• 한국기계가공학회지
• /
• 제18권11호
• /
• pp.63-68
• /
• 2019

The dimensional quality of flexible foams is often difficult to be evaluated through general machine vision inspection methods due to the free deformation of the outer shape. For the evaluation of the dimensions of flexible foams, methods of estimating the size of the product through the expansion rate of the product surface are evaluated. Specimens with various dimensions and surface gratings are prepared, and the degree of surface expansion is measured through machine vision. The correlation, between the measured surface grid size and the actual size of test specimens, is analyzed. We further analyze the correlation between the size of test specimens and the position of the surface grid. This study provides a basis for estimating the actual dimensions of specimens by measuring the surface expansion of flexible foams.

• 폴리머
• /
• 제34권4호
• /
• pp.352-356
• /
• 2010

2개의 종횡비에 의해 특징지어진 3차원 타원체를 사용하여 PP복합체의 충전제 형태와 함량이 열팽창률에 미 치는 영향에 대해 Lee와 Paul에 의해 제안된 이론적인 값과 실험적인 결과값이 비교분석되었다. 충전제의 형태는 구형에 황산바륨을, 섬유형에는 유리섬유를, 판상형에는 운모를 사용하였다. 실험의 결과로서 구형을 갖는 황산바륨 은 종횡비가 1의 값을 갖고 이론과 같이 열팽창률이 감소하였다. 유리섬유의 경우 함량증가에 따라 종횡비는 42, 37, 25, 20으로 감소하였으며 종단방향에선 열팽창률이 감소하였지만 수직방향에서는 증가하였다. 운모의 경우 그 함량증가에 따라 모두 종단방향과 횡단방향에서 감소하고 수직방향에서 증가하였다. 종횡비의 값은 각각, $\rho_\alpha$=13.5, $\rho_\beta$=1.8이었다.

• Journal of Photoscience
• /
• 제6권3호
• /
• pp.109-115
• /
• 1999

Intense excimer laser irradiation of polymer films results in expansion and the following contraction , recovering ithe initial flat surface. The morphological dynamics is meausred directly by nanosecond time-resolved interferometry for polystyrene(PS), polyurethane, and polyimide films. The expansion proceeds with a speed of a few nm/ns , while the contraction depends upon the polymer ; very low contraction for PS, rapid 2 component shrinking for polyurethane, and rapid monotonous decay for polymide. These characteristic behavior are considered from viewpoints of interpenetrating structures of polymers, glass-rubber phase transitioni, thermal diffusion, and photothermal mechanism.

• Journal of Industrial and Engineering Chemistry
• /
• 제67권
• /
• pp.1-11
• /
• 2018

Polymer composites offered broad engineered applications, however their diversity get restricted owing to fluctuations in thermomechanical properties during heating or cooling hence great concern required prior their applications through thermomechanical analysis (TMA). Traditionally, TMA or dilatometry found to be simple, ideal, reliable, sensitive, excellent and basic thermal analytical technique. TMA provides valuable information on thermal expansion, glass transitions temperature (Tg), softening points, composition and phase changes on material of having different geometries simply by applying a constant force as a function of temperature. This compilation highlights the basics and experimental of TMA for both research and technical applications and also provide literature on TMA of polymers, hybrid composites, nanocomposites and their diverse applications.

• Macromolecular Research
• /
• 제9권1호
• /
• pp.1-19
• /
• 2001

Poly(p-phenylene pyromellitimide) and poly(4,4'-biphenylene pyromellitimide) are representatives of fully rod-like polyimides. Their structure and properties in thin films are reviewed. The polymers exhibit some excellent properties such as high molecular packing coefficient, high mechanical modulus, and low thermal expansion coefficient, and low interfacial stress, so that they are very attractive to both industry and academia. However, these polymers are very brittle and thus practically useless. Some chemical modifications to improve such drawback with a little sacrifice of the high modulus are described: i) incorporation of short side groups into the polymer backbone and ii) insertion of proper linkages into the polymer backbone.

• 한국고분자학회:학술대회논문집
• /
• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
• /
• pp.215-215
• /
• 2006

The cyclic butylene terephthalte oligomer was synthesized and the composition of butylenes terephthalate cyclic oligomers was 51.2 % of dimer, 28.1 % of trimer, 7.9 % of tetramer, 8 % of pentamer and 4.8% of hexamer. Polybuthylene terephthalate was polymerized using this cyclic oligomer in the condition of melt process and supercritical process. And PBT/clay nanocomposite were manu- factured from melt process and supercritical process. Chlorodifluoro- methane(HCFC-22) was used as a solvent which has critical point ($Tc=96.2^{\circ}C$, Pc=49.7bar). Also polymer nanocomposite were manufactured using rapid expansion of supercritical solution process.

