• 제목/요약/키워드: polyester fiber

검색결과 444건 처리시간 0.03초

Dyeing Study on DMF-Modified Polyesters for Morphology Characterization

  • Park, Myung-Ja
    • The International Journal of Costume Culture
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    • 제5권2호
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    • pp.53-65
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    • 2002
  • Morphology of polyester fiber was physically modified by solvent treatment. PET fiber was treated with N,N-dimethylformamide (DMF) at 100, 120, $140^{circ}C$ for 10 minutes without tension. The structural changes in the morphology of DMF-induced modified PET fiber were FTIR and SEM analysis. Also dyeing behavior of DMF-treated polyester fibers with various disperse dyes was studied to detect changes of amorphous area in fine structure. DMF treatment resulted in increases in total void content, degree of crystallinity, trans isomer content, chain folding, segmental mobility and molecular packing, but it resulted in decreases in amorphous orientation, intermolecular forces and individual void size through longitudinal shrinkage, lateral welling and removal of oligomers. Void-size distribution could be estimated from the dye uptake with various sizes of disperse dyes. In contrast to the large increases in dye uptake with small dye molecules, there is no and little dye uptake with the bulkiest dye, which means that void size is bigger or smaller than the volume of each dye. Diffusion rates of dye molecules showed increases. This dyeing study revealed that the disperse dyeing is very effective method for characterizing the internal morphology of polyester fiber.

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Dispersant-free Dyeing of Polyester with Temporarily Solubilized Azo Disperse Dyes from Indole Derivatives

  • Lee, Jung-Jin;Lee, Won-Jae;Kim, Jae-Pil
    • Fibers and Polymers
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    • 제4권2호
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    • pp.66-70
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    • 2003
  • Temporarily solubilized azo disperse dyes based on 1,2-substituted indoles were synthesized and characterized. Dispersant-free dyeing of polyester by using the synthesized dyes has been investigated. The colour yields of the dyes on the polyester fabric were found to be highly dependent on the dyeing pH, optimum results being obtained at pH 5. The dyes exhibited good to excellent fastness properties on polyester while lightfastness was moderate.

부식 환경 하에서의 섬유강화복합재료의 마찰 및 마모 특성 연구 (A Study on the Frictional Characteristics of Fiber Reinforced Composites under Corrosive Environment)

  • 박충용;박동현;박수정;김윤해
    • Composites Research
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    • 제36권1호
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    • pp.37-41
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    • 2023
  • 선박의 평형수처리장치 전해조 내부 용액은 해수를 전기분해 시 DSA(Dimension Stable Anode) 전극에서 생성되는 수산화물로 인하여 높은 알칼리성 분위기를 생성한다. 본 연구에서는 기존 평형수처리장치 배관에 사용되어지는 PE 코팅 강관 배관의 취약성을 대체 가능한 복합재료로써 4가지 소재를 선정하였으며, 이들 BRE(Basalt fiber reinforced epoxy), BRP(Basalt fiber reinforced unsaturated polyester), GRE(Glass fiber reinforced epoxy), GRP(Glass fiber reinforced unsaturated polyester)를 강 알칼리성 NaOH 용액에 720시간 침지 후 마찰 및 마모 시험을 통하여 재료 마찰 깊이에 따른 마찰계수와 섬유와 수지 간 계면 결합 거동을 분석하였다. 그 결과, 수지와 섬유 간의 게면 분리 현상에 대한 메커니즘을 도출하였다. 또한, 불포화폴리에스테르와 같이 상대적으로 낮은 계면 결합력의 갖는 소재의 경우, 알칼리성 용액에 침지 시간이 길어질수록 표면에서부터 시작된 열화가 내부로 급격하게 확산되어 마찰 계수의 감소로 이어지는 경향을 나타냈다.

친환경 섬유소재에 대한 대학생들의 인식도 연구 (University Students' Awareness of Eco-friendly Textile Fiber)

  • 이선영;이승구;김정화;이정순
    • 한국생활과학회지
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    • 제21권4호
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    • pp.781-790
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    • 2012
  • In midst of growing interest and awareness towards sustainability and being "green", there has been increased demand for sustainable clothing. In the purpose of boosting eco-friendly textiles industry, this research was conducted by investigating environmentally-conscious clothing behavior of university students and assessing their views on eco-friendliness of fibers. Thus, their awareness on recycled polyester fiber was evaluated. The research was conducted by surveying 257 university students residing in Daejeon. The data were analyzed with descriptive statistics, factor analysis, and reliability analysis, using SPSS 19.0. The results were as follows. 1) The majority of the subjects answered "Disposing clothing in the clothing recycling container" to reduce environmental impact. 2) Six factors of eco-friendliness of fiber were extracted as reutilization, unfinishedness, economics, environment preservation, natural materials, and slow fashion by using factor analysis. 3) Subjects scored organic cotton as most eco-friendly among various fibers. Recycled polyester fiber was graded less sustainable than natural fiber, but more eco-friendly than artificial one. 4) In assessment of subject's awareness of recycled polyester fiber, they highly valued on resource-reutilization and economics, but less valued on its hygiene, thermal insulation and health-functionality.

