• 한국강구조학회 논문집
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• 제25권3호
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• pp.299-305
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• 2013

본 연구에서는 각형 중공강관(SHS) 장주기둥에 CFRP쉬트를 길이방향으로 보강하여 중심축하중 실험을 수행하였다. 총 3개의 장주실험체와 1개의 stub column 실험체를 제작하였으며, 실험변수는 CFRP 보강겹수이다. 실험결과 장주기둥에 대해 실험체 중간에서 전체좌굴이 발생하며 횡변위가 발생하여 파괴되었지만, CFRP쉬트의 보강을 통해 전체좌굴을 제어하며 횡변위로 인한 안정성을 확보하였다. 또한 CFRP쉬트의 보강으로 최대 22%의 내력이 상승하여 내력상승효과를 확인할 수 있었다.

• 약학회지
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• 제54권4호
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• pp.316-321
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• 2010

Adefovir dipivoxil which was originally developed by Gilead Sciences has been used as treatments of HIV and HBV, especially a therapeutics for HBeAg positive and negative chronic patients. We developed highly efficient purification method using reverse phase column chromatography for mass production and a stable amorphous Adefovir dipivoxil using solid dispersion method. Reverse phase column chromatography led to highly pure product, more than 99.7% by HPLC and can be used for mass production compared with normal column chromatography. Solid dispersion method containing watersoluble polymer and Isomalt showed improved stability of amorphous Adefovir dipivoxil against heat and moisture.

• Smart Structures and Systems
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• 제5권4호
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• pp.443-455
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• 2009

The use of fiber reinforced polymer (FRP) reinforcement in concrete structures has been on the rise due to its advantages over conventional steel reinforcement such as corrosion. Reinforcing steel corrosion has been the primary cause of deterioration of reinforced concrete (RC) structures, resulting in tremendous annual repair costs. One application of FRP reinforcement to be further explored is its use in RC frames. Nonetheless, due to FRP's inherently elastic behavior, FRP-reinforced (FRP-RC) members exhibit low ductility and energy dissipation as well as different damage mechanisms. Furthermore, current design standards for FRP-RC structures do not address seismic design in which the beam-column joint is a key issue. During an earthquake, the safety of beam-column joints is essential to the whole structure integrity. Thus, research is needed to gain better understanding of the behavior of FRP-RC structures and their damage mechanisms under seismic loading. In this study, two full-scale beam-column joint specimens reinforced with steel and GFRP configurations were tested under quasi-static loading. The control steel-reinforced specimen was detailed according to current design code provisions. The GFRP-RC specimen was detailed in a similar scheme. The damage in the two specimens is characterized to compare their performance under simulated seismic loading.

• 대한화학회지
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• 제53권3호
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• pp.279-285
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• 2009

This paper has described about preparation of $Zr^{4+}$ affinity column based on the poly(styrene-co- gly-cidyl methacrylate) prepared by emulsion polymerization of styrene and glycidyl methacrylate in order to isolate phosphopeptide. The $Zr^{4+}$ ions were introduced after the phophonation of an epoxy group on polymeric microspheres. The successful preparation of $Zr^{4+}$-immobilized polymeric microsphere stationary phase was confirmed through Fourier transform infrared spectra, optical microscopy, scanning electron microscopy, X-ray photoelectron spectra and inductively coupled plasma-atomic emission spectrometer. The separation efficiency for $Zr^{4+}$ affinity column prepared by slurry packing was tested to phosphonated casein and dephosphonated casein. The resolution time (min) of the phosphonated casein was higher than that of dephosphated casein for $Zr^{4+}$ affinity polymeric microsphere by liquid chromatography. This $Zr^{4+}$ affinity column can be used for isolation of phosphonated casein from casein using liquid chromatography.

• Computers and Concrete
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• 제27권5호
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• pp.437-445
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• 2021

Retrofitting of structures has gained importance over the recent years. Particularly, Reinforced Cement Concrete (RCC) column strengthening has become a challenge to the structural engineers, owing to the risks and complexities involved in it. There are several methods of RCC column strengthening viz. RCC jacketing, steel jacketing and Fiber Reinforced Polymer (FRP) wrapping etc., FRP wrapping is the most promising alternative when compared to the others. The large research database shows FRP wrapping, through lateral confinement, improves the axial load carrying capacity of the columns under concentric loading. However, its confining efficiency reduces under eccentric loading. Hence a relative newer technique called Near Surface Mounting (NSM), in which Carbon FRP (CFRP) strips are epoxy grouted to the precut grooves in the cover concrete of the columns, has been thrust domain of research. NSM technique strengthens the column nominally under concentric load case while significantly under eccentric case. A novel configuration of NSM in which the vertical NSM (VNSM) strips are being connected by horizontal NSM (HNSM) strips was numerically investigated under both concentric and eccentric loading. It was found that the configuration with 6 HNSM strips performed better under eccentric loading than under concentric loading, while the configuration with 3 HNSM strips performed better under concentric loading than under eccentric loading. Hence an optimum of 4 HNSM strips is recommended as strengthening measure for the given column specifications. It was also found that Aluminum alloy cannot be used instead of CFRP in NSM applications owing to its lower mechanical properties.

