• Title/Summary/Keyword: poly vinylidene fluoride (PVDF)

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Electrospinning of poly(vinylidene fluoride) with carbon nanotubes (Carbon nanotube를 포함한 PVDF/DMF 용액의 전기방사)

  • Kim, Yong-Tae;Chang Seoul;Zheng, Hai-Lan
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.183-186
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    • 2002
  • Polymer composites with carbon nanotubes have recently been investigated for improving certain properties i.e., electrical, optical and mechanical properties[1-3]. Kymakis et. al. have reported the electrical and optical properties of single wall carbon nanotube-poly(3-octylthiophene) composites[4]. Polyurethane dissolved in dimethylformanide (DMF) were electrospun by Demir et. al.[5]. (omitted)

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Study on the Hollow Fiber Nano-composite Membrane Preparation onto the Porous PVDF Membrane Surfaces using the Interfacial Polymerization (다공성 PVDF 막의 polyamide 계면중합법처리를 통한 나노 중공사 복합막 제조 연구)

  • Kang, Su Yeon;Cho, Eun Hye;Kim, Ihl hyung;Kim, Cheong Sik;Rhim, Ji Won
    • Membrane Journal
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    • v.24 no.2
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    • pp.107-112
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    • 2014
  • The composite membranes were prepared on the surface of hydrophobic porous poly (vinylidene fluoride) (PVDF) hollow fiber membranes through the interfacial polymerization. The preparation variables were the concentrations of piperazine (PIP), trimesoyl chloride (TMC) and the contents of polyethylene glyco l (PEG). The separation characterization of the resulting membranes were carried out for aqueous 100 ppm solution of NaCl, $CaSO_4$, and $MgCl_2$ and also mixed 300 ppm solution of NaCl and $CaSO_4$ in terms of the flux and rejection. Both the flux and rejection were the highest when the interfacial polymerization was conducted using TMC. When TMC concentration was 0.1 wt%, the flux and rejection were shown 48.3 LMH ($L/m^2{\cdot}hr$) and 59%, respectively. To improve the flux, the annealing post-treatment and the addition of PEG into piperazine were done. As expected, the overall flux was enhanced while the rejection was reduced.

Electro-Active Polymer Actuator by Employing Ionic Networking Membrane of Poly (styrene-alt-maleic anhydride)-Incorporated Poly (vinylidene fluoride) (이온성 망상구조막에 기반한 전기 활성 고분자 구동기)

  • Lu, Jun;Kim, Sang-Gyun;Lee, Sun-Woo;Oh, Il-Kwon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.11a
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    • pp.714-717
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    • 2007
  • In this study, a novel actuator was developed by employing the newly-synthesized ionic networking membrane (INM) of poly (styrene-alt-maleic anhydride) (PSMAn)-incorporated poly (vinylidene fluoride) (PVDF). Based on the same original membrane, various samples of INM actuator were prepared through different reduction times with the electroless-plating technique. The as-prepared INM actuators were tested in terms of surface resistance, platinum morphology, resonance frequency, tip displacement, current and blocked force, and their performance was compared to that of the widely-used traditional Nafion actuator. Scanning electron microscope (SEM) and transmission electron microscopy (TEM) revealed that much smaller and more uniform platinum particles were formed on the surfaces of the INM actuators as well as within their polymer matrix. Although excellent harmonic response was observed for the newly-developed INM actuators, this was found to be sensitive to the applied reduction times during the fabrication. The mechanical displacement of the INM actuator fabricated after optimum reduction times was much larger than that of its Nafion counterpart of comparable thickness under the stimulus of constant and alternating current voltage.

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Preparation and Anti-fouling Properties of PVDF Mixed Matrix Asymmetric Membranes Impregnated with 𝛽-cyclodextrin (𝛽-사이클로덱스트린을 함침시킨 PVDF 혼합기질 비대칭막의 제조와 내오염성 평가)

  • Shin, Sung Ju;Lee, Jong Sung;Lee, Jeong Gil;Youm, Kyung Ho
    • Membrane Journal
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    • v.31 no.6
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    • pp.434-442
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    • 2021
  • Poly(vinylidene fluoride) (PVDF) membrane has a good membrane durability because of its high mechanical resistance, thermal and chemical stability. However, the strong hydrophobic property of PVDF membrane can induce a low water permeability and easy fouling by proteins and organic matters. In order to improve the anti-fouling properties of PVDF membrane, the PVDF mixed matrix asymmetric membranes impregnated with biofunctional material 𝛽-cyclodextrin (𝛽-CD) in the membrane structure were prepared by phase inversion method. The membrane filtration experiments of pure water and BSA solution were performed using the PVDF/𝛽-CD mixed matrix asymmetric membranes prepared according to the 𝛽-CD contents. The experiments showed that the introduction of 𝛽-CD into the PVDF polymer matrix contributed to increase in the hydrophilic property of the PVDF membranes, and this led to the reduction of contact angles and improvement of anti-fouling properties. The PVDF/𝛽-CD membrane which was prepared using the dope solution with a 2 wt% 𝛽-CD content represented 64 L/m2·h of pure water flux, 95% of BSA rejection and maximum 80% of flux enhancements compared to flux results of the pristine PVDF membrane.

