• Title/Summary/Keyword: plate membrane

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Performance Evaluation of a Plate-Type Membrane Humidifier for PEMFC (고분자전해질연료전지용 판형막가습기 성능 평가)

  • Kho, Back Kyun;Park, JongCheol;Han, In-Su;Shin, Hyun Khil;Hur, Tae Uk;Cho, Sungbaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.98.2-98.2
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    • 2011
  • For optimal performance of a proton exchange membrane fuel cell (PEMFC), the membrane electrode assembly (MEA) requires hydration, and the membrane's conductivity depends on water content. A humidifier is required to ensure that the reactant gas, usually hydrogen and air, is hydrated before entering the fuel cell. Dry membrane operation or improper hydration causes performance degradation. Typically, the humidification of a fuel cell is carried out by means of an internal or external humidifier. A membrane humidifier is applied to the external humidification of transportation or residential power generation fuel cell due to its convenience and high performance. In this study, The experiments were constructed with a plate-type membrane humidifier in terms of geometric parameters and operating parameters. The results show that the temperature and pressure, the channel length, the membrane thickness and gas flow rate are critical parameters affecting the performance of the humidifier.

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Compressive and Bending Behaviors of the Shielded Slot Plate Considering Forming Effect for Fuel Cell Application (성형 이력을 고려한 용융탄산염 연료전지용 쉴디드 슬롯 플레이트의 압축 및 굽힘 거동 분석)

  • Lee, C.W.;Yang, D.Y.;Kang, D.W.;Chang, I.G.;Lee, T.W.
    • Transactions of Materials Processing
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    • v.21 no.6
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    • pp.341-347
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    • 2012
  • The metallic bipolar plates of the molten carbonate fuel cell(MCFC) are composed of shielded slot plates and a center-plate. The shielded slot plates support the center-plate and the membrane electrode assembly. Compressive forces are applied to the shielded slot plate in order to increase the contact area between shielded slot plates and the membrane electrode assembly (MEA). In the design of the shielded slot plate, it is necessary to predict the mechanical behavior of the shielded slot plate. The shielded slot plates are manufactured by a three-stage forming process consisting of slitting, preforming and the final forming process. The mechanical behavior of the shielded slot plate is largely affected by the forming process. In this study, the simulation of the three-stage forming process was used to predict the mechanical behavior of the shielded slot plate. The present simulation approach showed good agreements with the experimental results.

${\beta}-Ag_3SI$ Single Crystal Membrane Electrode (${\beta}-Ag_3SI$ 단결정막 전극에 관한 연구)

  • Sin Doo-Soon;Seon-Cheon Lee
    • Journal of the Korean Chemical Society
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    • v.28 no.2
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    • pp.86-94
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    • 1984
  • The single crystal ion-selective electrode,$ {\beta}-Ag_3SI/PVC-THF $membrane electrode has showed a linear potential response to the activities of iodide ion (10-1${\sim}$10-7M). The $ {\beta}-Ag_3SI$ membrane electrode was compared with AgI/PVC-THF membrane and copper metal plate membrane electrodes. In order to measure the selectivity coefficient of the electrodes toward $Cl^-$ and $Br^-$, the separation and mixed solution method were employed. The potential-time curve was obtained by the usual immersion technique and pH effect was also examined. The orders of selectivity for $Br^-$, $Cl^-$ and stability of response time are ${\beta}-Ag_3SI/PVC-THF $membrane > AgI/PVC-THF membrane > copper metal plate membrane. These electrodes could be used as indicating electrodes in the potentiometric titration of a single halide and mixed halides with the standard solution of silver nitrate.

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Permeation Characteristics of the Plate & Frame Membrane Module with Protuberances (돌기형 평판 분리막 모듈의 투과특성)

  • Chung, Kun-Yong;Jeon, Sung-Il
    • Membrane Journal
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    • v.18 no.2
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    • pp.168-175
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    • 2008
  • This study was carried out for the plate and frame membrane modules equipped with and without plastic protuberances on the support frame in order to determine the effect of eddy flow induced by the protuberances on permeate flux. The initial time for rapidly declined permeate flux on the module with protuberances was delayed twice or more than that on the module without protuberances when kaolin solution was permeated at the operating pressures from 0.4 to 1.6 bar. Also decreasing ratio of the kaolin solution to pure water flux for module with protuberances was 1 to 5% lower than that for module without protuberances. The flux improvement due to protuberances at laminar flow corresponding Reynolds number 1,750 was about double as compared with that in the transition flow region. In general, the kaolin fouling reduction for the plate module with protuberances during initial filtration process was very effective, even though the permeate flux after 60 minutes filtration did not increase significantly.

