• Bulletin of the Korean Chemical Society
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• v.27 no.6
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• pp.835-840
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• 2006

Dimethyl 1-(4-nitrobenzoyl)-8-oxo-2,8-dihydro-1H-pyrazolo[5,1-a]isoindole-2,3-dicarboxylate has been used as an ionophore and o-nitrophenyloctyl ether as a plasticizer in order to develop a poly(vinyl chloride)-based membrane electrode for calcium ion detection. The sensors exhibit significantly enhanced response towards calcium(II) ions over the concentration range $8.0{\times}10^{-7}\;1.0{\times}10^{-1}$ M at pH 3.0-11 with a lower detection limit of $5.0 {\times}10^{-7}$ M. The sensors display Nernstian slope of 29.5 ${\pm}$ 0.5 mV per decade for Ca(II) ions. Effects of plasticizers, lipophilic salts and various foreign common ions are tested. It has a fast response time within 10 s over the entire concentration range and can be used for at least 2 months without any divergence in potentials. The proposed electrode revealed good selectivity and response for $Ca^{2+}$ over a wide variety of other metal ions. The selectivity of the sensor is comparable with those reported for other such electrodes. The proposed sensor was successfully applied as an indicator electrode for the potentiometric titration of a Ca(II) solution, with EDTA.

• Bulletin of the Korean Chemical Society
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• v.27 no.9
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• pp.1439-1444
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• 2006

A $Cu^{2+}$ ion-selective membrane microelectrode has been fabricated from poly vinyl chloride (PVC) matrix membrane containing a new symmetrical hexadentate Schiff,s base 2-{1-(E)-2-((Z)-2-{(E)-2-[(Z)-1-(2-hydroxyphenyl)ethylidene]hydrazono}-1-methylpropylidene)hydrazono]ethyl}phenol (HDNOS) as a neutral carrier, Potassium tetrakis(4-chlorophenyl) borate (KTpClPB) as an anionic excluder and o-nitrophenyloctyl ether (NPOE) as a plasticizing solvent mediator. The microelectrode displays linear potential response in the concentration range of $1.0\;{\times}\;10^{-5}-1.0\;{\times}\;10^{-11}$ M of $Cu^{2+}$. The microelectrode exhibits a nice Nernstian slope of 25.9 ${\pm}$ 0.3 mV $decade^{-1}$ in the pH range of 3.1-8.1. The sensor has a relatively short response time in whole concentration ranges ($\sim$5 s). The detection limit of proposed sensor is $5.0\;{\times}\;10^{-12}$ M (320 pg/L), and it can be used over a period of eight weeks. The practical utility of the sensor has been demonstrated by using it as an indicator electrode in the potentiometric titration of $Cu^{2+}$ with EDTA. The proposed membrane electrode was used for the direct determining of $Cu^{2+}$ content in black and red pepper, and in waste water samples.

• Fire Science and Engineering
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• v.29 no.4
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• pp.61-66
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• 2015

PVC pipe has excellent corrosion resistance and chemical resistance and is broadly used. However there are no regulations regarding exposed piping material in buildings. There is growing concern about the vulnerability of piping to fires and generating toxic gas. Exposed piping should be made of incombustible materials to prevent spreading of toxic gas and to minimize damage to life and property in case of fire. Many big structures are being built, and concerns regarding damage by fire are continuously growing. In these circumstances, we should reinforce fire safety standards for buildings and heighten safety consciousness to become a well-developed country. For these reasons, we investigated the materials used for exposed piping and the standards of well-developed countries to enhance safety. We tried to figure out the alternatives by examining the actual conditions of each region's buildings. Based on the use of incombustible materials for exposed piping in each region, we tried to enhance the effectiveness for safety by suggesting revisions for related laws and regulations.

