• 제목/요약/키워드: polycarbonate

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Characterization of recycled polycarbonate from electronic waste and its use in hydraulic concrete: Improvement of compressive performance

  • Colina-Martinez, Ana L. De la;Martinez-Barrera, Gonzalo;Barrera-Diaz, Carlos E.;Avila-Cordoba, Liliana I.;Urena-Nunez, Fernando
    • Advances in concrete construction
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    • v.5 no.6
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    • pp.563-573
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    • 2017
  • Transparency, excellent toughness, thermal stability and a very good dimensional stability make Polycarbonate (PC) one of the most widely used engineering thermoplastics. Polycarbonate market include electronics, automotive, construction, optical media and packaging. One alternative for reducing the environmental pollution caused by polycarbonate from electronic waste (e-waste), is to use it in cement concretes. In this work, physical and chemical characterization of recycled polycarbonate from electronic waste was made, through the analysis by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), energy dispersive spectroscopy (EDS) and scanning electron microscope (SEM). Then cement concrete was made with Portland cement, sand, gravel, water, and this recycled polycarbonate. Specimens without polycarbonate were produced for comparison purposes. The effect of the particle sizes and concentrations of recycled polycarbonate within the concrete, on the compressive strength and density was studied. Results show that compressive strength values and equilibrium density of concrete depend on the polycarbonate particle sizes and its concentrations; particularly the highest compressive strength values were 20% higher than that for concrete without polycarbonate particles. Moreover, morphological, structural and crystallinity characteristics of recycled polycarbonate, are suitable for to be mixed into concrete.

The Effects of Plasma Treatments on the Surface Energy of the Polycarbonates and on the Adhesion Strength of the Cu Film/Polycarbonate Interface (플라즈마 표면처리에 의한 폴리카보네이트의 표면에너지 및 구리박막과의 접착력 변화에 관한 연구)

  • Cho Byeong-Hoon;Lee Won-Jong;Park Young-Ho
    • Korean Journal of Materials Research
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    • v.15 no.11
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    • pp.745-750
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    • 2005
  • Polycarbonates are widely used as housing materials of electronic handsets. Since the polycarbonate is electrically insulating, there should be a conducting layer on the polycarbonate for EMI shielding. In this study, we sputter deposited Cu films on the polycarbonate substrates for EMI shielding. Plasma treatments of polycarbonates were used to increase the adhesion strength of the Cu film/polycarbonate interface. The surface energy of the polycarbonate was greatly increased from $30mJ/m^2 \;to\; 65mJ/m^2$ by a 200 W $O_2$ plasma treatment for 10s. It is thought that this is because of the ion bombardment. The adhesion strength of the sputter deposited Cu film to the polycarbonate was quantitatively measured by a 4 point bending tester. A moderate plasma surface treatment of the polycarbonate increased the Cu film/polycarbonate adhesion strength by $30\%$. The EMI shielding efficiency of the sputter deposited $10{\mu}m$ Cu lam on the polycarbonate showed 90dB in the range of 100MHz to 1000MHz.

Review of the Polycarbonate (Polycarbonate의 고찰)

  • Choi, Gei-Hun
    • Journal of Korean Ophthalmic Optics Society
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    • v.9 no.2
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    • pp.313-322
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    • 2004
  • Glasses are to be classified in organic glasses and inorganic glasses. Generally, we just call glasses instead of calling inorganic glasses and call synthetic resin or plastic instead of calling organic glasses. One of the ophthalmic plastic glasses develops into polycarbonate resin in organic glasses. Recently, polycarbonate resin is widely known because it has larger index and impact than plastic lens. Ours study analyzed about polycarbonate resin in ophthalmic substance.

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Adhesion of Cu on Polycarbonate Modified by O2/ Ar Plasma Treatment (O2/ Ar 플라즈마 처리에 의해 개질된 폴리카보네이트 기판에서 Cu의 밀착성)

  • Park, Jun-Kyu;Kim, Dong-Won;Kim, Sang-Ho;Lee, Youn-Seoung
    • Korean Journal of Materials Research
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    • v.12 no.9
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    • pp.740-746
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    • 2002
  • In this study, the polycarbonate surface was treated by $O_2$/ Ar gases plasma for the enhancement of adhesion with Cu electrode. From the point of view of hydrophilicity and the functionality, the micro-roughness, new functional groups and oxygen content of the polycarbonate surface were increased by the $O_2$/ Ar gases plasma treatment. The Cu films deposited on the as-received polycarbonate were easily detached while, after the$ O_2$/ Ar gases plasma treatment the adhesive Cu films on polycarbonate could be obtained. These results can be explained that the polycarbonate had a hydrophilic surface with uniform micro-roughness and new functional groups by $O_2$/ Ar gases plasma treatment. Therefore,$O_2$/ Ar gases plasma treatment is a promising method for improvement of adhesion between polycarbonate and Cu electrode.

Preparation and characterization of isosorbide based PET/polycarbonate blends (Isosorbide가 함유된 바이오 기반 PET와 polycarbonate 블렌드의 제조 및 특성 연구)

  • Park, Ji-Soo;Nam, Byeong-Uk;Park, Jun-Seo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.2
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    • pp.1216-1221
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    • 2014
  • Poly(ethylene-co-isosorbide terephthalate) (PEIT) is interest in polymer which has isosorbide monomer that is renewable resources such as corn. However, there is important drawback which is low mechnical properties as increasing isosorbide contents. In this study, polycarbonate used to make up for drawback of mechanical properties of PEIT. In addition, PEIT used to improve the tensile elongation of polycarbonate because PEIT has good sheet proccessability. The effect of polycarbonate on morphology, thermal and mechanical properties were investigated using FE-SEM, DMA, TGA, UTM, and notched izod impact strength tester. As a result of this study, PEIT/PC blends were in compatible system and polycarbonate can act as an improvement of thermal stability and mechanical properties in the blends.

