• Title/Summary/Keyword: polyester resin

Search Result 244, Processing Time 0.024 seconds

Studies on Methacrylate Finish with Silk Fabrics and their Anticrease (Methacrylate 견직물가공과 방추도개선에 대한 연구)

  • 최병희;이양후
    • Journal of Sericultural and Entomological Science
    • /
    • v.28 no.2
    • /
    • pp.65-73
    • /
    • 1986
  • These studies are carried out to improve silk availability for anticrease by useing methacrylate monomer polymerization method with in silk fiber. For this purpose, degree of anticrease, stiffness and shrinkage of various silk fabrics, included finish or not, after repeat of washings and polyster fabric was compared as standard. The adopted samples are ; 1. Polyester, Georgette, Woven density…90cm-85g/m 2. Silk, Twill, Degumed, Light, Woven density…90cm-90g/m 3. Silk, Twill, Degumed, Heavy, Woven density…90cm-200g/m 4. Silk, Stain, Degumed, Light, Woven density…90cm-90g/m The reached results are as followings. 1. The results of improving on anticrease by the finished method were about ten per cent increase against their original samples. 2. The light density silks showed satisfactory improve for anticrease, but the heavy one remained as rather poor condition. 3. The results for degree of textile stiffness were investigated to make sure reserve their textile feeling and observed to be good condition upon the finish work. 4. Textile shrinkage after the repeat of soap wash was investigated on indivisual test sample and silk fabrics showed more shrinkage than polyester which it seemed to be tentering shrinkage druning their general finishing processes. 5. The investigation showed that anticrease, stiffness and shrinkage of the sample textile were more or less deteriorated regardless silk or polyester by the repeat of washings. These matters are considered that such results were obtained because of the fiber fatigue nature. 6. The report reached that silk textiles should be used by dry cleaning methed after finish of any resin finish to reserve their improved anticrease nature.

  • PDF

Void Formation Mechanism of Thermoset (열경화성 수지의 기공 생성 원인)

  • 강길호;박상윤
    • Polymer(Korea)
    • /
    • v.28 no.1
    • /
    • pp.35-40
    • /
    • 2004
  • The formation mechanism of void defect which deteriorate composite's property is various according to each composite process. In this paper, void formation and growth mechanism is analyzed by thermal analysis and GC/MS. We made a vacuum chamber for observing pressure effect. Thermal analysis has been done in various condition. Elements of volatiles during resin curing were turned out by GC/MS. The most of volatiles of polyester were composed of styrene (over 80%) and a small quantity of toluene. In case epoxy resin, butyl glycidyl ether was the main element of volatiles (over 90%). We concluded that the original sites of void growth existed in resin and they were eliminated by vacuum and heating process. And the growth of void was influenced by water, diluents, solvent, and reactants in resin.

Properties of Strength and Stress-Strain of Recycled-Plastic Polymer Concrete (폐플라스틱 재활용 폴리머콘크리트의 강도와 응력-변형률 특성)

  • Jo Byung-Wan;Koo Jakap;Park Seung-Kook
    • Journal of the Korea Concrete Institute
    • /
    • v.17 no.3 s.87
    • /
    • pp.329-334
    • /
    • 2005
  • The use of Polymer Concrete (PC) is growing very rapidly in many structural and construction applications such as box culverts, hazardous waste containers, trench lines, floor drains and the repair and overlay of damaged cement concrete surfaces in pavements, bridges, etc. However, PC has a defect economically because resin which be used for binder is expensive. Therefore the latest research is being progressed to replace existing resin with new resin which can reduce the high cost. Here, Polymer concrete using the recycled PET(polyethylene terephthalate) has some merits such as decrease of environmental destruction, decrease of environmental pollution and development of new construction materials. The variables of this study are amount of resin, curing condition and maximum size of coarse aggregate to find out mechanic properties of this. Stress-strain curve was obtained using MTS equipment by strain control. The results indicated that modulus of elasticity was increased gradually in an ascending branch of curve, as an increase of resin content. Compressive strength was the highest for resin content of $13\%$. And Compressive strength was increased as maximum size of coarse aggregate increases. The strain at maximum stress increases with an increase of resin content and size of coarse aggregate. For the descending branch of stress-strain curve the brittle fracture was decreased when it was cured at the room temperature compared to high temperature.