• 콘크리트학회논문집
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• 제24권4호
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• pp.473-480
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• 2012

아라미드 FRP로 보강된 RC 기둥의 전단보강효과를 평가하고자, 구조성능 실험을 수행하였다. 실험변수는 아라미드 시트 및 스트립 보강이며, 총 4개의 실험체를 대상으로 하였다. 실험 결과는 비보강 실험체를 기준으로 보강효과를 강도 및 에너지 능력 등을 평가하였다. 평가 결과 아라미드 시트보강이 강도증진과 아울러, 에너지 소산능력의 증진이라는 측면에서 매우 유효한 것으로 평가되었다.

• Bulletin of the Korean Chemical Society
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• 제27권1호
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• pp.71-76
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• 2006

Porous polymer monolithic columns were prepared by the direct free radical copolymerization of methacrylic acid and ethylene glycol dimethacrylate within the confines of a chromatographic column in the presence of toluene-dodecanol as a porogenic solvent. The separation characteristics of the monolithic columns were tested by a homologous series of xanthine derivatives, theophylline and caffeine. The effects of the polymerization mixture composition and polymerization condition, mobile phase composition, flow rate and temperature on the retention times and separation efficiencies were investigated. The results showed that the selection of correct porogenic solvents and appropriate polymerization conditions are crucial for the preparation of the monolithic stationary phases. The separation efficiency was only extremely weakly dependent on flow rate and temperatures. Hydrogen-bonding interaction played an important role in the retention and separation. Compared with conventional particle columns, the monolithic column exhibited good stability, ease of regeneration, high separation efficiency and fast analysis.

• Computers and Concrete
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• 제13권4호
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• pp.517-529
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• 2014

In order to increase the load carrying capacity and/or increase the service life of existing circular reinforced concrete bridge columns, Carbon Fiber Reinforced Polymer (CFRP) composites could be utilized. Transverse wrapping of circular concrete columns with CFRP sheets increases its axial and shear strengths. In addition, it provides good confinement to the concrete column core, which enhances the bending and compressive strength, as well as, ductility. Several experimental and analytical studies have been conducted on CFRP strengthened concrete cylinders/columns. However, there seem to be lack of thorough investigation of the effect of elevated temperatures on the response of CFRP strengthened circular concrete columns. A concrete confinement model that reflects the effects of elevated temperature on the mechanical properties of CFRP composites, and the efficiency of CFRP in strengthened concrete columns is presented. Tensile strength and modulus of CFRP under hot conditions and their effects on the concrete confinement are the primary parameters that were investigated. A modified concrete confinement model is developed and presented.

• Advances in concrete construction
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• 제9권3호
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• pp.313-326
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• 2020

Glass fiber-reinforced polymer (GFRP) bars have been introduced as an effective alternative for the conventional steel reinforcement in concrete structures to mitigate the costly consequences of steel corrosion. However, despite the superior performance of these composite materials in terms of corrosion, the effect of replacing steel reinforcement with GFRP on the seismic performance of concrete structures is not fully covered yet. To address some of the key parameters in the seismic behavior of GFRP-reinforced concrete (RC) structures, two full-scale beam-column joints reinforced with GFRP bars and stirrups were constructed and tested under two phases of loading, each simulating a severe ground motion. The objective was to investigate the effect of damage due to earthquakes on the service and ultimate behavior of GFRP-RC moment-resisting frames. The main parameters under investigation were geometrical configuration (interior or exterior beam-column joint) and joint shear stress. The performance of the specimens was measured in terms of lateral load-drift response, energy dissipation, mode of failure and stress distribution. Moreover, the effect of concrete damage due to earthquake loading on the performance of beam-column joints under service loading was investigated and a modified damage index was proposed to quantify the magnitude of damage in GFRP-RC beam-column joints under dynamic loading. Test results indicated that the geometrical configuration significantly affects the level of concrete damage and energy dissipation. Moreover, the level of residual damage in GFRP-RC beam-column joints after undergoing lateral displacements was related to reinforcement ratio of the main beams.

• Computers and Concrete
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• 제18권6호
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• pp.1083-1096
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• 2016

Beam-column joints are recognized as the weak points of reinforcement concrete frames. The ductility of reinforced concrete (RC) frames during severe earthquakes can be measured through the dissipation of large energy in beam-column joint. Retrofitting and rehabilitating structures through proper methods, such as carbon fiber reinforced polymer (CFRP), are required to prevent casualties that result from the collapse of earthquake-damaged structures. The main challenge of this issue is identifying the effect of CFRP on the occurrence of failure in the joint of a cross section with normal ductility. The present study evaluates the retrofitting method for a normal ductile beam-column joint using CFRP under monotonic and cyclic loads. Thus, the finite element model of a cross section with normal ductility and made of RC is developed, and CFRP is used to retrofit the joints. This study considers three beam-column joints: one with partial CFRP wrapping, one with full CFRP wrapping, and one with normal ductility. The two cases with partial and full CFRP wrapping in the beam-column joints are used to determine the effect of retrofitting with CFRP wrapping sheets on the behavior of the beam-column joint confined by such sheets. All the models are subjected to monotonic and cyclic loading. The final capacity and hysteretic results of the dynamic analysis are investigated. A comparison of the dissipation energy graphs of the three connections shows significant enhancement in the models with partial and full CFRP wrapping. An analysis of the load-displacement curves indicates that the stiffness of the specimens is enhanced by CFRP sheets. However, the models with both partial and full CFRP wrapping exhibited no considerable improvement in terms of energy dissipation and stiffness.