghwan;Park, Jong Kyoo
    • Journal of Adhesion and Interface
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    • v.10 no.2
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    • pp.106-112
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    • 2009
  • In the present work, novel biocomposites made with biodegradable Lyocell woven fabrics and poly (butylene succinate) were successfully fabricated for the first time. Lyocell/poly(butylene succinate) biocomposites with different fiber loadings of 0, 30, 40, 50 and 60 wt% were prepared by compression molding with a sheet interleaving manner. The effect of Lyocell fabric loading on the interlaminar shear strength, tensile and flexural properties, heat deflection temperature, thermal expansion behavior, and thermal stability of the biocomposites was investigated. The properties strongly depended on the fabric loading and the results were consistent with each other. It was demonstrated that the Lyocell fabrics played a remarkable role in improving the properties of poly(butylene succinate) resin by incorporating the fabrics into the resin. The greatest inter-laminar, tensile, flexural and thermal properties of the biocomposites were obtained with Lyocell fabrics of 50% by weight.

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Analysis of Thermal Expansion of Latex-Modified Concrete (라텍스개질 콘크리트의 열팽창 특성 분석)

  • Choi, Seong-Yong;Lee, Joo-Hyung;Lim, Hong-Beom;Yun, Kyong-Ku
    • Journal of Industrial Technology
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    • v.23 no.A
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    • pp.157-163
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    • 2003
  • The properties of mechanics and durability of LMC have been performed actively. However, little studies on analysis and properties of thermal expansion has been on the temperature variation. Especially, the low of bonding strength and tensile cracking are caused by difference of thermal expansion between LMC and the substrate concrete. Therefore, this study focused on effect of thermal expansion behavior and properties of LMC according to temperature variation. To identify the property of thermal expansion of LMC, tests of modulus of thermal expansion were carried out at 28 days after casting specimen, subjected to temperature variation between $10^{\circ}C$ and $60^{\circ}C$. The results of this study showed the modulus of elastic of LMC was similar to that of ordinary portland concrete(OPC). It means that stresses caused by difference of modulus of elastic did not occur on interface between LMC and existing concrete. The modulus of thermal expansion of LMC had a little smaller than that of OPC. The modulus of thermal expansion of polymer modified concrete is generally larger than OPC, but the result of this test is disagree with the fact, which may be due to the humidity evaporation difference and aggregate properties.

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A study on the Measurement of the Coefficient of Thermal Expansion of Polymer materials Exposed to Different Thermal Environments (서로 다른 열환경에 노출된 고분자 소재의 열팽창계수 측정에 관한 연구)

  • Kim, Dong-Ju;Park, Seul-Hyun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.4
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    • pp.80-86
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    • 2021
  • Plastics are widely used in mechanical and other fields due to their light weight, design flexibility, and molding processability. In processing plastics, defective products are mixed and reprocessed to improve production efficiency and reduce costs. In this study, an experiment was conducted to confirm the coefficient of thermal expansion of HDPE during this reprocessing. The coefficient of thermal expansion was measured at different measurement directions and heating rates. As a result, we observed that the coefficient of thermal expansion in the direction perpendicular to the injection direction is greater than that in the horizontal direction.

Effect of Water-Soluble Polymer on the Properties of High Strength Hardened Cement Paste (고강도 시멘트 경화체의 특성에 미치는 수용성 폴리머의 영향)

  • 김정환;최상흘;한기성
    • Journal of the Korean Ceramic Society
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    • v.26 no.5
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    • pp.698-704
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    • 1989
  • Basic investigation for the flexural strength and water stability of hardened cement pastes using ordinary portland cement with water-soluble polyer (hydroxypropyl methyl cellulose ; HPMC) was carried out with 0.2 of water cement ratio. For molding of the specimen, the paste was mixed by twin roll mill. According to increase in the content of HPMC, the setting time of cement paste was delayed and the flexural strength was increased. The maximum flexural strength of hardened cement paste with 5.0wt% of HPMC was about 330 kg/$\textrm{cm}^2$. The expansion of the hardened cement paste immersed in water was increased with the content of water soluble polymer(HPMC). Consequently, the strength and the water stability of the hardened cement pastes were remarkably reduced by the expansion of them.

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A PDMS-Coated Optical Fiber Bragg Grating Sensor for Enhancing Temperature Sensitivity

  • Park, Chang-Sub;Joo, Kyung-Il;Kang, Shin-Won;Kim, Hak-Rin
    • Journal of the Optical Society of Korea
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    • v.15 no.4
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    • pp.329-334
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    • 2011
  • We proposed a poly-dimethylsiloxane (PDMS)-coated fiber Bragg grating (FBG) temperature sensor for enhancing temperature sensitivity. By embedding the bare FBG in a temperature-sensitive elastomeric polymer, the temperature sensitivity of the proposed structure could be effectively improved by 4.2 times higher than those of the conventional bare-type FBG sensors due to the high thermal expansion coefficient of the PDMS. We analyzed the temperature-sensitivity enhancement effect with the increased Bragg wavelength shift in our structure and dependence on the temperature sensitivity with respect to the cross-section area of the PDMS.

