• Journal of the Microelectronics and Packaging Society
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• v.26 no.2
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• pp.31-43
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• 2019

In this study, polymer elastic bumps were fabricated for the flexible electronic package flip chip bonding and the viscoelastic and viscoplastic behavior of the polymer elastic bumps according to the temperature and load were analyzed using FEM and experiments. The polymer elastic bump is easy to deform by the bonding load, and it is confirmed that the bump height flatness problem is easily compensated and the stress concentration on thin chip is reduced remarkably. We also develop a spiral cap type and spoke cap type polymer elastic bump of $200{\mu}m$ diameter to complement Au metal cap crack phenomenon caused by excessive deformation of polymer elastic bump. The proposed polymer elastic bumps could reduce stress of metal wiring during bump deformation compared to metal cap bump, which is completely covered with metal wiring because the metal wiring on these bumps is partially patterned and easily deformable pattern. The spoke cap bump shows the lowest stress concentration in the metal wiring while maintaining the low contact resistance because the contact area between bump and pad was wider than that of the spiral cap bump.

• Computers and Concrete
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• v.12 no.5
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• pp.651-668
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• 2013

Concrete structures need repairing due to various reasons such as deteriorative effects, overloading, poor quality of workmanship and design failures. Cement based repair mortars are the most widely used solutions for concrete repair applications. Various factors may affect the bond strength between concrete substrate and repair mortars. In this paper, the effects of polymer additives, strength of the concrete substrate, surface roughness, surface wetness and aging on the bond between concrete substrate and repair mortar has been investigated. Full factorial experimental design is employed to investigate the main and interaction effects of these factors on the bond strength. Analysis of variance (ANOVA) under design of experiments (DOE) in Minitab 14 Statistical Software is used for the analysis. Results showed that the interaction bond strength is higher when the application surface is wet and strength of the concrete substrate is comparatively high. According to the results obtained from the analysis, the most effective repair mortar additive in terms of bonding efficiency was styrene butadiene rubber (SBR) within the investigated polymers and test conditions. This bonding ability improvement can be attributed to the self-flowing ability, high flexural strength and comparatively low air content of SBR modified repair mortars. On the other hand, styrene acrylate rubber (SAR) modified mortars was found incompatible with the concrete substrate.

• Polymer(Korea)
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• v.26 no.6
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• pp.737-744
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• 2002

Thermodynamic miscibility of the binary blends composed of semi-crystalline poly (butylene 2,6-naphthalate) (PBN) and amorphous poly (4-vinylphenol) (PVPh) was investigated using differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR) spectroscopy. DSC scan results showed that there was a single glass transition temperature (T$\_$g/) for each blend. Crystalline melting temperature (T$\_$m/) depression of the PBN in the blends was also observed with the increase of PVPh content. Both results of the single T$\_$g/ and the depression of T$\_$m/ for the PBN/PVPh blends indicate that the blends are thermodynamically miscible at the molecular level. FTIR spectroscopic analysis confirmed that strong intermolecular hydrogen bonding interactions between the ester carbonyl groups of the PBN and the hydroxyl groups of the PVPh are occurred.

• Korean Membrane Journal
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• v.10 no.1
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• pp.20-25
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• 2008

Proton conducting composite membranes were prepared by solution blending of poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-poly(sulfopropyl methacrylate) (P(VDF-CTFE)-g-PSPMA) graft copolymer and heteropolyacid (HPA). The P(VDF-CTFE)-g-PSPMA graft copolymer was synthesized by atom transfer radical polymerization (ATRP) using direct initiation of the secondary chlorines of P(VDF-CTFE). FT-IR spectroscopy revealed that HPA nanoparticles were incorporated into the graft copolymer via hydrogen bonding interactions. The water uptake of membranes continuously decreased with increasing HP A concentration up to 45wt%, after which it slightly increased. It is presumably due to the decrease in number of water absorption sites due to hydrogen bonding interaction between the HP A particles and the polymer matrix. The proton conductivity of membranes increased with increasing HPA concentration up to 45wt%, resulting from both the intrinsic conductivity of HP A particles and the enhanced acidity of the sulfonic acid of the graft copolymer.

• Bulletin of the Korean Chemical Society
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• v.24 no.7
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• pp.901-905
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• 2003

The lower critical solution temperature (LCST) of thermosensitive poly(organophosphazenes) with methoxypoly(ethylene glycol) (MPEG) and amino acid esters as side groups was studied as a function of saccharide concentration in aqueous solutions of mono-, di-, and polysaccharides. Most of the saccharides decreased the LCST of the polymers, and the LCST decrease was more prominently observed by saccharides containing a galactose ring, such as D-galactose, D-galactosamine and D-lactose, and also the polysacccharide, 1-6-linked D-dextran effectively decreased the LCST of the polymers. Such an effect was discussed in terms of intramolecular hydrogen bonding of saccharides in polymer aqueous solution. The saccharide effect was found to be almost independent on the kinds of the amino acid esters and MPEG length of the polymers. Such a result implies that the polymer-saccharide interaction in aqueous solution is clearly influenced by the structure of sacchardes rather than by that of the polymers. The acid saccharides such as D-glucuronic and D-lactobionic acid increased the LCST, which seems to be due to their pH effect.

