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Effect of Temperature on the Deposition Rate and Bending Strength Characteristics of Chemical Vapor Deposited Silicon Carbide Using Methyltrichlorosilane (메틸트리클로로실란을 이용한 화학증착 탄화규소의 증착율 및 굽힘강도 특성에 미치는 온도의 영향)

  • Song, Jun-Baek;Im, Hangjoon;Kim, Young-Ju;Jung, Youn-Woong;Ryu, Hee-Beom;Lee, Ju-Ho
    • Composites Research
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    • v.31 no.2
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    • pp.43-50
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    • 2018
  • The effects of deposition temperature on chemical vapor deposited silicon carbide (CVD-SiC) were studied to obtain high deposition rates and excellent bending strength characteristics. Silicon carbide prepared at $1250{\sim}1400^{\circ}C$ using methyltrichlorosilane(MTS : $CH_3SiCl_3$) by hot-wall CVD showed deposition rates of $95.7{\sim}117.2{\mu}m/hr$. The rate-limiting reaction showed the surface reaction at less than $1300^{\circ}C$, and the mass transfer dominant region at higher temperature. The activation energies calculated by Arrhenius plot were 11.26 kcal/mole and 4.47 kcal/mole, respectively. The surface morphology by the deposition temperature changed from $1250^{\circ}C$ pebble to $1300^{\circ}C$ facet structure and multi-facet structure at above $1350^{\circ}C$. The cross sectional microstructures were columnar at below $1300^{\circ}C$ and isometric at above $1350^{\circ}C$. The crystal phases were all identified as ${\beta}$-SiC, but (220) peak was observed from $1300^{\circ}C$ or higher at $1250^{\circ}C$ (111) and completely changed to (220) at $1400^{\circ}C$. The bending strength showed the maximum value at $1350^{\circ}C$ as densification increased at high temperatures and the microstructure changed from columnar to isometric. On the other hand, at $1400^{\circ}C$, the increasing of grain size and the direction of crystal growth were completely changed from (111) to (220), which is the closest packing face, so the bending strength value seems to have decreased.

Seedling Plug and Cutting Method for Multi-propagation of Ornamental Miscanthus Spp. (조경용 억새의 대량번식을 위한 플러그묘와 삽목번식법)

  • Hwang, Kyung Sik;Joo, Song Tak;Ha, Soo Sung;Kim, Ki Dong;Joo, Young Kyoo
    • Weed & Turfgrass Science
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    • v.7 no.3
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    • pp.275-282
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    • 2018
  • Miscanthus species are known as a genus of eco-friendly and low-maintenance cost ornamental grasses. Plug and cutting methods were tested for multi-propagation of most promising ornamental Miscanthus species in greenhouse and field plot. The plug formation period with three different cell sizes with four cultivars (M. sinensis 'Andersson', 'Strictus', 'Gracillimus', 'Variegatus') were evaluated the seedling development stages with two irrigation types of the over-head and the bottom watering in greenhouse and field plot afterward during 2015-2016 season. In seedling plug test, the size of tray cell affected the plug formation. Bottom irrigation resulted positively on plant height, weight, root and tiller development compared with the over-head irrigation. Plug cell size affected the plant growth in the field after transplanting. All of the 3 Miscanthus species showed higher rates of successful propagation at the lower nodes before inflorescence formation (vegetative growth stage). To analyze the survival factors of M. xgiganteus cutting, the cutting time, node part, and culm diameter were tested as independent variables with the binary logistic model. The survival probability was influenced by node part and culm diameter significantly. The third and fifth node parts showed 0.12 (8X higher failure probability) and 0.02 (50X higher failure probability) times less survival probability. It means the survival probability will be increased by using older and lower part of cuttings during a vegetative growth stage before inflorescences of M. xgiganteus.

Rice Blast Control and Race Diversity by Mixed-Planting of Two Cultivars ('Hopyeongbyeo'/'Nampyeongbyeo') with Different Susceptibility to Magnaporthe oryzae (호평벼와 남평벼의 혼합재배에 의한 도열병 방제와 레이스 다양성의 변화)

