• Title/Summary/Keyword: polyamide

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Multiple Polyamide Fiber Reinforced Shotcrete for Railway Tunnel Structure (철도 터널 구조물 시공을 위한 다발형 폴리아미드섬유 보강 숏크리트)

  • Jeon, Joong-Kyu;Chung, Jae-Min;Yoon, Ji-Hyun;Jeon, Chan-Ki
    • Proceedings of the KSR Conference
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    • 2011.10a
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    • pp.1214-1219
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    • 2011
  • Fiber reinforced shotcrete began to be used in tunnel constructions because it facilitates and expedites the construction process, and improves reinforcement properties. As one of the most widely used forms of shotcrete used in tunneling, steel fiber reinforced shotcrete offers excellent strength and ductility and allows quick reinforcement. However, steel fibers tend to lump together in cement matrix, and low levels of water and acid resistance cause corrosion in steel fiber, resulting in cracks and delamination. In particular, rebound and backlash of steel fiber is significantly increased during steel fiber reinforced shotcrete construction, compromising the flexural toughness and quality of shotcrete. In order to resolve the problems associated with steel fiber reinforced shotcrete and improve the application, durability, and cost-effectiveness of shotcrete, this paper proposes methods for manufacturing and constructing tunnels with multiple polyamide fiber reinforced shotcrete. We performed experiments to evaluate the performance of the proposed shotcrete, and the experimental results indicate that the multiple polyamide fiber reinforced shotcrete proposed in this paper offers outstanding performance that meets various construction design criteria.

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Synthesis and Characterization of Dimer Acid-Based Polyamides (다이머산계 폴리아미드의 합성 및 특성에 관한 연구)

  • Park, Hyun Ju;Jeon, Ho Kyun;Oh, Sang Taek
    • Journal of Adhesion and Interface
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    • v.17 no.4
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    • pp.136-140
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    • 2016
  • In this study, a series of dimer acid-based polyamides with different diamines were synthesized by condensation polymerization and the polyamides were characterized by Fourier transform infrared spectroscopy (FT-IR). Effects of diamine structures on mechanical and thermal properties of polyamides were investigated. The tensile strength and lap shear adhesion strength of aromatic-based polyamide (DAP) were higher than those of aliphatic-based polyamide (DAH). In DSC thermogram, DAP has a high $T_g$ and $T_m$ compared with DAH. DAP's and DAH's softening point were $112-115^{\circ}C$ and $98-121^{\circ}C$, respectively.

Effects of the Membrane Materials on the Filtration Characteristic in the Membrane Separation-activated Sludge Process (막 재질에 따른 막분리활성오니법의 여과 특성)

  • Kim, Hyung-Soo;Cho, Sang-Il
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.2
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    • pp.42-49
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    • 1998
  • By checking the variations of the raw water quality and MLSS, the effects of the membrane materials on permeable flux and quality of the treated water were investigated in this study. Due to the stability for high variations of MLSS, tubular type membranes were selected. Polysulfone group membranes and polyamide group membranes were tested. The crossflow operation mode was adapted, because membrane fouling problems could be easily controlled by adjusting the linear velocity. Due to the high concentration of the raw water, polyamide group membranes were originally expected to achieve two times higher permeable fluxes. However, difference was only approximately $20l/m^2{\cdot}h$ at $3kgf/cm^2$. It might be resulted from the high concentration of organic materials in the effluent of the RBC process. For the quality of the treated water, polyamide group membranes were slightly less effective. It might be resulted from the fact that polysulfone group membranes had more adsorptive capacities for the organic materials. The effects of temperature on the permeable flux were found to be significant. Despite of the irregular injection of raw water, the quality of the treated water was kept stable.

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Electrical and Thermo-mechanical Properties of DGEBA Cycloaliphatic Diamine Nano PA and SiO2 Composites

  • Trnka, Pavel;Mentlik, Vaclav;Harvanek, Lukas;Hornak, Jaroslav;Matejka, Libor
    • Journal of Electrical Engineering and Technology
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    • v.13 no.6
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    • pp.2425-2433
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    • 2018
  • This study investigates a new organic based material and its dielectric and mechanical properties. It is a comprehensive nanocomposite comprising a combination of various types of nanofillers with hydrophobic silica nanoparticles (AEROSIL R 974) as a matrix modifier and a polyamide nano nonwoven textile, Ultramid-Polyamide 6, pulped in the electrostatic field as a dielectric barrier. The polymer matrix is an epoxy network based on diglycidyl ether of bisphenol A (DGEBA) and cycloaliphatic diamine (Laromine C260). The designed nanocomposite material is an alternative to the conventional three-component composites containing fiberglass and mica with properties that exceed current electroinsulating systems (volume resistivity on the order of $10^{16}{\Omega}{\cdot}m$, dissipation factor tan ${\delta}=4.7{\cdot}10^{-3}$, dielectric strength 39 kV/mm).

Study of Adhesion according to Various Surface Treatments for Lithium Ion Secondary Battery Pouch Film (다양한 표면처리에 따른 리튬이온 이차전지용 파우치 필름을 위한 접착성에 관한 연구)

  • Kim, Do Hyun;Bae, Sung Woo;Cho, Jung Min;Yoo, Min Sook;Kim, Dong Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.33 no.3
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    • pp.231-234
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    • 2016
  • Pouch film is manufactured by laminating aluminum foil, polyamide film and polypropylene film with an adhesive or extrusion resin. However, a surface treatment is required for the aluminum because bonding does not occur easily between the aluminum foil and the polymer film. Thus, for this study, surface treatment experiments were performed in order to confirm the effect on adhesion strength. First, a variety of surface treatment solutions were coated on aluminum foil, and contact angle and surface morphology analysis was carried out for the surface-treated aluminum. For lamination of the surface-treated aluminum foil with polyamide film, a polyurethane base adhesive was prepared for the adhesive strength test specimens. The adhesive strength between the aluminum foil and the polyamide film of the resulting specimens was measured (UTM). With such an experiment, it was possible to evaluate the effect on adhesive strength of the various surface treatments.

