• Fibers and Polymers
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• 제7권4호
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• pp.352-357
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• 2006

The cotton fabrics were pretreated by sodium 2-(2,3-dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino) benzenesulfonate (DBDCBS) at alkaline condition ofroom temperature and then dyed with four disperse dyes having amino groups (C.I. Disperse Yellow 9, C.I. Disperse Red 11, C.I. Disperse Blue 56 and C.I. Disperse Violet 1) at acidic condition of high temperature. A novel hetero-bifunctional bridge compound, DBDCBS, has two reactive groups such as dichloro-striazinyl group and ${\alpha},\;{\beta}$-dibromopropionylamido group. The first has reactivity towards hydroxy group of cellulosic fiber and the second shows reactivity towards amino groups of disperse dye containing amino groups. The results indicate that it is possible to dye polyester/cotton blend at one-bath dyeing using one kind of disperse dye containing amino groups. Therefore, two kinds of dyeing methods such as two-bath process one-bath dyeing and one-bath process one-bath dyeing were investigated and their dyeabilities were compared. The differences between these two methods were negligibly small so that perfect one-bath one-step dyeing of polyester/cotton blend by one kind of disperse dye was achieved.

• Fibers and Polymers
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• 제3권3호
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• pp.85-90
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• 2002

Five temporarily solubilized reactive disperse dyes were synthesized and characterized. They were applied to polyester/cotton blend fabric using one-bath dyeing method without dispersing agent. The dye that has azonaphthalene chro-mophore seemed to not only be exhausted on polyester but also react with cotton. But other dyes were selectively dyed on polyester and showed limited uptake on cotton. Good levelling as well as moderate to good colour fastness was obtained with the dyes on P/C blend fabric.

• 한국염색가공학회지
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• 제18권3호
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• pp.1-9
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• 2006

In order to dye polyester/cotton blend fabric by one-bath dyeing process with single disperse dye, a novel hetero-bifunctional bridge compound(DBDCBS) was synthesized and utilized. The DBDCBS was designed to contain two different reactive groups such as ${\alpha},{\beta}$-dibromopropionylamido and dichloro-s-triazinyl groups. The ${\alpha},{\beta}$-dibromopropionylamido group shows considerable reactivity towards amines or amino groups at acidic condition and high temperature. In contrast, the dichloro-s-triazinyl group has reactivity towards hydroxyl groups at alkaline condition and room temperature. In order to examine whether as a bridge the compound could combine dyes containing amino groups with cellulosic substrates, disperse dyes containing amino group were tried to dye the cotton fibers pretreated with the DBDCBS compound. By the results, polyester/cotton blends were dyed by one-bath dyeing process with single disperse dye,1,4-diaminoanthraquinone.

• 한국염색가공학회지
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• 제19권1호
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• pp.1-11
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• 2007

Dyeing of polyester/cotton blends is usually carried out through the two-bath or one-bath two-step dyeing method using proper disperse dyes and reactive dyes for each fiber. However, the dyeing requires relatively long and complicated procedure as well as there are some problems such as lower dyeability. In the present study, new one-bath one-step dyeing process was investigated using disperse dyes having amino groups and hetero-bifunctional bridge compound(DBDCBS) including dichloro-s-triazinyl groups and ${\alpha},{\beta}$-dibromopropionylamido groups to improve the dyeability of cotton component in polyester/cotton blends. And the one-bath dyeing properties of polyester/cotton blends was evaluated by various dyeing conditions such as pH, temperature and dye concentration, The optimum dyeing condition was pH 4 and $110-120^{\circ}C$. Color fastness were relatively good because of the colvalent bond formation between DBDCBS-reacted cotton fiber and disperse dye.

• 한국염색가공학회지
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• 제20권1호
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• pp.16-21
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• 2008

In this study the effects of swelling and fixing agent for the cotton side of polyester/cotton blended fabrics and the thermosol temperature on the dyeing properties and fastness. were investigated, when the polyester/cotton blended fabrics were dyed with a disperse dye which was able to dye both side of fiber by one bath one step thermosol process. The obtained results are as follows; The dye adsorption decreased with the increase of cotton blend ratio in polyester/cotton blended fabrics, when the ratio of swelling and fixing agent for cotton side was constant. As the thermosol temperature increased up to $210^{\circ}C$, the dye adsorption were increased, but that effect was less significant when the cotton blend ratio was higher.