• Title/Summary/Keyword: plate membrane

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고분자 전해질 연료전지용 분리판 최적 설계 (Optimal Design of Bipolar-Plates for a PEM Fuel Cell)

  • 한인수;정지훈;임종구;임찬;정광섭
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 춘계학술대회
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    • pp.99-102
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    • 2006
  • Optimal flow-field design of bipolar-plates for a commercial class PEM(polymer electrolyte membrane) fuel cell stack was carried out on the basis of three-dimensional computational fluid dynamics(CFD) simulation. A three-dimensional CFD model originally developed by Shimpalee et al., has been utilized for performing large-scale simulation of a single fuel cell consisting of bipolar-plates gas diffusion layers, and a membrane-electrode-assembly(MEA). The CFD model is able to predict the current density, pressure drops, gas velocities, vapor and liquid water contents, temperature distributions, etc. inside a single fuel cell. Depending on simulation results from the CFD modeling of a PEM fuel cell, several flow-fields of bipolar-plates were designed and verified. The final design of the bipolar-plate has been chosen from the simulations and experimental tests and showed the best performance as expected from the simulation results under a normal operating condition. Thus, the CFD simulation approach to design the optimal flow-field of the bipolar-plates was successful. The final design was adopted as the best flow-field to build a commercial scale PEM fuel cell stack, the performance of which shows about 42% higher than that of the older bipolar-plate design.

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Electricity Generation Coupled with Wastewater Treatment Using a Microbial Fuel Cell Composed of a Modified Cathode with a Ceramic Membrane and Cellulose Acetate Film

  • Seo, Ha-Na;Lee, Woo-Jin;Hwang, Tae-Sik;Park, Doo-Hyun
    • Journal of Microbiology and Biotechnology
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    • 제19권9호
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    • pp.1019-1027
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    • 2009
  • A noncompartmented microbial fuel cell (NCMFC) composed of a Mn(IV)-carbon plate and a Fe(III)-carbon plate was used for electricity generation from organic wastewater without consumption of external energy. The Fe(III)-carbon plate, coated with a porous ceramic membrane and a semipermeable cellulose acetate film, was used as a cathode, which substituted for the catholyte and cathode. The Mn(IV)-carbon plate was used as an anode without a membrane or film coating. A solar cell connected to the NCMFC activated electricity generation and bacterial consumption of organic matter contained in the wastewater. More than 99% of the organic matter was biochemically oxidized during wastewater flow through the four NCMFC units. A predominant bacterium isolated from the anode surface in both the conventional and the solar cell-linked NCMFC was found to be more than 99% similar to a Mn(II)-oxidizing bacterium and Burkeholderia sp., based on 16S rDNA sequence analysis. The isolate reacted electrochemically with the Mn(IV)-modified anode and produced electricity in the NCMFC. After 90 days of incubation, a bacterial species that was enriched on the Mn(IV)-modified anode surface in all of the NCMFC units was found to be very similar to the initially isolated predominant species by comparing 16S rDNA sequences.

Fatigue Analysis of LNG Cargo Containment System Connections in Membrane LNG Carrier

  • Park, Jun-Bum
    • Journal of Advanced Research in Ocean Engineering
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    • 제3권3호
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    • pp.112-124
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    • 2017
  • As an LNG carrier preserves and transports liquefied natural gas under minus $163^{\circ}C$, the cargo tank has to have sufficient hull strength against not only the wave loads but also against loads caused by loading and unloading and thermal expansion to keep the LNG safely. The main insulation types for a CCS are No.96 and Mark III from GTT for the membrane LNG carrier. Particularly, the invar membrane plate in No.96 is very thin and its connections could experience high local stresses owing to such dynamic loads. Therefore, it should be verified whether those connections have sufficient fatigue lives for the purpose of operation and maintenance. This research aims at performing fatigue analysis with 0.1 fatigue damage criteria for 40 years of design life to support new membrane CCS development using proper S-N curves and the associated finite element modeling technique for each connection and then propose a reasonable design methodology.

