• Journal of Soil and Groundwater Environment
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• v.26 no.5
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• pp.20-28
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• 2021

Perfluorinated compounds(PFCs), an emerging environmental pollutant, are environmentally persistent and bioaccumulative organic compounds that possess a toxic impact on human health and ecosystems. PFCs are distributed widely in environment media including groundwater, surface water, soil and sediment. PFCs in contaminated solid can potentially leach into groundwater. Therefore, understanding PFCs partitioning between the aqueous phase and solid phase is important for the determination of their fate and transport in the environment. In this study, the sorption equilibrium batch and kinetic experiment of PFCs were carried out to estimated the sorption coefficient(K_d) and the fraction between aqueous-solid phase partition, respectively. Sorption branches of the PFDA(Perfluoro-n-decanoic acid), PFNA(Perfluoro-n-nonanoic acid), PFOA(Perfluoro-n-octanoic acid), PFOS(Perfluoro-1-octane sulfonic acid) and PFHxS(Perfluoro-1-hexane sulfonic acid) isotherms were nearly linear, and the estimated K_d was as follow: PFDA(1.50) > PFOS(1.49) > PFNA(0.81) > PFHxS(0.45) > PFOA(0.39). The sorption kinetics of PFDA, PFNA, PFOA, PFOS and PFHxS onto soil were described by a biexponential adsorption model, suggesting that a fast transport into the surface layer of soil, followed by two-step diffusion transport into the internal water and/or organic matter of soil. Shorter times(<20hr) were required to achieve equilibrium and fraction for adsorption on solid(F₁, F₂) increased with perfluorinated carbon chain length and sulfonate compounds in this study. Overall, our results suggested that not only the perfluorocarbon chain length, but also the terminal functional groups are important contributors to electrostatic and hydrophobic interactions between PFCs and soils, and organic matter in soils significantly affects adsorption maximum capacity than kinetic rate.

• International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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• v.23 no.1
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• pp.18-33
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• 1995

Under the synoptic scale strong westerly winds flowing over the large steep mountains in the eastern coastal region, the strong downslope wind storms such as internal gravity waves should be generated in the lee-side of mountain. Int he daytime as sea breeze circulation induced by meso-scale thermal forcing from sea toward inland confines to the offshore side of coastal sites due to the eastward internal gravity waves. Thus, surface winds near the coastal seas were relatively weaker than those in the open sea or the inland sites. Evidently, two different kinds of atmospheric circulations such as an internal gravity wave circulation with westerly wind and a sea breeze circulation with both easterly wind near the sea surface and westerly in the upper level were apparently produced. Under this situation the atmospheric pollutants at Kangnung city should be trapped by two different circulations in the opposite directions and resulted in the high concentrations of Total Suspended Particles (TSP) and ozone (O3). At night a meso-scale land breeze from land toward the more intensification of westerly winds in the coastal regions. The concentrations of TSP controled by the strong surface winds blowing from the mountain side toward the coastal sea were relatively higher at night than those in the daytime case and the concentrations of O3 due to the downward transport of ozone from the upper atmosphere toward the surface were also much higher at night than during the day. Consequently, the atmospheric pollutant concentrations in the mountainous coastal region under the downslope wind storms were higher than those after and before the occurrences of wind storms.

• Journal of the Korean GEO-environmental Society
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• v.15 no.4
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• pp.29-36
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• 2014

The purpose of this study investigates the delivery characteristics according to the load of pollutants by calculating the delivery rate of targeted areas on pollutants in Sapkyo reservoir. The main rivers of Sapkyo reservoir are Namwoncheon, Dogocheon, Sapkyocheon, Muhancheon and Gokgyocheon. The delivery rate and their characteristics of five major rivers during rainfall season are investigated. As th result, biochemical oxygen demand (BOD), total nitrogen (T-N) and total phosphorous (T-P) of total delivery rate are calculated by 0.40, 0.34 and 0.08, respectively. The delivery rate of T-P compares to other water quality is investigated relatively low. Looked at the overall characteristics of the watershed, the delivery rate of T-N and T-P is little change in the rate of the year, too. The delivery rate of T-N is calculated from 0.2 to 0.3 in the dry season, and from 0.31 to 0.39 in a flood, respectively. The delivery rate of T-P is calculated to more than 0.3 in the dry season, and 0.11 in a flood. It is similar values which the average annual delivery rate of T-P is 0.08. Therefore, the measured delivery rate of Sapkyo reservoir can be applicable such as a delivery rate of similar features of the terrain and land use.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.4
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• pp.439-458
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• 2005

