• 한국건축시공학회지
• /
• 제3권4호
• /
• pp.103-109
• /
• 2003

Reinforced concrete structures under sever conditions such as marine structures, bridges and structural constructed with aggregated(dredged front sea). can be deteriorated from corrosion of the reinforcing bars. The purpose of this study is to evaluate the corrosion reflectance of coated steel using polymer dispersion and polymer cement slurry. Polymer dispersion and polymer cement slurry with various polymer types were coated to the surface of bars and steel plate, and tested for accelerated corrosion tests. Tests include adhesion in tension, bending test, chloride ion spray, penetration of NaCl 10％ solution and carbonation. From the test results, the corrosive resistance of steel is considerably improved by using polymer dispersion and polymer cement flurry at surface of steel. The difference of the corrosive resistance is hardly recognized according to types of polymer dispersion. The coated steel using polymer dispersion and polymer foment slurry will be improved to a great extent compared to those of plain steel when increasing content of chloride ion in cement concrete.

• Journal of Pharmaceutical Investigation
• /
• 제41권3호
• /
• pp.179-184
• /
• 2011

This study aimed to confirm the effect of molecular weight (MW) in solid dispersion of carvedilol with poly-vinylpyrrolidone (PVP) of various MW. Solid dispersion of carvedilol with PVP was prepared by spray-drying method. Scanning electron microscopy (SEM) was used to analyze the surface of solid dispersion samples. Differential scanning calorimetry (DSC) and X-ray diffraction (XRD) were used to analyze the crystalline of solid dispersion. Fourier transform infrared spectroscopy (FT-IR) was used to analyze the change of chemical structure characteristic of solid dispersion. DSC and XRD show that drug crystalline was changed. FT-IR revealed that chemical structure of solid dispersion comparing the chemical structure of drug was changed. The dissolution studies of solid dispersion presented at simulated gastric juice (pH 1.2). The dissolution rate of solid dispersion was dramatically enhanced than pure drug and the MW of PVP has an effect on the release property of carvedilol in solid dispersion. In conclusion, the present study has confirmed the effect of MW of PVP on release property of solid dispersion formulation of carvedilol with PVP.

• Bulletin of the Korean Chemical Society
• /
• 제17권3호
• /
• pp.245-253
• /
• 1996

A topological theory has been introduced to explain and evaluate the fractional volumes of system materials, the change of the weight and concentration of monomer molecules, molecular weight distribution, and interaction functions of polymer-polymer and polymer-oligomer, etc. for dispersion polymerization. The previous theory of Lu et al. has offered only an incomplete simulation model for dispersion polymer systems, whereas our present one gives a general theoretical model applicable to all the polymerization systems. The theory of Lu et al. considered only the physical property term caused by interaction between matters of low molecular weight (i.e., diluent, monomer, and oligomer) and polymer particles without dealing with physical properties caused by the structure of polymer networks in polymer particles, while our theory deals with all physical effect possible, caused by the displacement of not only entangled points but also junction points in polymer particles. The theoretically predictive values show good agreement with the experimental data for dispersion polymerization systems.

• 한국고분자학회:학술대회논문집
• /
• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
• /
• pp.365-365
• /
• 2006

The wavelength dispersion of birefringence (or retardation) is very important property for optical use of polymer films. Birefringence free film and retardation film have been widely used for applications such as liquid crystal display (LCD). In this study, miscible polymer blends which consist of polymers of positive and negative birefringence were found. By operating composition and orientation of molecules in the transparent blend films, the behavior of wavelength dispersion of birefringence (retardation) was controlled. The applicability to wideband birefringence free film and quarter wave (retardation) film was discussed.

• 폴리머
• /
• 제39권1호
• /
• pp.33-39
• /
• 2015

올메사탄은 BCS 2단계에 해당하는 약물로 물에 잘 녹지 않는 난용성 약물이다. 이런 약물이 낮은 생체이용률과 제형을 설계하는 과정에서 어려움을 주는 원인이 된다. 본 연구에서는 올메사탄을 분무건조법 및 회전용매증 발법을 이용해 고체분산체를 제조하여 제법에 따른 난용성약물의 용출률을 확인하였다. 수용성 고분자로 PVP를 사용하여 약물과 고분자의 비율별로 고체분산체를 제조하였다. SEM을 이용하여 고체분산체의 형태학적인 특성을 분석하였고, 고체분산체의 결정학적 성질은 XRD와 DSC를 통하여 확인하였다. 또한 FTIR을 통해 화학적인 변화를 확인하고, 생체 외 용출거동 실험을 통하여 변화된 용출률을 확인하였다. 제조된 고체분산체는 pH 1.2에서 용출을 확인하였으며, 올메텍과 용출률을 비교하였으며, 분무건조를 통해 약물의 용출률을 향상시킬 수 있다는 것을 확인할 수 있다.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
• /
• pp.1011-1016
• /
• 2001