습식 상 전이법으로 제조된 Theophylline 각인 대칭 막의 선택적 흡착 (Selective Adsorption of a Symmetrie Theophylline Imprinted Membrane Prepare by a Wet Phase Inversion Method)

  • 박중곤;오창엽;서정일
    • KSBB Journal
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    • 제17권2호
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    • pp.207-211
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    • 2002
  • 습식 상 전환법으로 theophylline이 각인된 poly(acryloni-trile-co-acrylic acid) 막을 제조하였다. theophylline은 고분자가 공중합되는 과정에 각인시키거나(in-situ implanting) 제자리 동시 각인) 공중합된 고분자를 DMSO 용액에 녹이면서 template를 섞어 각인시켰다(post implanting, 후 각인). 막의 template molecule에 대한 흡착 선택도는 응고시키는 물의 온도가 높을수록, 혼합물의 초기 농도가 높을수록 크게 나타났다. 후 각인법으로 제조된 막의 흡착선택도가 제자리 동시각인 제작법으로 제조된 막보다 흡착선택도가 우수하였다.

양극산화에 의한 다공성 알루미나 막의 기체투과 특성 (Gas Permeation Characteristics of Porous Alumina Membrane Prepared by Anodic Oxidation)

  • 함영민
    • 환경위생공학
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    • 제13권3호
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    • pp.72-78
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    • 1998
  • For investigation into gas permeation characteristics, the porous alumina membrane with asymmetrical structure, having upper layer with 10 nanometer under of pore diameter and lower layer with 36 nanometer of pore diameter, was prepared by anodic oxidation using DC power supply of constant current mode in an aqueous solution of sulfuric acid. The aluminium plate was pre-treated with thermal oxidation, chemical polishing and electrochemical polishing before anodic oxidation. Because the pore size depended upon the electrolyte, electrolyte concentration, temperature, current density, and so on, the the membranes were prepared by controling the current density, as a very low current density for upper layer of membrane and a high current density for lower layer of membrane. By control of current quantity, the thicknesses of upper layer of membranes were about $6{\;}{\mu}m$ and the total thicknesses of membranes were about $80-90{\;}{\mu}m$. We found that the mechanism of gas permeation depended on model of the Knudsen flow for the membrane prepared at each condition.

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Wave propagation in a generalized thermo elastic plate embedded in elastic medium

  • Ponnusamy, P.;Selvamani, R.
    • Interaction and multiscale mechanics
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    • 제5권1호
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    • pp.13-26
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    • 2012
  • In this paper, the wave propagation in a generalized thermo elastic plate embedded in an elastic medium (Winkler model) is studied based on the Lord-Schulman (LS) and Green-Lindsay (GL) generalized two dimensional theory of thermo elasticity. Two displacement potential functions are introduced to uncouple the equations of motion. The frequency equations that include the interaction between the plate and foundation are obtained by the traction free boundary conditions using the Bessel function solutions. The numerical calculations are carried out for the material Zinc and the computed non-dimensional frequency and attenuation coefficient are plotted as the dispersion curves for the plate with thermally insulated and isothermal boundaries. The wave characteristics are found to be more stable and realistic in the presence of thermal relaxation times and the foundation parameter. A comparison of the results for the case with no thermal effects shows well agreement with those by the membrane theory.