• YAKHAK HOEJI
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• v.40 no.2
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• pp.135-140
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• 1996

Ion-selective poly(vinyl chloride)(PVC) membrane electrodes for the determination of the calcium antagonist verapamil and its pharmaceutical preparations were described. Verapam il-superchrome garnet Y(SGY), lumogallion(LG), acid red 97(AR97), Dragendorff(DD) and Meyer reagent ion pairs were inverstigated as an electroactive compound for membrane electrode. Stable potentiometric response was obtained with azo dye at pH 6.5-4.0 and with DD, and Meyer reagent at pH 6.5-3.0. The best plasticizer was 49w/w% 2-nitrophenyl octyl ether for azo dye, and 65.3w/w% tri(n-butyl) citrate for DD and Meyer reagent. Potentiometric response slopes of optimized membrane electrodes based on SGY, LG, AR97, DD, and Meyer complex for verapamil were 52.49, 54.88, 50.81, 54.13 and 49.31 mV/dec., respectively. Lower limits of linear range were $1.0{\times}10^6M$ for SGY, LG, and AR97, while those for DD and Meyer reagent were $4{\times}10^{-6}M$. Detection limits for all these electrodes were $1{\times}10^{-5}M,\;4{\times}10^{-6}M,\;1.8{\times}10^{-6}M,\;8{\times}10^{-7}M,\;and\;1{\times}10^{-6}M$ with relative standard deviation of 2.56, 3.6, 3.96, 2.56, 3.20%, respectively.

• Analytical Science and Technology
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• v.14 no.1
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• pp.59-63
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• 2001

A PVC membrane electrodes based on Fe(II)-dipyridyl-mefenamic acid ternary complex as ion exchanger were prepared using o-nitrophenyl octyl ether as a plasticizer. The 2,2'-dipyridyl, 4,4'-dipyridyl and 4,4'-dipyridyl-2,2'-dipyridyl were used as dipyridyl derivative ligand. The electrode dxhibits a fast stable and linear response for $10^{-5}-10^{-3}mol/L$ mefenamate with an anionic slope of -55.98, -49.47, -59.35mV/decade in pH 8.9 borate buffer solution respectively. Potentiometric selectivity measurements revealed negligible interferences from aromatic and aliphatic carboxylic acid salts.

• Journal of the Korean Wood Science and Technology
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• v.44 no.4
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• pp.600-606
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• 2016

Wood-based composite panels such as plywood, particleboard (PB), or medium density fiberboard (MDF) are mostly used in the lamination on their surface for the manufacturing of furniture, or interior building products, the concern on the formaldehyde emission (FE) from the surface laminated wood panels is increasingly attracting attentions from the public. Thus, this study was conducted to understand influence of surface laminating materials to the FE from PB and MDF with or without edge sealing, using 24-hour desiccator method. Both PB samples that had been laminated on their surface with low-pressure laminate (LPL) or polypropylene (PP) film and MDF that had been treated with poly(vinyl chloride) (PVC) or coating were tested for the FE with or without edge sealing. As expected, the FE of PB with the sealed edges decreased to 37.4% and 80.7% with the LPL and PP lamination, respectively. The surface laminated MDF with the sealed edges also showed a decrease in the emission up to 57.8% and 54.3%, with the PVC lamination and coating, respectively. However, the coated MDF samples showed 5.3% increase in the emission when their edges were not sealed, indicating a FE form the solvent used for coating. These results showed that the type of surface lamination materials on wood-based composite panels has a great impact on their resultant FE, indicating that the influence of surface laminating materials should be taken into consideration for the formaldehyde mission measurement.

• Bulletin of the Korean Chemical Society
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• v.30 no.10
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• pp.2303-2308
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• 2009