The purpose of this study is to find out the effect of polymer glass transition temperature on mechanical properties of polymer latex-modified mortars in comparison with ordinary cement mortar. The Polymer latex-modified mortars are prepared with 5, 10, 15 and 20% of polymer cement ratio respectively, and properties of modified mortars such as air content, compressive, flexural and tensile strengths are tested. The test results indicate that the types of polymer dispersion and the polymer-cement ratio are very important factors to characterize the properties of polymer-modified mortars, and also the glass transition temperature of polymer dispersions has an important effect on the performance of polymer-modified mortars. The modifying effects of two kinds of polymer dispersion, St/BA-1 and SBR, are evaluated.

• 폴리머
• /
• 제37권3호
• /
• pp.342-346
• /
• 2013

마이크론 크기의 입자를 분산하기에 적합하나 나노 크기의 입자를 분산하기에는 미흡한 이축압출기를 사용하여 카본나노튜브(CNT) 분산을 시도하였다. 카본나노튜브 분산성 향상을 위해 서로 다른 입자 형상을 가지는 무기 충전제를 부가하였다. 무기 충전제 첨가에 따른 점도 증가는 상대적으로 높은 전단력을 유도하여 응집된 카본나노튜브 입자의 분산을 도모하였다. 또한 충전제 입자들은 전단력이 미치지 않는 구역에서 일어나는 카본나노튜브의 재응집을 억제함으로써 분산 안정화에 기여하였다.

• 펄프종이기술
• /
• 제35권2호
• /
• pp.18-25
• /
• 2003

The adsorption of co-cationic dual polymer system was investigated as was the fiber dispersion stability of a paper stock suspension. Polyaluminum chloride(PAC) and polyamidoamine epichlorohy-drin(PAE) polymers were used as wet-end additives. The adsorbed amounts of PAE polymer in a wet stock were measured by using polyelectrolytic PCD titration. The sheet forming experiments were carried out in a standard handsheet machine. Fiber dispersion stability and relative retention were evaluated in terms of M/K non-uniformity index and sheet basis weight, respectively. The PAE polymer adsorption of Langmuir-isothermal type decreased with increasing PAC addition level. The combination of the two cationic polymers presumably exerts a site-blocking effect by the low molecular weight PAC which gives a partial charge neutralization at a minimum level of addition. From a thermodynamic view point of PAE adsorption, an increase in adsorption entropy and a decrease in train number suggests that the PAR polymer has an extended conformation structure that potentially leads to an enhancement of the fiber dispersion stability. This conclusion is supported by handsheet experiments that examined the PAC-PAE dual polymer effects on the sheet formation and retention.

• 폴리머
• /
• 제38권4호
• /
• pp.434-440
• /
• 2014

셀레콕시브는 높은 결정성을 갖는 난용성 약물로서 이러한 난용성 약물의 용해도를 증진시키기 위해 고체분산법을 바탕으로 한 분무건조기를 이용하여 고체분산체를 제조하였다. PVP K30과 Eudragit EPO를 수용성 담체로 사용하였고 폴록사머 407은 계면활성제로 사용하였다. 제조된 셀레콕시브 고체분산체의 특성을 SEM, DSC, XRD 그리고 FTIR을 이용하여 확인하였다. SEM과 DSC 그리고 XRD를 통하여 셀레콕시브 고체분산체가 무정형임을 알 수 있었다. 제조된 고체분산체는 pH 1.2에서 용출을 실시하였으며 시판제인 Celebres$^{(R)}$ 용출률을 비교하였으며 분무건조를 통해 제조한 고체분산체가 Celebres$^{(R)}$보다 용출률이 크다는 것을 확인하였다.

• 폴리머
• /
• 제35권2호
• /
• pp.99-105
• /
• 2011

컴파운드의 물성을 최적화하기 위해서는 충전제 입자들의 분배와 분산이 잘 일어나도록 효율적으로 훈련하는 것이 중요하다. 혼련 효용을 향상시키고자 다양한 종류의 혼련 요소들이 이축압출기에 이용되고 있다. 본 연구에서는 탄산칼슘이 충전된 폴리스티렌을 대상으로 충전제 분산에 대한 이축압출기의 스크루 조합 영향을 알아보았다. 충전제의 분산 상태는 포토다이오드가 장착된 광학현미경으로 조사하였다. 실험 결과는 충전제의 분산 정도가 혼련 요소들의 형태 및 위치에 주로 영향을 받는다는 것을 보여주었다.