• Journal of Adhesion and Interface
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• v.21 no.1
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• pp.20-26
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• 2020

Single lap-shear joints (SLJ) specimens with and without partial round fillets were fabricated to measure the average shear strength of adhesives. The effects of the length of the adherend on the SLJ specimens were also investigated. An epoxy adhesive was used to bond aluminum alloy. Tensile tests were performed on the adhesive bulk specimens to measure the mechanical properties. The finite element analysis (FEA) method was used to measure the adhesive stress distributions, i.e., the peel and shear stresses, on the bonded part. The experimental results revealed that the specimen consisting short length of adherend and without the partial round fillets exhibited the smallest average shear strength of adhesive among the investigated specimens. FEA revealed that the low average shear strength for the specimen with a short adherend length was caused by high stress concentrations on the adhesive at the edge of the bonded part.

• Structural Engineering and Mechanics
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• v.30 no.4
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• pp.403-426
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• 2008

Externally bonding fiber reinforced polymer (FRP) sheets with an epoxy resin is an effective technique for strengthening and repairing reinforced concrete (RC) beams under flexural loads. Their resistance to electro-chemical corrosion, high strength-to-weight ratio, larger creep strain, fatigue resistance, and nonmagnetic and nonmetallic properties make carbon fiber reinforced polymer (CFRP) composites a viable alternative to bonding of steel plates in repair and rehabilitation of RC structures. The objective of this investigation is to study the effectiveness of CFRP sheets on ductility and flexural strength of reinforced high strength concrete (HSC) beams. This objective is achieved by conducting the following tasks: (1) flexural four-point testing of reinforced HSC beams strengthened with different amounts of cross-ply of CFRP sheets with different amount of tensile reinforcement up to failure; (2) calculating the effect of different layouts of CFRP sheets on the flexural strength; (3) Evaluating the failure modes; (4) developing an analytical procedure based on compatibility of deformations and equilibrium of forces to calculate the flexural strength of reinforced HSC beams strengthened with CFRP composites; and (5) comparing the analytical calculations with experimental results.

• Journal of the Korea Concrete Institute
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• v.21 no.3
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• pp.275-282
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• 2009

The effects of surface treatment method of reinforcing fiber on the bonding strength between carbon fiber reinforced polymer rebar (CFRP rebar) and high strength concrete have been evaluated in this study. The structural PVA fiber is coated with a proprietary hydrophobicoiling agent and crimped type polyolefin based structural synthetic fiber is deformed with a geometrical modification were used for the reinforcing fiber. The compressive tests have been performed to evaluate the strength property of high strength concrete depending on the surface treatment method of fiber. The bonding property between the high strength concrete and the CFRP rebar was evaluated by means of direct bonding test. The test results indicated that the surface treatment method of fiber effect on the bonding behavior of high strength concrete and CFRP rebar. Also, as the development and propagation of splitting cracks were controled by adding fibers into the high strength concrete, the bonding behavior, bond strength and relative bonding strength of CFRP rebar and high strength concrete were significantly improved.

• Magazine of the Korea Concrete Institute
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• v.7 no.6
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• pp.233-241
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• 1995

In this thesis, the fatigue tests were performed on a series of R /C beams repaired with co& crete-lmlyrner composites to investigate the fatigue bahavior. The three point loading system is used in the fatigue tests. In these tests, relations between the repeated loading cycles and mid-span deflections, number of repeated loading cycles when repaired beams were fractured, the bonding performance of repair materials were observed. On this basis, the mid-span deflections, the crack growth and failure mode of repaired R /C beams were studied. A S-N curve was drawn to present the fatigue strength of repaired beams. From the test results, it was shown that behavior of R /C beams repaired with polymer-cement series were very sirnillar to control beam about bonding performance, mid-span deflections and fatigue strength according to S-N curve drawn by the regression anlysis on the fatigue test results.

• Journal of Korean Tunnelling and Underground Space Association
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• v.14 no.1
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• pp.79-91
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• 2012

A curved fiber reinforced polymer (FRP) panel is produced with a certain width depending on allowances of manufacturing processes and facilities. An targeted arch-shaped structure could be built by sequential connection of series of the FRP panels. The connection manner between the FRP panels could be given by chemical treatment, mechanical treatment and hybrid method. Among those, the connection between the panels by chemical treatment is commonly adopted. Therefore, For an optimized design of the connected part between FRP pannels, a number of direct shear tests have been undertaken in terms of a number of parameters: surface treatment conditions, bonding materials, etc.. As results, surface grinding condition by sand paper or surface treatment by sand blasting appear properly acceptable methods, and epoxy and acryl resins are shown to be effective bonding materials for the purpose in this study.