A Study on Development of Eco-friendly Wrap using Biodegradable Resin (생분해성 수지를 이용한 환경친화성 랩 개발에 관한 연구)

  • Lim, Mi-Jin;Sim, Jae-Ho;Choi, Jong-Moon;Kim, Young-Sik
    • Applied Chemistry for Engineering
    • /
    • v.16 no.6
    • /
    • pp.800-808
    • /
    • 2005
  • The compounding resin for biodegradable wrap was developed, and its manufacturing process and physical properties were studied. For these purposes, following factors were optimized: the types and amounts of raw resin material, anti-oxidants, and lubricants used. In this work, the stable compounding resin used to make biodegradable wrap was based on poly(butylene adipate-co-butylenesuccinate) (PBAS) and poly(butyleneadipate-co-butylene succinate-co-butyleneterephthalate) (PBAST). The improved properties of resin with an additive were investigated by melting flow index (MFI). From these results, the physical properties of compounding resin, based on PBAST, were more than those of PBAS. For PBAS, the Irganox 1010, 1076 and Irgafos TNPP as the first and second anti-oxidants, respectively, were good. For PBAST, the good first and second anti-oxidants, respectively, were Irganox 1076 and Mark PEP 36. The good lubricants for feeding PBAS and PBAST were glycerol monostearate and palmityl alcohol, respectively. The stability and tensile strength experiment of wrap were also investigated by the elution of heavy metals and universal testing machine (UTM), respectively. The decomposition ratio of developed wrap was increased proportional to the reclaiming time. The degradation ratio of compounding resin sample was about 60% after 40 days.

Effects of Temperature and Binder Components on Working Life of Fresh MMA Modified UP Polymer Concrete (굳지 않은 MMA개질 UP 폴리머 콘크리트의 사용가능시간에 미치는 온도와 결합재의 영향)

  • Yeon, Jung-Heum;Hyun, Sang-Hoon
    • International Journal of Highway Engineering
    • /
    • v.14 no.4
    • /
    • pp.51-61
    • /
    • 2012
  • PURPOSES : This study deals with the working life of polymer concrete, which is typically used as a repair or overlay material for portland cement concrete pavements. METHODS : In the scope of this study, laboratory testing was conducted on fresh MMA modified UP polymer concrete, which uses an MMA monomer for viscosity adjustment and strength improvement of UP resin. The experimental variables were temperature (-20 to $+20^{\circ}C$) and binder components (MMA, MEKPO, and DMA). RESULTS : The result showed that the optimum binder ratios for polymer concrete production were 12, 11, and 10 wt.% when the MMA contents were 20, 30, and 40 wt.%, respectively. The working life of polymer concrete depending on temperature and binder components could be expressed by a logarithmic functional formula. The coefficient of variation for each binder component was the highest for DMA content while the lowest for MEKPO content. Also, the contents of each binder component for ensuring the working life of 60 minutes were proposed. CONCLUSIONS : Ultimately, the present study derived a linear regression equation estimating 60 minutes working life based on the setting times of each binder component.

Tension Creep Model of Recycled PET Polymer Concrete with Flexural Loading (휨 하중을 받는 재생 PET 폴리머 콘크리트의 인장크리프 모델)

  • Chae, Young-Suk;Tae, Ghi-Ho
    • Journal of the Korean Society of Safety
    • /
    • v.27 no.5
    • /
    • pp.117-125
    • /
    • 2012
  • In recent years, polymer concrete based on polyester resin have been widely generalized and the research of polymer concrete have been actively pursued by the technical innovations. Polymer concrete is a composite consisting of aggregates and an organic resin binder that hardens by polymerization. Polymer concrete are stronger by a factor of three or more in compression, a factor of four to six in tension and flexural and a factor of two in impact when compared with portland cement concrete. In view of the growing use of polymer concrete, it is important to study the physical characteristics of the material, emphasizing the short term properties as well as long term mechanical behavior. If polymer concrete is to be used in flexural load-bearing application such as in beam, it is imperative to understand the deformation of the material under sustained loading conditions. This study is proposed to empirical and mechanical model of polymer concrete tension creep using long-term experimental results and mathematical development. The test results showed that proposed model has been used successfully to predict creep deformations at a stress level that was 20 percent of the ultimate strength and viscoelastic behavior of recycled-PET polymer concrete is linear of stress level up to 30 percent. It is expected that the present model allows more realistic evaluation of varying stresses in polymer concrete structures with a constant loading.