  • Oh, In-Seok;Min, Ji-Young;Cho, Myung-Gil;Roh, Jae-Hwan;Shin, Dong-Bum;Song, Jin;Kim, Myeong-Ki;Cho, Young-Chan;Kim, Byung-Ryun;Han, Seong-Sook
    • Research in Plant Disease
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    • v.14 no.3
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    • pp.143-152
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    • 2008
  • Mixed-planting of two rice cultivars, HP ('Hopyeongbyeo') and NP ('Nampyeongbyeo'), having a dissimilar susceptibility to rice blast was practiced for chemical-free control of rice blast in the field. The HP/NP combination was selected for applying under mechanized agricultural conditions. Because they have similar genetic characteristics such as seed germination and heading time, culm length, rice quality and size of rice grains except susceptibility to blast. Incidence of panicle blast was reduced 50.4 % compare with supposed blast incidence by HP/NP mixed-planting when the seeds of two cultivars were combined 1 to 1 as weight. Supposed blast incidence was estimated from reduction of rice blast caused by addition of a resistant cultivar NP. Race diversity of Magnaporthe oryzae was examined for correlation with control effect of HP/NP mixed-planting on rice blast. The population of dominant race KJ-101 was diminished and replaced with various co-existing races and eleven new races were appeared in mixed-planting plot. Total number of race isolated from mixed-planting plot was not largely different from mono-culture. However, detection frequency of the new race was increased and variation of the population size of each race was decreased in mixed-planting plots. It was shown that a biased community with a dominant race (KJ-101 or KI-181) was altered to a balanced one of coexisting races. From these results, it was supposed that the balanced diversity among co-existing races within a community might be correlated to control effect by HP/NP mixed-planting on rice blast. Further more, it should be studied that genetic characteristics of the individual race including a virulence on cv. HP and NP was examined for verifying a correlation of mixed-planting effect and race diversity.

Plot Size for Investigating Forest Community Structure(I) -Adequate Number of Plots of Tree Stratum in a Mixed Deciduous Forest Community at Sobaeksan Area- (삼림군집구조 조사를 위한 조사구 크기에 관한 연구(I) -소백산지역 활엽수혼효림군집 교목층의 적정 조사구수-)

  • 박인협;이경재;조재창
    • Korean Journal of Environment and Ecology
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    • v.6 no.2
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    • pp.162-167
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    • 1993
  • A mixed deciduous forest community in Mt. Sobaek was studied to determine the adequate number of plots of tree stratum for investigating forest community structure. Twenty l0m $\times$ l0m plots were set up iii the studied forest community, and species area curve. performance curve and statistical method were carried out. According to species-area curve, the minimal number of plots where a given percentage increase in number of plots produced less than the same percentage increase in number of species was eight. The minimal number of plots where a given percentage increase in number of plots produced less than the half of the percentage increase in number of plots was eleven. According to performance curve by importance value of the major species, the minimal number of plots where the dominant species was distinguished from the subdominant species was five. The minimal number of plots where the subdominant species was distinguished from each other was ten. Therefore, ten l0m $\times$ l0m plots seems to give an adequate sample for investigating structure of the studied forest community. Similarity index between the ten plots and total twenty plots was above 90%, and 95% confidence interval of species diversity of the ten plots was $\pm$ 0.073.

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Plot Size for Investigating Forest Community Structure (IV) - Adequate Number of Plots for Shrub Stratum in a Mixed Forest Community of Abies holophylla and Broad-leaved Trees at Odaesan National Park - (삼림군집구조 조사를 위한 조사구 크기에 관한 연구(IV) - 오대산 국립공원지역 젓나무-활엽수 혼효림군집 관목층의 적정 조사구수 -)

  • 박인협;문광선
    • Korean Journal of Environment and Ecology
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    • v.9 no.2
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    • pp.197-201
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    • 1996
  • A mixed forest community of Abies holophylla and broad-leaved trees in Odaesan National Park was studied to determine the adequate number of plots of shrub stratum for investigating forest community structure. Thirty 5m*5m plots were set up in the shrub stratum, and species-area curve and performance curve were made out. The minimum number of plots where a given percentage increase in number of plots produce in number of plots produced less than the same percentage increase in number of species was six. The minimum number of plots where a given percentage increase in number of plots produced less than the half of the percentage increase in number of plots was eleven. The minimum number of plots where the dominant species was distinguished from the subdominant species was five. The minimum numver of plots where the first subdominant species was distinguished from other subdominant species was ten. The diffrence of species diversity(H') between five or more plots and total thirty plots was less than 0.05. Similarity index was more than 70% between five or more plots and total thirty plots, and more than 80% between ten or more plots and total thirty plots. The conclusion is that the adequate number of 5m*5m plots for the shrub stratum was about 5 in general case and about 10 in case of requiring more accuracy.