• 폴리머
• /
• 제34권3호
• /
• pp.220-225
• /
• 2010

폴리에테르설폰(PES) 필름의 주사슬 연신에 의한 광학 특성 변화와 보상 필름으로 사용 환경온도에 따른 이들의 특성변화를 살펴보았다. 아울러 연신 및 열처리가 필름의 광학 특성 및 치수안정성에 미치는 영향을 함께 확인하였다. PES는 연신에 의하여 광학용 보상 필름으로 사용이 가능할 정도의 $R_e$ 값과 $R_{th}$ 값을 얻을 수 있었으며 이러한 값들은 반복적인 사용 환경 온도에 따라 변화되며 이를 최소화하기 위하여 열처리 공정이 필요함을 알 수 있었다. 연신된 PES 필름은 사용온도가 증가됨에 따라 연신에 의한 주사슬의 수축이 발생되며 그 이후 고유 특성인 열팽창이 일어나며, 연신에 의한 주사슬 배향에 의하여 열팽창계수는 다소 감소함을 알 수 있었다. 필름의 열처리는 열팽창계수에는 크게 영향을 미치지 않는 반면 열수축을 현저하게 감소시킴을 확인하였다.

• 폴리머
• /
• 제34권4호
• /
• pp.369-375
• /
• 2010

용융 중합법을 이용하여 말단에 메틸 말레이미드(methyl maleimide) 반응성기를 가지며 방향족 에스터와 아 미드 결합을 포함하는 액정(liquid crystal, LC)을 합성하였다. 합성된 액정은 용액 캐스팅과 열처리를 거쳐 열경화 성 액정(liquid crystalline thermoset, LCT) 필름으로 제조되었다. 합성된 LC 및 LCT는 적외선 분광기(FTIR), 시차주사 열량계(DSC), 열중량 분석기(TGA), 열-기계 분석기(TMA), X-선 회절기(XRD) 및 가열판이 부착된 편광 현미경(POM) 등을 이용해서 각각 특성 분석을 하였다. 합성된 모든 액정은 스멕틱(smectic) 상을 보였으며 LC와 LCT들의 열적 성질은 주로 주사슬에 포함된 메소젠 구조에 영향을 받았다. 열팽창 계수(coefficients of thermal expansion, CTE)는 27.72~50.95 ppm/$^{\circ}C$ 사이의 값을 보였다.

• Macromolecular Research
• /
• 제15권1호
• /
• pp.51-58
• /
• 2007

The approach studied in the present work produced an exfoliated state of clay layers via confinement of the charged nano-sized polystyrene (PS) beads within the gallery of swollen pristine clay. It was demonstrated that adsorption of the polymer nanobeads dramatically promotes expansion of the clay gallery. A comparative study of incorporation was conducted by employing organo-modified clay along with two different colloid polymer systems: electrostatically stabilized PS nanobeads and cationic monomer-grafted PS nanobeads. The mechanism of adsorption of the monomer-grafted polymer beads onto clay via cationic exchange between the alkyl ammonium group of the polymer nanobeads and the interlayer sodium cation of the layered silicate was verified by using several techniques. As distinct from the polymer nanobeads formed using conventional miniemulsion polymerization method, competitive adsorption of stabilizing surfactant molecules was be prevented by grafting the surface functional groups into the polymer chain, thereby supporting the observed effective adsorption of the polymer beads. The presence of surface functional groups that support the establishment of strong polymer-clay interactions was suggested to improve the compatibility of the clay with the polymer matrix and eventually play a crucial role in the performance of the final nanocomposites.

• 대한전기학회논문지
• /
• 제37권1호
• /
• pp.55-62
• /
• 1988

The variation of electrical resistivity of silver particle-filled polymers with the volume percent of silver particles was investigated. Also, the relationships between the surface tension of polymer and dispersion effect of silver particles were studied to find the steep drop of electrical resisivity, in view of agglomerate morphology. The critical volume precent of silver particles varied depending on the polymer species and increased with the increasing surface tension of polymer. The steep variation of resistivity with the increasing temperature was explained with the expansion of polymer at the melting temperature of polymer. The conductive break down current increased with the increasing volume percent of silver particles in the Ag/LDPE system and that was attributed to heat of Joule taken througn the contact area between the silver particle.