• Macromolecular Research
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• v.17 no.1
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• pp.58-61
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• 2009

• Journal of Integrative Natural Science
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• v.6 no.4
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• pp.211-214
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• 2013

In this study, in order to investigate how consecutive treatments of glass surface with HF acid and water vapor/Ar plasma affect the quality of 3-aminopropyltriethoxysilane self-assembled monolayer (APS-SAM), poly(3,4-ethylenedioxythiophene) (PEDOT) thin films were vapor phase-polymerized immediately after spin coating of FeCl3 and poly-urethane diol-mixed oxidant solution on the monolayer surfaces prepared at various treatment conditions. For the film characterization, various poweful tools were used, e.g., FE-SEM, an optical microscope, four point probe, and a contact angle analyzer. The characterization revealed that HF treatment is not desirable for the synthesis of a high quality PEDOT thin film via vapor phase polymerization method. Rather, sole treatment with plasma noticeably improved the quality of APS-SAM on glass surface. As a result, a highly dense and smooth PEDOT thin film was grown on uniform oxidant film-coated APS monolayer surface.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.1
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• pp.77-84
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• 2017

In this study, Poly-urethane acrylate (PUA) was synthesized by the reaction between Polycaprolactonetriol (PCLT) and Isophorone dissocyanate (IPDI) and hybridized with inorganic materials. Tetraethylortho silicate (TEOS) and nano clay (Closite 20A) were used as inorganic particles. For the hybridization of TEOS with PUA, sol-gel method is used, in which TEOS is made into spherical particle in the firsthand. In the case of Nano clay, hybridization is carried out through the dispersion as Nano clay has a layered structure. The solution of PUA hybrid was made into a film after UV curing and its thermo and electrical properties were measured. The experimental analysis and result demonstrate that the PUA hybrid shows an improved thermal properties and lower dielectric constant than that of the non-hybrid PUA. The trend of improved properties was different depending on structure of inorganic materials.

• Textile Coloration and Finishing
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• v.11 no.4
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• pp.1-7
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• 1999

Urethane-acrylate propelymers for secondary coating of optical fiber and high - performance material were prepared from the 4,4'-diphenylmethane diisocyanate(MDI), poly(tetramethylene oxide)glycol(PTMG, Mw 650 or 1000), 1,6-hexanediol(HD), 2-hydroxyethyl acrylate(HEA), and dibutyltin dilaurate as a catalyst. UV-Curable polyurethane acrylates were formulated from the urethane-acrylate prepolymers, three types of reactive diluents(DTs) having mono-, di-, and trifunctional-phenoxyethyl acrylate(PEA), hexanediol diacrylate(HDDA), and trimethylolpropane triacrylate(TMPTA), and 1-hydtoxycyclohexyl phenyl ketone(Irgacure 184) as a photoinitiator. The UV-cured films of polyurethane acrylates were obtained by curing using a medium-pressure mercury lamp(U W/cm, $\lambda_{max}=365\;nm)$. In this work, the effects of molecular weights of polyol and diol with low molecular weight into polymer chain on mechanical and dynamic mechanical properties of UV-cured polyurethane acrylates were studied. The structure and properties of the films obtained from the UV photopolymerization of urethane-acrylate prepolymer were investigated by FT-IR spectroscopy, dynamic mechanical measurement, tensile testing, and X-ray diffractometry.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.11a
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• pp.25-26
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• 2023

The internal core material and external color of a sandwich panel have a significant impact on the performance of the sandwich panel. For use on roofs and walls, the internal core material and external color must be considered. Therefore, the surface and back side temperatures were measured for each exterior color and inner core material type. For the internal core materials, urethane foam and Expanded Poly Styrene(EPS), which are core materials mainly used in sandwich panels, were selected. As colors, black and ivory were selected according to brightness, and a total of five colors were selected: red, blue, and green, which are the three primary colors of light. As a result, there were differences in surface and temperature depending on the external color and type of internal core material. Regardless of the color, the temperature was measured lower for panels with urethane foam than for panels with an internal core of EPS. This is believed to have been influenced by the difference in thermal conductivity of urethane foam being 0.023W/(m·K) and that of EPS being 0.032W/(m·K). In addition, panels with a black exterior color were found to have higher surface and back temperatures than panels of other colors, and ivory-colored panels had lower back temperatures regardless of the core material. This is proportional to the brightness and light-absorbing characteristics.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.1016-1018
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• 2002

Poly[bis (3,5-di-t-butyl-1,2-phenylene-1,2-thenylene)-1,4-phenylene-bis(11-oxyundecanylphenyl urethane)] (PV-PU) consisting of alternating a confined phenylenevinylene and a nonconjugated urethane segment in the main chain was synthesized by multistep, photoluminescence of PV-PU is emitted in the blue region with a maximum intensity at about 337 nm.

• Journal of Adhesion and Interface
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• v.23 no.2
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• pp.44-52
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• 2022

Epoxy resin has the disadvantage of being easily destroyed by instantaneous impact due to its high crosslinking density despite its high glass transition temperature (T_g) and excellent properties. To compensate for this, in this study, polyol was synthesized by ring opening polymerization of propylene glycol (PPG) diamine, Jeffamine D 2000 and propylene carbonate, and urethane modified epoxy was synthesized using this. The properties of the synthesized urethane modified epoxy were confirmed by FT-IR, H-NMR. To confirm the degree of improvement in impact resistance as an adhesive, a urethane modified epoxy adhesive was prepared by mixing a digylcidyl ether bisphenol A (DGEBA) with curing agent and curing accelerator. Properties test of urethane modified epoxy were shear strength, tensile strength and impact strength. As a result, excellent results were obtained in all test when the ratio of DGEBA : urethane modified epoxy was 8:2.

• Journal of Integrative Natural Science
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• v.6 no.4
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• pp.215-219
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• 2013

In this study, in order to investigate how consecutive treatments of glass surface with HF acid and water vapor/Ar plasma affect the quality of 3-aminopropyltriethoxysilane self-assembled monolayer (APS-SAM), poly(3,4-ethylenedioxythiophene) (PEDOT) thin films were vapor phase-polymerized immediately after spin coating of FeCl3 and poly-urethane diol-mixed oxidant solution on the monolayer surfaces prepared at various treatment conditions. For the film characterization, various poweful tools were used, e.g., FE-SEM, an optical microscope, four point probe, and a contact angle analyzer. The characterization revealed that a well prepared APS-SAM on a glass surface treated with water vapor/Ar plasma is very useful for uniform coating of FeCl3 and DUDO mixed oxidant solution, regardless of HF treatment. On the other hand, a bare glass surface without APS-SAM but treated with HF and water vapor/Ar plasma generally led to a very poor oxidant film. As a result, PEDOT films vapor phase-polymerized on APS-SAM surfaces are far superior to those on bare glass surfaces in the quality and electrical characteristics aspects.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2013.05a
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• pp.1255-1256
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• 2013

• Proceedings of the Korean Fiber Society Conference
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• 1998.04a
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• pp.9-13
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• 1998

A number of papers concerning the preparation and physical properties of thermotropic polyurethanes have been reported,$^{1.2}$ since thermotropic polyurethanes were first reported by Iimura and coworkers.$^3$ We have been studying the synthesis of thermotropic para-type aromatic polyurethanes containing alkylene spacers.$^{4.7}$ .(omitted)