접착제 접합된 자연섬유강화 복합재료의 파괴 강도특성에 미치는 섬유방향의 영향 (Effect of Fiber Orientation on Failure Strength Properties of Natural Fiber Reinforced Composites including Adhesive Bonded Joints)

  • 임재규;윤호철;이상용
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2005년도 추계학술발표대회 개요집
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    • pp.94-96
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    • 2005
  • This paper is concerned with a fracture strength study of composite adhesive lap joints. The tensile and peel tests were carried out on specimen manufactured hybrid stacked composites such as the polyester and bamboo natural fiber layer. The main objective of the work was to test the failure strength of adhesive bonded joints using hybrid stacked composites with a polyester and bamboo natural fiber layer adjacent to the fiber orientation. From results, the load directional orientation, small amount and low thickness of bamboo natural fiber layer have a good effect on the tensile and peel strength of natural fiber reinforced composites. and these characters are have a great influence on fracture strength and failure shape of adhesive bonded joints using hybrid stacked composites in the difference of fiber orientation.

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폴리우레탄함침 폴리에스터 극세사 소재의 분산염료 염색시 폴리우레탄 성분에 대한 염료의 상대염착률 정량분석 (Quantitative Analysis of Relative Adsorption of Disperse Dyes on Polyurethane in Polyurethane-impregnated Polyester Microfibers)

  • 전희정;박수현;이준헌;김태경
    • 한국염색가공학회지
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    • 제32권3호
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    • pp.121-127
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    • 2020
  • The analysis method of relative adsorption of disperse dyes on impregnated polyurethane resin and polyester fiber separately was investigated. The solvents for extracting the dyes from polyurethane resin and polyester fiber were determined by acetone and DMF, respectively. By extracting the dyed fibers with acetone at room temperature within 30 minutes, the dyes adsorbed only on the polyurethane resin could be extracted. And then by additional extracting the same fabrics with DMF at 95℃ for longer than 1 hour, the dyes adsorbed on polyester fabrics was extracted. This means that the dyes adsorbed on polyurethane and polyester could be extracted separately and that relative adsorption of the dyes on the both components could be analyzed quantitatively. Using this analysis method, the relative adsorption of a disperse dye was investigated after reduction clearing with various conditions.

Effect of Graft Copolymerization Conditions on Grafting Yield of AA and MA onto Polyester Fiber

  • Park, Myung-Ja
    • The International Journal of Costume Culture
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    • 제6권2호
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    • pp.134-146
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    • 2003
  • Polyester of linear homopolymer poly(ethylene terephthalate)(PET) was chemically modified through the formation of branched copolymer to improve the undesirable properties of fiber. Photo-induced graft copolymerization of the acrylic monomers acrylic acid (AA) and methyl acrylate (MA) in the liquid and vapor phase, respectively, onto N,N-dimetylformamide (DMF)-pretreated PET fibers was carried out. The effect of various synthesis conditions and DMF pretreatment of the PET on the graft yield was investigated. Grafting mechanism was analysed. The grafting was promoted by increasing DMF pretreatment temperature and amount of DMF retention in the fiber. The increasing biacetyl and monomer flow time, and irradiation time enhanced the grafting up to a certain amount and thereafter it decreased.

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초극세 폴리에스테르 섬유의 염색성 (Dyeing Properties of Polyester Ultrarmicrofiber)

  • 정동석;김호정;이문철
    • 한국염색가공학회지
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    • 제11권3호
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    • pp.1-8
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    • 1999
  • Polyester ultrarmcrofiber(UMF, fiber fineness : 0.05d) and the other three kinds of polyester fibers(0.52, 1.04 and 2.08d) were dyed with two disperse dyes, C.1. Disperse Red 60 and Blue 56. Dyeing rates and absorption isotherms of these dyes have been measured at 100, 115 and $130^\circ{C}$ in water system. The dye bath was maintained at pH 5.0 with acetic acid(0.1mo1/1) /sodium acetate(0.1mo1/1) buffers and a liquor ratio of 1000:1. The absorption isotherms from two disperse dyes are nearly linear up to the saturation values, which increase with the temperature of dyeing. Dye uptake decreased with the fiber fineness in lower temperature $100^\circ{C})$, whereas increased in higher temperature$(130^\circ{C})$. A comparatively greater quantity of dye is necessary to dye ultrarmcrofiber fabrics than conventional fabrics. Disperse Blue 56 having a good build-up property is agreed to Fothergill's equation, which is inversely varied with the fiber fineness by the quantity of dye necessary to obtain a given shade.

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