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A Study on Conductance Behaviors of Amine Salts in the Binary Solvent Mixtures. Methylammonium Chlorides in Methanol-Water Mixtures at $25^{\circ}C$ (혼합용매계에 대한 아민염의 전기전도도에 관한 연구. 메탄올-물 혼합계에 대한 메틸암모늄염의 전도도)

  • Sang Kee Yoon;Bong Kyu Kim;Uhm Tae Seop;Jong Yul Park
    • Journal of the Korean Chemical Society
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    • v.20 no.3
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    • pp.185-192
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    • 1976
  • Equivalent conductances of ammonium salts such as $NH_4Cl,\;CH_3NH_3Cl,\;(CH_3)_2NH_2Cl,\;(CH_3)_3NHCl\;and\;(CH_3)_4NCl$ have been measured in methanol-water mixtures of various composition (0.0${\sim}$0.6-mole frcation: m. f.) in the concentration range from 0.01 to 0.04 M at $25^{\circ}C$, and limiting equivalent conductances (${\Lambda}_0$) are determined by the analysis of Fuoss Onsager's semiempirical equation.The experimental results are discussed in terms of varing the size of ${\Lambda}_0$ due to the salts species and solvent composition. It has been observed in quite common over all salts that ${\Lambda}_0$ decreases with the increase of m. f. methanol, and the maximum decrement in ${\Lambda}_0$ shows between water and 0.1 m. f., while the plot of ${\Lambda}_0$ vs. m. f. goes through a minimum at 0.4 m. f. and then turns slightly upward. On the other hand, the ${\Lambda}_0$ decrease with the increase of the size of ammonium cation and the larger values ${\Lambda}_0$ are showed in comparison with those of values observed for the corresponding $n-RNH_3Cl$ under the same experimental procedure. All these behaviors are considered to be closely correlated with the structures of solvents and solutes and the significant similarities are compared with the behaviors of partial molar volumes for amine salts in same solvent system.

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Factor Analysis for Exploratory Research in the Distribution Science Field (유통과학분야에서 탐색적 연구를 위한 요인분석)

  • Yim, Myung-Seong
    • Journal of Distribution Science
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    • v.13 no.9
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    • pp.103-112
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    • 2015
  • Purpose - This paper aims to provide a step-by-step approach to factor analytic procedures, such as principal component analysis (PCA) and exploratory factor analysis (EFA), and to offer a guideline for factor analysis. Authors have argued that the results of PCA and EFA are substantially similar. Additionally, they assert that PCA is a more appropriate technique for factor analysis because PCA produces easily interpreted results that are likely to be the basis of better decisions. For these reasons, many researchers have used PCA as a technique instead of EFA. However, these techniques are clearly different. PCA should be used for data reduction. On the other hand, EFA has been tailored to identify any underlying factor structure, a set of measured variables that cause the manifest variables to covary. Thus, it is needed for a guideline and for procedures to use in factor analysis. To date, however, these two techniques have been indiscriminately misused. Research design, data, and methodology - This research conducted a literature review. For this, we summarized the meaningful and consistent arguments and drew up guidelines and suggested procedures for rigorous EFA. Results - PCA can be used instead of common factor analysis when all measured variables have high communality. However, common factor analysis is recommended for EFA. First, researchers should evaluate the sample size and check for sampling adequacy before conducting factor analysis. If these conditions are not satisfied, then the next steps cannot be followed. Sample size must be at least 100 with communality above 0.5 and a minimum subject to item ratio of at least 5:1, with a minimum of five items in EFA. Next, Bartlett's sphericity test and the Kaiser-Mayer-Olkin (KMO) measure should be assessed for sampling adequacy. The chi-square value for Bartlett's test should be significant. In addition, a KMO of more than 0.8 is recommended. The next step is to conduct a factor analysis. The analysis is composed of three stages. The first stage determines a rotation technique. Generally, ML or PAF will suggest to researchers the best results. Selection of one of the two techniques heavily hinges on data normality. ML requires normally distributed data; on the other hand, PAF does not. The second step is associated with determining the number of factors to retain in the EFA. The best way to determine the number of factors to retain is to apply three methods including eigenvalues greater than 1.0, the scree plot test, and the variance extracted. The last step is to select one of two rotation methods: orthogonal or oblique. If the research suggests some variables that are correlated to each other, then the oblique method should be selected for factor rotation because the method assumes all factors are correlated in the research. If not, the orthogonal method is possible for factor rotation. Conclusions - Recommendations are offered for the best factor analytic practice for empirical research.

Nitrogen fixation, and growth characteristics of Three Legume cover crops in no-tillage paddy field