Sulfonation of Polyamide Containing Carboxylic Acid (Carboxylic acid를 함유한 sulfonated polynmide의 제조)

  • Jeon, Jong-Young;Lee, Gi-Jo
    • Journal of Sericultural and Entomological Science
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    • v.48 no.1
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    • pp.1-5
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    • 2006
  • Polyamide containing carboxylic acid was sulfonated with chlorosulfonic acid in dichloroethane under various conditions. The impact of the sulfonating agent concentration, the reaction temperature, and the reaction time on the ion exchange capacity was investigated. The mechanical and thermal properties, the contact angle, and the change of poly-dispersity were calculated for studying change of their properties. The reactions were effective, when the temperature was below $10^{\circ}C$ and the concentration of chlorosulfonic acid was below 0.05 mol. The value of ion exchange capacity was increased with reaction time. Thermal and mechanical properties were nearly unchanged according to the degree of sulfonation, but the contact angle was increased with increasing the value of ion exchange capacity.

Characterization of Synthetic Polyamides by MALDI-TOF Mass Spectrometry

  • Choi, Hae-Young;Choe, Eun-Kyung;Yang, Eun-Kyung;Jang, Sung-Woo;Park, Chan-Ryang
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2354-2358
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    • 2007
  • MALDI-TOF-MS technique was applied to obtain structural and compositional information of synthetic polyamides, Nylon6 and Nylon66. Mass spectra of both the original and the hydrolyzed polyamide samples were analyzed using the self calibration method as well as the internal calibration method with the standard materials of known masses. The MALDI-TOF mass spectra of Nylon6 samples showed the presence of protonated, sodiated, and potassiated ions that were assigned to cyclic and NH2/COOH terminated linear oligomers. From the MALDI-TOF mass spectra of Nylon66 samples, the potassiated linear oligomers with three different end groups are identified as well as the cyclic oligomers, i.e., NH2/COOH terminated oligomers, NH2/NH2 terminated oligomers, and COOH/COOH terminated oligomers. Full characterization of the molecular species and end groups present in the polyamide samples has been achieved, and also the changes in mass spectral patterns after the hydrolysis of the samples are presented.

Study for Applicability of Polymer and Polymer Coated Metal Materials within PBF System (PBF 시스템에서 고분자 및 금속 소재 적용성 연구)

  • Kim, Dong Soo;Bae, Sungwoo
    • Journal of the Korean Society for Precision Engineering
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    • v.32 no.9
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    • pp.765-771
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    • 2015
  • In an Additive Manufacturing (AM) system emplying the Powder Bed Fusion (PBF) system, polyamide-12 powder is currently recognized as the general material used. The Polyamide-12 powder's properties include an average particle size of 58 $58{\mu}m$, a density of 0.59 g/cm3, and melting point of $184^{\circ}C$, and can also be to used coat materials for metal powder. For this reason, the sintering process is similar to the polymer powder and polymer coated metal powder process, except during the post-process. The polyamide-12 powder has some disadvantages such as its high cost and the fact that it can only be used for the provided equipment from the maker. Therefore, this study aims to perform the applicability of new material, polymer and polymer coated metal, to the PBF system.

Nanofiltration of Dyeing Wastewater Using Polyamide Ro-Membranes after the Pretreatment with Chemical Coagulants

  • Hwang Jeong-Eun;Jegal Jonggeon;Mo Joonghwan;Kim Jaephil
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.58-66
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    • 2005
  • Nanofiltration (NF) of a dyeing wastewater was carried out using polyamide NF-membranes. Before applying the wastewater to the membrane process, it was pretreated with various chemical coagulants such as alum, ferric chloride and HOC-100A. In order to see the effect of the pretreatment of the wastewater using chemical coagulants on the membrane separation process, the optimum conditions for the coagulation and sedimentation process using the chemical coagulants were sought. By the pretreatment, despite the different coagulants used, the chemical oxygen demand (COD) and UV-absorbance of the wastewater were lowered by more than $70\%$. The pretreated wastewater was then applied to the membrane process. The effect of the coagulants used for the pretreatment on the membrane fouling was studied. From this study, it was found that the HOC-100A was the best out of the coagulants used far the removal of the materials that could cause membrane fouling.

Review on Changes in Surface Properties and Performance of Polyamide Membranes when Exposed to Acidic Solutions (산성용액 노출 시 폴리아마이드 분리막의 표면성질 및 투과성능 변화에 관한 총설)

  • Lee, Hyung Kae;Dao, Huyen Thi Thanh;Kang, Wooseok;Kwon, Young-Nam
    • Membrane Journal
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    • v.30 no.5
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    • pp.283-292
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    • 2020
  • Various kind of solutions need to be separated, purified, and concentrated using membranes in the field of industries. However, when the solution contains strong acids, the use of membrane is limited. Acid resistant membrane currently available in market does not show high efficiency of flux. This review explains the causes and mechanisms of changes in surface properties and performance of polyamide membranes when exposed to acidic solutions, and this can be used in the development of a membrane with acid resistance and high flux.