• 제목/요약/키워드: polyimide(PI)

검색결과 368건 처리시간 0.029초

폴리이미드/$\textrm{TiO}_2$ 나노 복합재의 합성 및 특성에 관한 연구 (A study on the synthesis and characterization of PI/$\textrm{TiO}_2$ nano-composite)

  • 이중희;이봉신;허석봉
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2001년도 추계학술발표대회 논문집
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    • pp.137-140
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    • 2001
  • Oragnic/inorganic hybrid materials prepared by sol-gel method have rapidly become a fasci nating research field in materials science. In this study, Polyimide/$\textrm{TiO}_2$ composites were synthesized from nano-sized anatase $\textrm{TiO}_2$ and two types of Polyimide (BTDA-PPD, PMDA-ODA) by Sol-gel method. Nano-sized $\textrm{TiO}_2$ particles were prepared from $\textrm{TiOEt}_4$ solution. The composites were charcaterized by using XRD, TGA, IR, TEM, and Atomic Force Microscope(AFM). $\textrm{TiO}_2$ nano particles were dispersed well in polyimide matrix and the thermal stability of polyimide was improved with $\textrm{TiO}_2$ nano-sized particles.

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네마틱 백정의 표면 액정 배향에관한 폴리이미드막의 분자 구조의 효과 (Effect of the Molecular Structure of Rubbed Polyimide Films for Surface Liquid Crystal Alignment of Nematic Liquid Crystal)

  • 서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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    • pp.232-234
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    • 1996
  • We have investigated the effect of molecular structure of polymer of rubbed polyimide (PI) films for surface liquid crystal alignment. To obtain surface alignment effect of Polymer molecular structure, we measured the polar (out of plane-tilt) anchoring strength and surface ordering of 5CB on rubbed PI surfaces. We have found that the polar anchoring strength of 5CB is depend on the polymer molecular structure of these unidirectionally rubbed PI surfaces.

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No-bias-bend pi cell using the rubbed polyimide mixture

  • 김대현;박홍규;김영환;김병용;옥철호;한정민;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.186-186
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    • 2009
  • Most liquid crystal display modes, including the twisted nematic (TN) $mode^1$, the in-plane switching (IPS) $mode^2$, the fringe field switching (FFS) $mode^3$, and the vertically aligned (VA) $mode^4$ are based on either a horizontal or a vertical alignment. However, for some applications, such as no-bias-bend (NBB) pi cell or bistable bend-splay display, an intermediate pretilt angle is essential$^5$. NBB pi cells have been a focus of interest because of their fast response time; however, the reliable control of the intermediate pretilt angle of liquid crystals that is required for the fabrication of NBB pi cells is challenging. The controllable pre-tilt angle of liquid crystals was investigated using a blend of horizontal and vertical polyimide prepared by a rubbing method. Various pretilt angles in the range from 0^{\circ}$ to 90^{\circ}$ were achieved as a function of the vertical polyimide content. We observed uniform liquid crystal alignment on the rubbing-treated blended polyimide layer. A NBB pi cell with an intermediate pretilt angle of 47.8^{\circ}$ was manufactured. This cell had no initial bias voltage and a low threshold voltage, which indicates that it has low power consumption. In addition, the response time of the NBB pi cell was rapid.

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새로운 이온빔장치를 사용한 Twisted Nematic-LCD의 전기광학특성 (Electro-optical Characteristics of Twisted Nematic(TN)-LCD using New Ion Beam Equipment)

  • 김상훈;황정연;장미혜;김귀열;서대식
    • 한국전기전자재료학회논문지
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    • 제19권6호
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    • pp.547-551
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    • 2006
  • We studied liquid crystal (LC) alignment with ion beam (IB) on polyimide and electro-optical characteristics of twisted nematic (TN)-liquid crystal display (LCD) on the polyimide surface using obliquely ion beam (IB) exposure with new IB type equipment. A good uniform alignment of the nematic liquid crystal (NLC) alignment with the ion beam exposure on the polyimide surface was observed. In addition, it can be achieved the good EO properties of the ion-beam-aligned TN-LCD on polyimide surface. Also, the EO characteristics of the ion-beam-aligned TN-LCD on a polyimide (PI) surface with ion beam exposure using new type IB equipment is same or more superior than ion-beam-aligned TN-LCD on a polyimide (PI) surface with ion beam exposure using Kaufman-type Ar ion gun.

혼합된 polymer에서의 틸트 감소 효과를 이용한 VA-$\pi$ mode LCD의 전기광학 특성 (EO Characteristics in the Vertical Alignment (VA)-$\pi$ mode LCD Using the Tilt Angle Decrease Effect on the Blended Polymer)

  • 이경준;황정연;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 제5회 학술대회 논문집 일렉트렛트 및 응용기술연구회
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    • pp.53-56
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    • 2003
  • Blending effects for generating a pretilt angle in nematic liquid crystal (NLC) with negative dielectric anisotropy on the blended polyimide (PI) of homeotropic and homogeneous alignment surface were studied. Also, we investigated the EO performances for the advanced VA-$\pi$ cell using this homeotropic blended PI surface. A many decrease of tilt angle on the polymer surface to blend homeotropic PI and homogeneous PI with side chain type was measured, and the tilt angle decreased as blended ratio and rubbing strength increase. The blended effects for generating a pretilt angle were clearly observed, and the many decrease of tilt angle can be achieved by using the blended PI surface. The electro-optical (EO) characteristics using the advanced VA-$\pi$ cell using the homeotropic blended PI surface than that of conventional VA cell can be improved. We suggest that the developed advanced VA-$\pi$ cell on a homeotropic blended PI surface is a promising technique for the achievement of a fast response time, and a high contrast ratio.