An automated analysis system for water soluble constituents in $PM_{2.5}$ has been developed. The system consists of a high capacity multi tube diffusion scrubber (MTDS), a low temperature particle impactor (LTPI), and two ion (anion and cation) chromatography (IC) systems. Atmospheric particles have been collected by passing sample air through a thermostated MTDS followed by a LTPI. This system allows simultaneous measurements of soluble ions in $PM_{2.5}$ at 30 minutes interval. At the air sampling flow rate of 1.0L/min, the detection limits of the overall system are in the order of tens of $ng/m^3$. This system has been successfully used for the measurement of particulate components of Seoul air from April 2003 to January 2004. $SO_4^{2-},\;NO_3^-,\;NH_4^+,\;NO_2^-,\;Cl^-,\;Na^+,\;K^+,\;Ca^{2+},\;and\;Mg^{2+}$ are the major ionic species for $PM_{2.5}$ at Seoul. Among them, $SO_4^{2-},\;NO_3^-\;and\;NH_4^+$ are the most abundant ions, contributed up to $86\%$ of the total and the concentrations were higher than those in any other urban sites in the world except for Chinese cities. There are high pollutant episodes which contribute about $15\~20\%$ of annual average values of the major ions. During the episode, the all parcels were transported from the asian continent and $PM_{2.5}$ were significantly neutralized. This suggests that aged and long range transported pollutants caused the high pollutant episodes. They showed a distinct daily and seasonal variations:they showed a peak in the early morning caused by the night-time accumulation of particulate matters. Atmospheric reactions including gas-to-particle reactions and inter-particle reactions and meteorological parameters including relative humidity and ambient temperature were described with related to the $PM_{2.5}$ 5 concentrations. All of the ionic species showed higher concentrations during the spring than those for summer and winter.

• Korean Journal of Ecology and Environment
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• v.54 no.4
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• pp.265-271
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• 2021

Intertidal mud crab (Macrophthalmus japonicus) is an organism with a hard chitinous exoskeleton and has function for an osmotic control in response to the salinity gradient of seawater. Crustacean exoskeletons change in their natural state in response to environmental factors, such as changes in the pH and water temperature, and the presence of pollutant substances and pathogen infection. In this study, the ecotoxicological effects of irgarol exposure and heavy metal distribution were presented by analyzing the surface roughness of the crab exoskeleton. The exoskeleton surface roughness and variation reduced in M. japonicus exposed to irgarol. In addition, it was confirmed that the surface roughness and variation were changed in the field M. japonicus crab according to the distribution of toxic heavy metals(Cd, Pb, Hg) in marine sediments. This change in the surface roughness of the exoskeleton represents a new end-point of the biological response of the crab according to external environmental stressors. This suggests that it may affect the functional aspects of exoskeleton protection, support, and transport. This approach can be utilized as a useful method for monitoring the aquatic environment as an integrated technology of mechanical engineering and biology.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.6B
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• pp.653-663
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• 2008

The purpose of this study is to establish a database of weather, hydrology, point source pollution management, reservoir release and tillage management for SWAT model evaluation of Anseongcheon watershed ($370.1km^2$, the upstream of Gongdo water level gauging station), and to use them for the following research of future climate and land use change impact on streamflow and stream water quality. It is expected that the database can achieve the practical analysis of current watershed hydrologic and environmental condition. The model calibration and validation were conducted using the constructed database. The model results showed that the tillage management affected the temporal shift of pollutant loads, and changed the flow pattern of pollutant transport through cultivation area. It was identified that the April and May irrigation water supply from the agricultural reservoir also affected the streamflow of downstream. The data application of pollutants treatment facilities and tillage management of cultivation area showed about 10% difference in the simulation results of stream water quality. The data establishment of agricultural reservoir operation, the tillage management of cultivated area within the watershed and the attributes inclusion of pollutants treatment facilities were proved to be important in SWAT model evaluation. The results of model setup in this study are expected for more reliable model application in the following research of future climate and land use change impact on hydrology and stream water quality of the study watershed.