A thiocyanate poly(vinyl chloride) (PVC) membrane electrode based on [1,2-bis(diphenylphosphino)ethane]dihalopalladium( II), [(dppe)$PdX_2$, X = Cl ($L^1$), X = I ($L^2$)] as active sensor has been developed. The diiodopalladium complex, [(dppe)$PdI_2](L^2$) displays an anti-Hofmeister selectivity sequence: $SCN^-\;>\;I^-\;>\;{ClO_4}^-\;>\;Sal^-\;>\;Br^-\;>\;{NO_2}^-\;>\;{HPO_4}^-\;>\;AcO^-\;>\;{NO_3}^-\;>\;{H_2PO_4}^-\;>\;{CO_3}^{2-}$. The electrode exhibits a Nernstian response (-59.8 mV/decade) over a wide linear concentration range of thiocyanate ($(1.0\;{\times}\;10^{-1}\;to\;5.0\;{\times}\;10^{-6}$ M), low detection limit ($(1.1\;{\times}\;10^{-6}$ M), fast response $(t_{90%}$ = 24 s), and applicability over a wide pH range (3.5∼11). Addition of anionic sites, potassium tetrakis[p-chlorophenyl] borate (KTpClPB) is shown to improve potentiometric anion selectivity, suggesting that the palladium complex may operate as a partially charged carrier-type ionophore within the polymer membrane phase. The reaction mechanism is discussed with respect to UV-Vis and IR spectroscopy. Application of the electrode to the potentiometric titration of thiocyanate ion with silver nitrate is reported.

• Journal of the Korean Chemical Society
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• v.37 no.8
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• pp.773-778
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• 1993

Poly(vinyl chloride)(PVC) membrane electrodes based on the lipophilic neutral carrier, dibenzo-18-crown-6(DB18C6) and benzo-15-crown-5 (B15C5) as the active sensors for Tl$^+$ ion have been prepared and tested in different content of the potassium tetrakis(4-chlorophenyl)borate (KTClPB) as lipophilic salt. Dioctyl adipate (DOA), 2-nitrophenyl phenyl ether (NPPE) and o-nitrophenyl actyl ether (NPOE) were used as plasticizing solvent mediators. Electrodes exhibited good linear responses of 40∼55 mV decade$^{-1}$ for Tl$^+$ ion within the concentration ranges 10$^{-1}$∼10$^{-5}$M TlNO$_3$. Selectivity coefficients of interfering ions (alkali metal, alkaline earth metal and some transition metal ions) for Tl$^+$-ISE were determined by separate solution method and were sufficiently small for most of them. These crown ether type ion-selective electrodes are suitable for use with aqueous solution at pH > 3.

• Korean Journal of Materials Research
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• v.26 no.4
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• pp.173-181
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• 2016

In order to use coal tar pitch (CTP) as a raw material for carbon fibers, it should have suitable properties such as a narrow range of softening point, suitable viscosity and uniform optical properties. In this study, raw CTP was modified by heat treatment with three types of polymer additives (PS, PET, and PVC) to make a spinnable pitch for carbon fibers. The yield, softening point, C/H ratio, insoluble yield, and meso-phase content of various modified CTPs with polymer additives were analyzed by changing the type of polymer additive and the heat treatment temperature. The purpose of this study was to compare the properties of CTPs modified by polymer addition with those of a commercial CTP. After the pitch spinning, the obtained green fibers were stabilized and carbonized. The properties of the respective fibers were analyzed to compare their uniformity, diameter change, and mechanical properties. Among three polymer additives, PS220 and PET261 pitches were found to be spinnable, but the carbon fibers from PET261 showed mechanical properties comparable with those of a commercial CTP produced by an air-blowing method (OCI284). The CTPs modified with polymer additive had higher ${\beta}$-resin fractions than the CTP with only thermal treatment indicating a beneficial effect of carbon fiber application.

• Applied Chemistry for Engineering
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• v.2 no.2
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• pp.175-184
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• 1991

Ultraviolet curable coatings are often used to protect the surface of polymer materials exposed to the ultraviolet radiation. However, the adhesion of epoxy acrylate on poly(vinyl chloride) and the UV curable coating on polystyren are poor. The objective of this work was to improve the adhesion of coating according to various formulations of the reactive diluents and finishing methods using the photografting of multifunctional acrylate and the surface activation on polymer surface impregnated a phtoinitiator. The addition of Tripropylene glycole diacrlate in the formulation of coating results in the improvement of adhesion of coating due to the flexibility. But the increase of the crosslinking density which results from the oxidation of surface during the exposure of UV radiation caused the loss of adhesion of coating exept the photografting method. In the trimethylolpropane triacrylate the improvement of adhesion are considerable due to the chemical bond between multifundtional acrylate and surface. From this work we expect to achieve the varity and functionality in the formulation of coating according to the photografting and surface activating of polymer.