  • Cho, Young-Son
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.4
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    • pp.308-315
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    • 2003
  • A field experiment was conducted to investigate the performance of three legume species in a zero-tillage, non-fertilized rice field in a temperate zone. Before the experiment for 5 years, from 1995 to 1999, plant growth patterns of three legume species grown as over-wintering (October-May) cover crops on a paddy field were maintained to study N balance and $\textrm{N}_2$ fixation. Decrease in plant density accelerated from after winter to flowering from 1,090, 320, and 5 to 732, 232, and 6 plants $\textrm{m}^{-2}$ in Chinese milk vetch (CMV), white clover (WC), and hairy vetch (HV), respectively. Total dry weights of plants above-ground level were 0.05, 0.11, and 2.43 g $\textrm{plant}^{-1}$. in WC, CMV and HV respectively but steeply increased at ripening up to 0.77, 2.33, and 26 g $\textrm{plant}^{-1}$. The root dry weight of HV and CMV rapidly increased while in WC, root dry weight increased slightly towards flowering. The highest nodule numbers were recorded in CMV to April thereafter WC produced the highest. Nodule size was distributed within 7mm in CMV but it was larger in HV varying from 1 to 10mm. Shoot N (g $\textrm{m}^{-2}$) greatly increased from over-wintering to flowering in CMV, HV and WC and it ranged from 1.66, 0.5 and 1.92 to 12.6, 3.1 and 13.02 g $\textrm{m}^{-2}$, respectively. After wintering, the initial shoot N content (%) was more in CMV. Root N content (%) was constant or slightly decreased in HV and WC. Soil total N in the control plot (clean fallow) was the highest on Mar. 2 then decreased rapidly to flowering. Soil N content was constant in HV plots whereas it was low in WC plots for the entire growth period except just after winter. Maximum nitrogenase activities were 9, 37.8, and 131 mol $\textrm{C}_2\textrm{H}_4$ $\textrm{plant}^{-1}$ $\textrm{hour}^{-1}$. in CMV, HV, and WC, respectively. Nitrogenase activity showed a direct correlation with nodule number, size and fresh weight. As a cover crop preceding a rice crop, CMV is more suited to colder regions due to its earlier ripening characteristics. Hairy vetch and WC are recommended for regions with a mild winter and a long summer owing to their late ripening and great N fixation activity.

Volatility of Export Volume and Export Value of Gwangyang Port (광양항의 수출물동량과 수출액의 변동성)

  • Mo, Soo-Won;Lee, Kwang-Bae
    • Journal of Korea Port Economic Association
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    • v.31 no.1
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    • pp.1-14
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    • 2015
  • The standard GARCH model imposing symmetry on the conditional variance, tends to fail in capturing some important features of the data. This paper, hence, introduces the models capturing asymmetric effect. They are the EGARCH model and the GJR model. We provide the systematic comparison of volatility models focusing on the asymmetric effect of news on volatility. Specifically, three diagnostic tests are provided: the sign bias test, the negative size bias test, and the positive size bias test. This paper shows that there is significant evidence of GARCH-type process in the data, as shown by the test for the Ljung-Box Q statistic on the squared residual data. The estimated unconditional density function for squared residual is clearly skewed to the left and markedly leptokurtic when compared with the standard normal distribution. The observation of volatility clustering is also clearly reinforced by the plot of the squared value of residuals of export volume and values. The unconditional variance of both export volumes and export value indicates that large shocks of either sign tend to be followed by large shocks, and small shocks of either sign tend to follow small shocks. The estimated export volume news impact curve for the GARCH also suggests that $h_t$ is overestimated for large negative and positive shocks. The conditional variance equation of the GARCH model for export volumes contains two parameters ${\alpha}$ and ${\beta}$ that are insignificant, indicating that the GARCH model is a poor characterization of the conditional variance of export volumes. The conditional variance equation of the EGARCH model for export value, however, shows a positive sign of parameter ${\delta}$, which is contrary to our expectation, while the GJR model exhibits that parameters ${\alpha}$ and ${\beta}$ are insignificant, and ${\delta}$ is marginally significant. That indicates that the asymmetric volatility models are poor characterization of the conditional variance of export value. It is concluded that the asymmetric EGARCH and GJR model are appropriate in explaining the volatility of export volume, while the symmetric standard GARCH model is good for capturing the volatility.

A study on slim-hole density logging based on numerical simulation (소구경 시추공에서의 밀도검층 수치모델링 연구)

  • Ku, Bonjin;Nam, Myung Jin;Hwang, Seho
    • Geophysics and Geophysical Exploration
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    • v.15 no.4
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    • pp.227-234
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    • 2012
  • In this study, we make simulation of density log using a Monte Carlo N-Particle (MCNP) algorithm to make an analysis on density logging under different borehole environments, since density logging is affected by various borehole conditions like borehole size, density of borehole fluid, thickness and type of casing, and so on. MCNP algorithm has been widely used for simulation of problems of nuclear particle transportation. In the simulation, we consider the specific configuration of a tool (Robertson Geologging Co. Ltd) that Korea institute of geoscience and mineral resources (KIGAM) has used. In order to measure accurate bulk density of a formation, it is essential to make a calibration and correction chart for the tool under considerations. Through numerical simulation, this study makes calibration plot of the density tool in material with several known bulk densities and with boreholes of several different diameters. In order to make correction charts for the density logging, we simulate and analyze measurements of density logging under different borehole conditions by considering borehole size, density of borehole fluid, and presence of casing.