Fabrication of Duplex Ceramic Composites by Organic-Inorganic Solution Process

  • Lee, Sang-Jin;Kim, Youn-Cheol
    • Journal of the Korean Ceramic Society
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    • v.40 no.9
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    • pp.837-841
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    • 2003
  • Duplex microstructure of zirconia and alumina has been achieved via an organic-inorganic solution technique. Zirconium 2,4-pentanedionate, aluminum nitrate and polyethylene glycol were dissolved in ethyl alcohol without any precipitation. The organicinorganic precursor gels were turned to porous powders having volume expansion through explosive, exothermic reaction during drying process. The volume expansion was caused by abrupt decomposition of the organic groups in the gels during the vigorous exothermic reaction. The volume expanded, porous powders were crystallized and densified at 1500$^{\circ}C$ for 1 h. At the optimum amount of the PEG polymer, the metal cations were well dispersed in the solution and a homogeneous polymeric network was formed. The polymer content also affected on the specific surface area of the synthesized powder and the grain size of the sintered composite.

Physical and Mechanical Properties of Polymer Concrete Using Coal Mine Waste (석탄폐석을 이용한 폴리머 콘크리트의 물리.역학적 특성)

  • 연규석;김기성;장태연;정경현;주명기;최동순
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.04a
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    • pp.57-64
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    • 1996
  • Lately, rapid expansion of construction industry and following increment of demand for concrete in the construction created shortage of aggregates in the nation. Supplement of good quality aggregate is an immediate issue for the construction industry to solve. Therefore, this study evaluated a possibility of using coal mine waste collceted from Kwangwon-do region as a source of aggregate in manufacturing polymer concretes which have high strength and high durability. First, aggregates were obtained by crushing coal mine waste and polymer concrete was manufactured using these aggregate. Mechanical property test results for the polymer concrete showed that the coal mine waste aggregates were acceptable to use as a replacement of the aggregate in polymer concrete manufacture.

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Flexural Cnaracteristics of Polymer Concrete Sandwich Constructions (폴리머 콘크리트 샌드위치 구조재의 휨특성)

  • 연규석
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.31 no.2
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    • pp.125-134
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    • 1989
  • This study was conducted to investigate the flexural behaviour of sandwich constructions with cement concrete core and polymer concrete facings. Six different cross-sectional shapes using epoxy based polymer concrete facings were investigated. Some of the results from the static tests are given including the load-deflection responses, load-strain relationships, ultimate moment, and mode of failure. From the. results the following conclusions can be made. 1. The various strengths of polymer concrete were very high compared to the strengths for portland cement concrete, while modulus of elasticity assumed an aspect of contrast. 2. The thickness of core and facing exerted a great influence on the deflection and ultimate strenght of polymer concrete sandwich constructions. 3. The variation shape of deflection and strain depend on loading were a very close approximation to the straight line. The ultimate strain of polymer concrete at the end of tensile side were ranged from 625x10-6 to 766x10-6 and these values increased in proportion to the decrease of thickness of core and facings. 4. The ultimate moments of polymer sandwich constructions were 3 to 4 times that of cement concrete constructions which was transformed same section. It should he noted that polymer concrete have an effect on the reinforcement of weak constructions. 5. Further tests are neede to investigate the shear strain of constructions, and thermal expansion, shrinkage and creep of cement and polymer concrete which were composite materials of sandwich constructions.

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Evaluation of interfacial tension for poly(methyl methacrylate) and polystyrene by rheological measurements and interaction parameter of the two polymers

  • Sung, Y.T.;Seo, W.J.;Kim, Y.H.;Lee, H.S.;Kim, W.N.
    • Korea-Australia Rheology Journal
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    • v.16 no.3
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    • pp.135-140
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    • 2004
  • Morphological and rheological properties of the poly(methyl methacrylate) (PMMA) and polystyrene (PS) blends were studied by scanning electron microscopy (SEM) and advanced rheometric expansion system (ARES). From the SEM results, the PMMA-PS blends showed dispersed morphology and the particle size of the dispersed phase was quite small (0.1~0.6 $\mu\textrm{m}$ compared with other immiscible polymer blends. Values of the interfacial tension of the PMMA-PS blend were obtained from the Choi-Schowalter and the Palierne emulsion models using the storage modulus of the PMMA and PS, and found to be 1.0 and 2.0 mN/m, respectively. The interfacial tension between the PMMA and PS was also calculated from the Flory-Huggins polymer-polymer interaction parameter ($\chi$) and found to be from 0.98 to 1.86 mN/m depending on the molecular weight and composition. Comparing the values of the interfacial tension from the Flory-Huggins polymer-polymer interaction parameter and the values measured by oscillatory rheometer, it is suggested that the interfacial tension of the PMMA-PS blend obtained from the polymer-polymer interaction parameter are in good agreement with the values obtained by rheological measurements.

Modified Effects or Surfactants with Polymer-Clay Nanocomposites (고분자-점토 나노복합체에 관한 계면활성제의 개질 영향)

  • Kim, Hong-Un;Bang, Yun-Hyuk;Choi, Soo-Myung;Lim, Kyung-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.4
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    • pp.290-299
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    • 2006
  • This article investigated to polymer-clay nanocomposite, especially in interfacial respect clay structure, its dispersion into polymer matrix, and clay modification is studied. The cationic exchange of surfactants with clay gallery results in preparing organo-clay capable of compatiblizing to monomer or polymer and increasing interlayer adhesion energy due to expansion of interlayer spacing. The orientation of surfactant in clay gallery is affected by chemical structure and charge density of clay, and interlayer spacing and volume is increased with alkyl chain length of surfactant, or charge density of clay. Also, the interaction between clay and polymer in preparing polymer-clay nanocomposite is explained thermodynamically. In the future, the study and development of polymer-clay nanocomposite is paid attention to the interfacial adhesion, clay dispersion within polymer, mechanism of clay intercalation or exfoliation.