Improvement of Separation of Polystyrene Particles with PAN Membranes in Hollow Fiber Flow Field-Flow Fractionation

  • Shin, Se-Jong;Chung, Hyun-Joo;Min, Byoung-Ryul;Park, Jin-Won;An, Ik-Sung;Lee, Kang-Taek
    • Bulletin of the Korean Chemical Society
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    • 제24권9호
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    • pp.1333-1338
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    • 2003
  • Hollow Fiber flow field-flow fractionation (HF-FlFFF) has been tested in polyacrylonitrile (PAN) membrane channel in order to compare it with polysulfone (PSf) membrane channel. It has been experimentally shown that the separation time of 0.05-0.304 ${mu}m$ polystyrene latex (PSL) standards in PAN membrane channel is shorter than that in PSf channel by approximately 65%. The optimized separation condition in PAN membrane is ${\dot V}_{out}/{\dot V}_{rad}=1.4/0.12\;mL/min$, which is equal to the condition in PSf membrane channel. In addition both the resolution ($R_s$) and plate height (H) in PAN membrane channel are better than that in PSf membrane channel. The membrane radius was obtained by back calculation with retention time. It shows that the PSf membrane is expanded by swelling and pressure, but the PAN membrane doesn't expand by swelling and pressure.

약품역세를 적용한 하수재이용 막여과 시스템의 운전성능 평가 (Evaluation of operating performance of secondary effluents treatment membrane system adapted chemical backwashing)

  • 김영훈;이창하;전민정;이용수;이의종;남종우;김형수
    • 상하수도학회지
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    • 제25권3호
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    • pp.335-342
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    • 2011
  • Secondary effluent contains particle compounds which are comprised of microorganisms that occurs membrane fouling when the water is reused. This study evaluates the characteristics of membrane fouling of secondary effluent reuse. Effects of chemical backwashing are analyzed to reduce membrane fouling by regular chemical backwashing. As the result, major membrane foulants are verified EPS materials which include protein and polysaccharide that cause biofilm cake layer on the membrane. Also, sodium hypochlorite is applied to chemical backwashing. The backwashing improves recover rate when injected chemical concentration is increased and chemical backwashing cycle is amplified. Chemical backwashing cycle affects more than injected chemical concentration yet idle time does not noticeably influence on reducing membrane fouling.

Structural Performance of Reinforced Concrete Flat Plate Buildings Subjected to Fire

  • George, Sara J.;Tian, Ying
    • International Journal of Concrete Structures and Materials
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    • 제6권2호
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    • pp.111-121
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    • 2012
  • The research presented in this paper analytically examines the fire performance of flat plate buildings. The modeling parameters for the mechanical and thermal properties of materials are calibrated from relevant test data to minimize the uncertainties involved in analysis. The calibrated models are then adopted to perform a nonlinear finite element simulation on a flat plate building subjected to fire. The analysis examines the characteristics of slab deflection, in-plane deformation, membrane force, bending moment redistribution, and slab rotational deformation near the supporting columns. The numerical simulation enables the understanding of structural performance of flat plate under elevated temperature and, more importantly, identifies the high risk of punching failure at slab-column connections that may trigger large-scale failure in flat plate structures.

전처리가 그래핀을 코팅한 고체고분자 연료전지 분리판의 전기화학적 특성에 미치는 영향 (Effect of Pretreatments on Graphene Coated Bipolar Plate of PEMFC on Electrochemical)

  • 차성윤;이재봉
    • Corrosion Science and Technology
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    • 제13권6호
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    • pp.224-232
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    • 2014
  • Effect of pretreatments on the graphene coated bipolar plate of proton exchange membrane fuel cell(PEMFC) was investigated in simulated environments for PEMFC by using electrochemical measurement techniques. Interfacial contact resistance(ICR) between the graphene coated bipolar plate and the gas diffusion layer(GDL) was measured. The value of ICR decreased with an increase in compaction stress($20N/cm^2{\sim}220N/cm^2$). ICR of graphene coated bipolar plate was higher than that of bare 316L stainless steel. However, Potentiodynamic measurement results showed that the corrosion resistance of graphene coated bipolar plate was higher than that of bare 316L stainless steel. $H_2SO_4$ acid pretreatment was the most effective among various pretreatments. The lowest ICR and the corrosion current density were obtained when using $H_2SO_4$ solution pretreatment.