Study on the Preparation and Properties of Polyurethane-Acryl Emulsion Resin (폴리우레탄-아크릴 에멀젼 수지 제조 및 물성에 관한 연구)

  • Kim, Hong-Tae;Lee, Myung-Cheon
    • Applied Chemistry for Engineering
    • /
    • v.16 no.1
    • /
    • pp.39-44
    • /
    • 2005
  • In this study, polyurethane-acryl emulsion resins were synthesized from HDI (hexamethylene diisocyanate), IPDI (isophorone diisocyanate), Polyol, 2-HEMA (2-hydroxy ethylmethacrylate), n-BA (n-butyl acrylate) and MMA (methylmethacrylate). The effects of polyol types on the properties of polyurethane-acryl emulsion resin, such as degree of strength and water resistance and on the manufacturing process were investigated. In addition, the results were compared with those of acrylic emulsion. The test results showed that polyester type polyol demonstrated stronger tensile strength and higher water resistance with time than did acrylic emulsion and polyether type polyol.

Physical Properties and Flame Retardant Effects of Polyurethane Coatings Containing Pyrophosphoric Lactone Modified Polyesters (피로포스포릭 락톤 변성폴리에스테르를 함유한 폴리우레탄 난연도료의 물성 및 난연효과)

  • Jung, Choong-Ho;Choi, Yong-Ho;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
    • /
    • v.17 no.3
    • /
    • pp.203-211
    • /
    • 2000
  • Pyrophosphoric lactone modified polyester(PATT) that contains two phosphorous functional groups in one unit base resin structure was synthesized to prepare a non-toxic reactive flame retardant coatings. Then the PATT was cured at room temperature with isocyanate, Desmodur IL, to get a two-component polyurethane flame retardant coatings(PIPUC). Comparing the physical properties of the films of PIPUC with the film of non-flame retardant coatings, there was no degradation observed in physical properties by the introduction of a flame-retarding component into the resin. We found that the char lengths measured by $45^{\circ}$Meckel burner method were $3.1{\sim}4.4cm$ and LOI values recorded $27{\sim}30%$. These results indicate that the coatings prepared in this study is good flame retardant one. The surface structure of coatings investigated with SEM does not show any defects and phase separation.

Effect of Counterpart Roughness on Abrasive Wear Characteristics of Side Plate of FRP Ship (FRP 선박 외판재의 연삭마모 특성에 관한 상대재 거칠기의 영향)

  • Kim, Hyung-Jin;Koh, Sung-Wi;Kim, Jae-Dong
    • Journal of Ocean Engineering and Technology
    • /
    • v.22 no.6
    • /
    • pp.35-40
    • /
    • 2008
  • The effect of counterpart roughness on abrasive wear characteristics of side plate materials of FRP ship, which were composed of glass fiber and unsaturated polyester resin composites, were investigated at ambient temperature by pin-an-disc friction test. The friction coefficient, wear rate and cumulative wear volume of these materials against SiC abrasive paper were determined experimentally. The wear rate of these materials decreased rapidly with sliding distance and then maintained a constant value. It was increased as counterpart roughness was rougher in a wear test. The cumulative wear volume tended to increase nonlinearly with sliding distance and depended on applied load and sliding speed for these composites. It could be verified by SEM photograph of fracture surface that major failure mechanisms were overlapping layers, microcutting, deformation of resin, delamination, and cracking.

Basic study on selecting mold transfer paper for gloss exposed mass concrete (광택 노출콘크리트용 거푸집 전사지 선정에 관한 기초적 연구)

  • Lee, Jea-Hyeon;Kim, Min-Sang;Baek, Cheol;Kyung, Yeong-Hyeok;Han, In-Deok;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2016.10a
    • /
    • pp.15-16
    • /
    • 2016
  • Ways to efficiently manufacture gloss exposed mass concrete at an inexpensive price, in other words, ways to paste transparent transfer paper onto the surface of a combined mold has been designated as New Technology Article 191 by the Ministry of Land, Infrastructure and Transport. But if the difference in the coefficient of linear expansion between the mold's and transfer paper's material causes temperature to rise or fall, a wrinkly surface can appear. Therefore this study, by experimentally comparing the deformation characteristics between the mold material and transfer paper material upon changes in temperature, seeks to serve as a basic reference point for selecting the optimal transfer paper for different mold types. Study results revealed that for molds, polyester resin transfer paper is optimal, and for aluminum molds, acrylic resin transfer paper is.

  • PDF