Nanogenerator Device Based on Piezoelectric Active Layer of ZnO-Nanowires/PVDF Composite (ZnO-나노와이어/PVDF 복합체를 압전 활성층으로 한 나노발전기 소자)

  • Lim, Young-Taek;Shin, Paik-Kyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.11
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    • pp.740-745
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    • 2014
  • ZnO nanowires were grown by hydrothermal synthesis process and piezoelectric poly vinylidene fluoride (PVDF) was then coated on top of the ZnO-nanowires by spray-coating technique. The composite layer of ZnO-nanowires/PVDF was applied to an energy harvesting device based on piezoelectric-conversion mechanism. A defined mechanical force was given to the nanogenerator device to evaluate their electric power generation characteristics, where output current density and voltage were examined. Electric power generation property of the ZnO-nanowires/PVDF based nanogenerator device was compared to that of the nanogenerator device with ZnO-nanowires as single active layer. Effect of the ZnO-nanowires on improvement of power generation was discussed to examine its feasibility for the nanogenerator device.

A study on microstrip antenna using PVDF (PVDF를 이용한 마이크로스트립 안테나에 관한 연구)

  • Kang, Hyun-Il;Song, Joon-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.224-225
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    • 2005
  • The microstrip patch antenna with PVDF (poly vinylidene fluoride) substrate, were experimentally studied at frequency 6 GHz. During the design of the essential elements of microstrip antenna, EM simulation tool Ensemble V 7.0 is used. We observed the resonant frequency by DC appled electric field in a microstrip patch antenna. This research has been made as an electronically tunable microstrip antenna, taking advantage of the voltage control dielectric substrate and piezoelectric properties substrate. We discuss the effect of substrates, electric field and piezoelectric phenomena in the PVDF microstrip antenna. The antenna frequency can be changed by varying the applied dc voltage. In this paper, we propose, a new technique to agile frequency of the microstrip antenna by using the PVDF piezoelectric substrate.

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Preparation and Properties of PVDF Multilayer Film

  • Han, Fei-Fei;Son, Tea-Won
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2009.03a
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    • pp.118-119
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    • 2009
  • As the rapid development of the electronics, the demand for portable electronics and wireless sensors is growing faster, also with the increased needs of one material which can power it automatically, and then power the electrical devices. The piezoelectric effect of the PVDF material can be used for this. So in this paper, PVDF multilayer films were made for this aim. Make the PVDF / DMAc solution in the 10% concentration; use the spin coater technique to make films with the optimum process parameters: the spin rate is 1260rpm; the spin time is 70s; the dry temperature is 100$^{\circ}C$; the dry time is 30mins. And also, for obtaining the higher $\beta$-phase crystallinity, put the Ca(NH3)2.4H2O into the PVDF / DMAc solution system.

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A Study on Fabrication and Characteristics of PVDF Ultrasonic Transducer (PVDF 초음파 변환기의 제작과 특성에 관한 연구)

  • Jung, Hong-Ryang
    • Journal of radiological science and technology
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    • v.23 no.2
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    • pp.33-37
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    • 2000
  • The authors fabricated ultrasonic transducer with PVDF[poly(vinylidene fluoride)] piezoelectric polymer film. When impulse waves were applied to the PVDF ultrasonic transducer, the dependence of the response properties on the backing material with copper was investigated through not only theoretical calculations using Mason's equivalent circuit but also experimental measurements. The experimental pulse response properties agree with those of the theoretical calculations and the pulses were shorter than those for a PZT transducer. If such short-pulse properties are used in an medical ultrasonic image diagnosis apparatus, the resolution of the apparatus will be improved. When the insertion loss was calculated theoretically to the PVDF ultrasonic transducer, the frequency characteristics of its showed wideband frequency.

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The Effect on Antioxidant for Improving to Radiation Resistance on Irradiated PVDF (PVDF의 내방사선 특성 향상을 위한 산화방지제 첨가효과)

  • Kim, Ki-Yup;Lee, Chung;Ryu, Boo-Hyung;Lim, Kee-Joe
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.252-253
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    • 2005
  • The dielectric relaxation properties of $^{60}Co$ gamma-ray irradiated Poly(vinylidene fluoride) (PVDF) containing various antioxidants have been investigated for radiation degradation. Cole-Cole's circular arcs were induced from the results of temperature and frequency dependency of dielectric properties with radiation dose. The magnitude of polarization of PVDF was decreased by adding antioxidants. The values of dielectric relaxation intensity calculated by using the Cole-Cole's circular arcs showed a certain tendency for radiation degradation.

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Water desalination by membrane distillation using PVDF-HFP hollow fiber membranes

  • Garcia-Payo, M.C.;Essalhi, M.;Khayet, M.;Garcia-Fernandez, L.;Charfi, K.;Arafat, H.
    • Membrane and Water Treatment
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    • v.1 no.3
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    • pp.215-230
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    • 2010
  • Poly(vinylidene fluoride-co-hexafluoropropylene), PVDF-HFP, hollow fiber membranes were prepared by the dry/wet spinning technique using different polyethylene glycol (PEG) concentrations as non-solvent additive in the dope solution. Two different PEG concentrations (3 and 5 wt.%). The morphology and structural characteristics of the hollow fiber membranes were studied by means of optical microscopy, scanning electron microscopy, atomic force microscopy (AFM) and void volume fraction. The experimental permeate flux and the salt (NaCl) rejection factor were determined using direct contact membrane distillation (DCMD) process. An increase of the PEG content in the spinning solution resulted in a faster coagulation of the PVDF-HFP copolymer and a transition of the cross-section internal layer structure from a sponge-type structure to a finger-type structure. Pore size, nodule size and roughness parameters of both the internal and external hollow fiber surfaces were determined by AFM. It was observed that both the pore size and roughness of the internal surface of the hollow fibers enhanced with increasing the PEG concentration, whereas no change was observed at the outer surface. The void volume fraction increased with the increase of the PEG content in the spinning solution resulting in a higher DCMD flux and a smaller salt rejection factor.