Synthesis and Self-healing Properties of Waterborne Polyurethane Based on Polycarbonate and Polyether Polyol (폴리카보네이트계 및 폴리에테르계 폴리올 기반 자가치유 기능 수분산 폴리우레탄 합성과 특성)

  • Kwon, Seon-Young;Park, Soo-Yong;Paik, In Kyu;Chung, Ildoo
    • Journal of Adhesion and Interface
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    • v.23 no.1
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    • pp.8-16
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    • 2022
  • In this study, self-healable waterborne polyurethane (SH-WPU) as shoes and coating materials with self-healable disulfide functionalities was synthesized by mixing polyether polyol to impart excellent durability and heat resistance and polycarbonate polyol to impart excellent mechanical properties. The synthesized SH-WPU was characterized by fourier transform-infrared spectroscopy (FT-IR), and physical and self-healing properties were confirmed through universal testing machine (UTM) and scanning electron microscope (SEM) measurements. Tensile strength and hardness were increased and elongation was decreased by using polycarbonate polyol. In addition, as a result of comparison of thermal properties, thermal stability has been increased as the content of polycarbonate polyol increased. The healing efficiency showed the highest efficiency when poly(tetramethylene ether)glycol : polycarbonate polyol = 0.75 : 0.25, and it was confirmed that the damaged part was healed through surface observation using a microscope and SEM.

Nano-graphene oxide damping behavior in polycarbonate coated on GFRP

  • Mohammad, Afzali;Yasser, Rostamiyan;Pooya, Esmaeili
    • Structural Engineering and Mechanics
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    • v.84 no.6
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    • pp.823-829
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    • 2022
  • This study considered the experimental parameters (Nano-graphene oxide reinforced polycarbonate, GFRP) under low-velocity impact load and vibration analysis. The effect of nano-graphene oxide (NGO) on a polycarbonate-based composite was studied. Two test procedures were adopted to obtain experimental results, vibration analysis. The mechanical tests were performed on damaged and non-damaged specimens to determine the damaging effect on the composite specimens. After the test was carried out, the effect of NGO was measured and damping factors were ascertained experimentally. 0. 2 wt% NGO was determined as the optimum amount that best affected the Vibration Analysis. The experiments revealed that the composite's damping properties were increased by adding the nanoparticles to 0.25 wt% and decreased slightly for the specimens with the highest nanoparticles content. Cyclic sinus loading was applied at a frequency of 3.5 Hz. This paper study the frequency effect of 3.5khz frequency damage on mechanical results. Found that high frequency will worthlessly affect the fatigue life in NGO/polycarbonate composite. In 3.5 Hz frequency, it was chosen to decrease the heat by frequency. Transmission electron microscopy (TEM) micrographs were used to investigate the distribution of NGO on the polycarbonate matrix and revealed a homogeneous mixture of nano-composites and strong bonding between NGO and the polycarbonate which increased the damping properties and decreased vibration. Finally, experimental modal analysis was conducted after the high-velocity impact damage process to investigate the defect on the NGO polycarbonate composites.

Polycarbonate Engineering Thermoplastic from the Industrial Point of View

  • Choi, Jae-Ho;Kim, Doe
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.144-145
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    • 2006
  • It is well known that the aromatic polycarbonate of bisphenol A (hereafter BPA polycarbonate) possesses superior transparency, exceptional toughness, high heat resistance and mechanical properties, which allow it to be diversely used for automotive, electrical, electronic, appliance and optical industries. In this paper, polycarbonate is reviewed on not only prospects of technology but market trend from the industrial point of view. It also demonstrates the diverse applications of polycarbonates with respect to its development history.

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An Experimental Study on Magnetic Assisted Polishing of Polycarbonate Plate for Recycling (폴리카보네이트 판재의 재활용을 위한 자기연마 가공)

  • Lee, Yong-Chul;Kim, Kwang-Sam;Kwak, Tae-Soo;Lee, Jong-Ryul
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.3
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    • pp.1-6
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    • 2013
  • This study has focused on transparency recovering of the polycarbonate by polishing its surface for recycling. The polycarbonate has many properties such as excellent mechanical strength, electrical insulating, superior heat resistance to other plastic material and especially good transparency. It has been used as barrier for the traffic noise at the roadside and the greenhouse for the palm house. But the polycarbonate has changed slightly as time goes by 10 years because of exposure to the strong sunlight and oxidization in the atmosphere, as result has lost its transparency. Magnetic assisted polishing has been utilized as an effective polishing method to recover the transparency of polycarbonate. The polycarbonate which has been used for 10 years was adopted as the sample. The first surface roughness of the sample was 1$1.23{\mu}mRa$, $7.5{\mu}mRz(DIN)$ respectively. In the experimental results, it showed that the surface roughness of the polished sample improved $0.013{\mu}mRa$, $0.08{\mu}mRz(DIN)$ from the first surface roughness respectively. The surface roughness get almost back again by magnetic assisted polishing. These results also showed that the magnetic assisted polishing was efficient machining method to reuse the polycarbonate material.