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수직 복합 폴리머 표면을 이용한 Advanced VA-$\pi$ cell의 전기광학 특성 (EO Characteristics in the Advanced Vertical Alignment VA-$\pi$ Cell on a Homeotropic Blended Polymer)

  • 이경준;황정연;한은주;백승권;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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    • pp.530-533
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    • 2002
  • Blending effects for generating a pretilt angle in nematic liquid crystal (NLC) with negative dielectric anisotropy on the blended polyimide (PI) of homeotropic and homogeneous alignment surface were studied. Also, we investigated the EO performances for the advanced VA-$\pi$ cell using this homeotropic blended PI surface. A many decrease of tilt angle on the polymer surface to blend homeotropic PI and homogeneous PI with side chain type was measured, and the tilt angle decreased as blended ratio and rubbing strength increase. The blended effects for generating a pretilt angle were clearly observed, and the many decrease of tilt angle can be achieved by using the blended PI surface. The electro-optical (EO) characteristics using the advanced VA-$\pi$ cell using the homeotropic blended PI surface than that of conventional VA cell can be improved. We suggest that the developed advanced VA-$\pi$ cell on a homeotropic blended PI surface is a promising technique for the achievement of a fast response time, and a high contrast ratio.

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이온빔 배향을 이용한 수직 폴리이미드 표면에서의 틸트 각 제어 (Control of Tilt Angle on Homeotropic Polyimide Surface by Ion Beam Alignment)

  • 강동훈;김병용;강상훈;황정연;한진우;김종환;강희진;옥철호;오용철;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.288-289
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    • 2006
  • The tilt angle generation of nematic liquid crystal(NLC) on the homeotropic polyimide(PI) surface by the new Ion beam alignment method is studied. The tilt angle of NLC on the homeotropic PI surface for all incident angle is about 38and this has a stabilization trend. And the good LC alignment of the NLC on the PI surface by ion beam exposure of 45Incident angle was observed. Also the tilt angle of NLC on the homeotropic PI surface by ion beam exposure of 45Incident angle had a tendency to decrease as ion beam energy density increase. So we had known that pretilit angle could be controlled from verticality to horizontality.

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Synthesis and Properties of Polyimide Composites Containing Graphene Oxide Via In-Situ Polymerization

  • Zhu, Jiadeng;Lee, Cheol-Ho;Joh, Han-Ik;Kim, Hwan Chul;Lee, Sungho
    • Carbon letters
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    • 제13권4호
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    • pp.230-235
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    • 2012
  • In this study, reduced graphene oxide/polyimide (r-GO/PI) composite films, which showed significant enhancement in their electrical conductivity, were successfully fabricated. GO was prepared from graphite using a modified Hummers method. The GO was used as a nanofiller material for the preparation of r-GO/PI composites by in-situ polymerization. An addition of 20 wt% of GO led to a significant decrease in the volume resistivity of composite films by less than nine orders of magnitude compared to that of pure PI films due to the electrical percolation networks of reduced GO created during imidization within the films. A tensile test indicated that the Young's modulus of the r-GO/PI composite film containing 20 wt% GO increased drastically from 2.3 GPa to 4.4 GPa, which was an improvement of approximately 84% compared to that of pure PI film. In addition, the corresponding tensile strength was found to have decreased only by 12%, from 113 MPa to 99 MPa.

Electro-optical Characteristics of the One-side Rubbing TN-LCD on Polyimide Surface with Ion-beam Irradiation

  • Kim, Young-Hwan;Lee, Kang-Min;Kim, Byoung-Yong;Oh, Byeong-Yun;Han, Jeong-Min;Lee, Sang-Keuk;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
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    • 제9권5호
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    • pp.198-201
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    • 2008
  • The electro-optical (EO) characteristics of the one-side rubbing twisted nematic (TN) - liquid crystal display (LCD) on the polyimide (PI) surface with one-side ion beam (IB) irradiation were successfully studied. The good LC alignment for the one-side rubbing TN-LCD on the PI surface with one-side IB irradiation was observed. The suitable transmittance-voltage curves for the one-side rubbing TN-LCD on the PI surface with one-side IB irradiation were measured. Also, the good response time characteristics of the one-side rubbing TN-LCD on the PI surface with one-side IB irradiation were measured. The fast response time can be achieved for the one-side rubbing TN-LCD on the PI surface with one-side IB irradiation.

광배향을 이용한 플렉시블 STN 셀의 전기 광학 특성 (Electro-Optical Characteristics of Plastic STN Cell using photoalignment method)

  • 배유한;황정연;김종환;남기형;이휘원;김강우;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.1007-1009
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    • 2004
  • We investigated the electro-optical(EO) performances of the super twisted nematic liquid crystal display(STN-LCD) on the polyimide(PI) surface with polymer film using rubbing and photoalignment method. Monodomain alignment of the plastic STN-LCD can be observed. A faster response time for the photoaligned plastic STN-LCD on the polyimide(PI) surfaces can be achieved than rubbingaligned plastic STN-LCD.

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