• Journal of Korean Society on Water Environment
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• v.35 no.6
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• pp.470-480
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• 2019

The Doam lake watershed was designated as a non-point pollution management area in 2007 to improve water quality based on watershed management implementation. There have been studies of non-point source reduction with respect to the watershed management impacting the pollutant transport of the reservoir. However, a little attention has been focused on the impact of water quality improvement by the management of the dam operation or the guidelines on the dam operation. In this study, the impact of in-lake management practices combined with watershed management is analyzed, and the appropriate guidelines on the operation of the dam are suggested. The integrated modeling system by coupling with the watershed model (HSPF) and reservoir water quality model (CE-QUAL-W2) was applied for analyzing the impact of water quality management practices. A scenario implemented with sedimentation basin and suspended matter barrier showed decrease in SS concentration up to 4.6%. The SS concentration increased in the scenarios adjusting withdrawal location from EL.673 m to the upper direction(EL.683 m and EL.688 m). The water quality was comparably high when the scenario implemented all in-lake practices with water intake at EL.673 m. However, there was improvement in water quality when the height of the water intake was moved to EL.688 m during the summer by preventing sediments inflow after the rainfall. Therefore, to manage water quality of the Doam lake, it is essential to control the water quality by modulating the height of water intake through consistent turbidity monitoring during rainfall.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.2
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• pp.220-224
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• 2017

Nitrogen dioxide ($NO_2$) is an important urban pollutant in Korea. Expecially, diesel vehicles are responsible for the most traffic rated nitrogen oxide ($NO_X$) emission, including nitric oxide (NO) and nitrogen dioxide ($NO_2$). Though nitrogen oxide ($NO_X$) emission from vehicle was applied a strict enforcement of emission standard, the specific $NO_2$ fraction in $NO_X$ ($NO_2/NO_X$) from various types of diesel vehicles was not understood. In order to investigate the fraction of $NO_2/NO_X$, the vehicle emission study was carried out at the facility of Transport Pollution Research Center (TPRC), National Institute of Environmental Research (NIER), Korea. Three different types of diesel vehicles(VAN, SUV, passenger) were tested on the NIER driving mode. The result of $NO_2/NO_X$ ratio was over 0.1 for all test vehicles and the highest $NO_2$ emission was observed at the van vehicle. The observation was showed that the emission trend of $NO_2/NO_X$ for passenger and SUV vehicles were inversely proportional. Also, as the emission standard has been strengthen, the emission rate of $NO_2$ has been decrease.

• Korean Journal of Environmental Agriculture
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• v.8 no.1
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• pp.37-46
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• 1989

A 2-dimensional pollutant transport phenomenon in shallow reservoirs was analyzed by using a finite element method. The Galerkin's weighted residual method, based on linear interpolation, was used and a triangle was adopted as an element. The two dimensional Stock's equation and the advection-diffusion equation integrated over depth were used as governing equations. Also the Newton-Raphson method was introduced to solve the non-linear terms of the equation. The results calculated by the model are in good agreement with the analytical solution for a simplified channel where a known solution is avaiable. An actual application of the model is attempted for Sapkyo Lake with a consideration of the influx of the Sapkyo Chun, the Muhan Chun and kogkyo Chun. Further refined research is needed to evaluate the water quality in the other reservoirs.

• Proceedings of the Korea Water Resources Association Conference
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• 2009.05a
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• pp.149-153
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• 2009

Physics-based distributed rainfall-runoff models are now commonly used in a variety of hydrologic applications such as to estimate flooding, water pollutant transport, sedimentation yield and so on. Moreover, it is not surprising that GIS has become an integral part of hydrologic research since this technology offers abundant information about spatial heterogeneity for both model parameters and input data that control hydrological processes. This study presents the development of a distributed rainfall-runoff prediction system for the Guem river basin ($9,835km^2$) using an Object-oriented Hydrological Modeling System (OHyMoS). We developed three types of element modules: Slope Runoff Module (SRM), Channel Routing Module (CRM), and Dam Reservoir Module (DRM) and then incorporated them systemically into a catchment modeling system under the OHyMoS. The study basin delineated by the 250m DEM (resampled from SRTM90) was divided into 14 midsize catchments and 80 sub-catchments where correspond to the WAMIS digital map. Each sub-catchment was represented by rectangular slope and channel components; water flows among these components were simulated by both SRM and CRM. In addition, outflows of two multi-purpose dams: Yongdam and Daechung dams were calculated by DRM reflecting decision makers' opinions. Therefore, the Guem river basin rainfall-runoff modeling system can provide not only each sub-catchment outflow but also dam inand outflow at one hour (or less) time step such that users can obtain comprehensive hydrological information readily for the effective and efficient flood control during a flood season.