Surface Treatment of Air Gap Membrane Distillation (AGMD) Condensation Plates: Techniques and Influences on Module Performance

  • Harianto, Rachel Ananda;Aryapratama, Rio;Lee, Seockheon;Jo, Wonjin;Lee, Heon Ju
    • Applied Science and Convergence Technology
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    • v.23 no.5
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    • pp.248-253
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    • 2014
  • Air Gap Membrane Distillation (AGMD) is one of several technologies that can be used to solve problems fresh water availability. AGMD exhibits several advantages, including low conductive heat loss and higher thermal efficiency, due to the presence of an air gap between the membrane and condensation wall. A previous study by Bhardwaj found that the condensation surface properties (materials and contact angle) affected the total collected fresh water in the solar distillation process. However, the process condition differences between solar distillation and AGMD might result in different condensation phenomena. In contrast, N. Miljkovic showed that a hydrophobic surface has higher condensation heat transfer. Moreover, to the best of our knowledge, there is no study that investigates the effect of condensation surface properties in AGMD to overall process performance (i.e. flux and thermal efficiency). Thus, in this study, we treated the AGMD condensation surface to make it hydrophobic or hydrophilic. The condensation surface could be made hydrophilic by immersing and boiling plate in deionized (DI) water, which caused the formation of hydrophilic aluminum hydroxide (AlOOH) nanostructures. Afterwards, the treated plate was coated using hexamethyldisiloxane (HMDSO) through plasma-enhanced chemical vapor deposition (PECVD). The result indicated that condensation surface properties do not affect the permeate flux or thermal efficiency significantly. In general, the permeate flux and thermal efficiency for the treated plates were lower than those of the non-treated plate (pristine). However, at a 1 mm and 3 mm air gap, the treated plate outperformed the non-treated plate (pristine) in terms of permeate flux. Therefore, although surface wettability effect was not significant, it still provided a little influence.

Flow-Field Analysis for Designing Bipolar Plate Patterns in a Proton Exchange Membrane Fuel Cell (연료전지 분리판의 형상설계를 위한 유동해석)

  • Park, Jeong-Seon;Jeong, Hye-Mi
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.9
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    • pp.1201-1208
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    • 2002
  • A numerical flow-field analysis is performed to investigate flow configurations in the anode, cathode and cooling channels on the bipolar plates of a proton exchange membrane fuel cell (PEMFC). Continuous open-faced flow channels are formed on the bipolar plate surface to supply hydrogen, air and water. In this analysis, two types of channel pattern are considered: serpentine and spiral. The averaged pressure distribution and velocity profiles of the hydrogen, air and water channels are calculated by two-dimensional flow-field analysis. The equations for the conservation of mass and momentum in the two-dimensional fluid flow analysis are slightly modified to include the characteristics of the PEMFC. The analysis results indicate that the serpentine flow-fields are locally unstable (because two channels are cross at right angles). The spiral flow-fields has more stable than the serpentine, due to rotational fluid-flow inertia forces. From this study, the spiral channel pattern is suggested for a channel pattern of the bipolar plate of the PEMFC to obtain better performance.

Visualization of Thecal Plates of Lightly Armored Dinoflagellates Cryptoperidiniopsis brodyi and Pfiesteria piscicida (Dinophyceae) (유각 와편모조류 Pfiesteria piscicida (Dinophyceae)의 형태분석)

  • Park, Tae-Gyu;Bae, Heon-Meen;Kang, Yang-Soon
    • Journal of Environmental Science International
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    • v.18 no.1
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    • pp.15-19
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    • 2009
  • Early studies claimed that heterotrophic dinoflagellates Pfiesteria piscicida and related genera may produce a putative water-soluble toxin that causes death of fish and other marine animals. Several methods were tested to visualize plate morphology of Cryptoperidiniopsis brodyi and Pfiesteria piscicida. Cellulose plates of cells were exposed and visualized- by a membrane stripping method using Triton X-100. While calcofluor M2R white stain could readily bind to the thecal plates, details of the plate tabulation were difficult to observe. Fixation with osmium tetroxide $(OsO_4)$ produced well preserved cells with little morphological distortion, but thecal plates could not be visualized. Scanning electron microscopy (SEM) observation using the membrane stripping method showed distinctive plate tabulations between C. brodyi and P. piscicida suggesting that this method is a useful tool for morphological identification of lightly armored dinoflagellates.

Analysis of Dynamic Characteristics of Rectangular Plates by Finite Element Method (유한요소법을 이용한 평판의 동특성 연구)

  • 태순호;이태연;허문회
    • Journal of the Korean Society of Safety
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    • v.7 no.2
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    • pp.30-41
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    • 1992
  • Analysis of Dynamic Characterisocs of Rectangular Plate by Finite Element Method. Dynamic characteristics of a rectangular plate with opening in it is studied by finite element method. To investigate these characteristics 12 degrees of freedom membrane finite element in used. The rectangular membrane finite elements are defined by specifying geometry, internal displacement functions and strain-displacement relations. Then, the governing equation for the finite element is derived by energy method. To derive the mass matrix and stiffness matrix of the element, expressions for strain and kineic energy in terms of the node displacement are generated. In constructing the overall structure matrix, the matrix of each elements are superposed and partitioned by applying the given boundary condition to obtain a nonslngular matrix. To find the natural freguencies and viration modes, the eigen values and the corresponding eigen vectors are computed by the computer using well known Jacobi power method. In order to verify the capability of the membrane finite element, a flat rectangular plate is analyzed first, and the result is compared with well known analytical results to show the good agreement. A rectangular plate with opening in It is analyzed with the same finite element. The results are presented in this paper. Unfortunately, the literature study could not provide with some results to compare, but the results reveal that the output of this research is phlslcally reasonable. And the results of this research are useful not only in practice but also for the future experimental research in comparison purpose.

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On-line monitoring of microorganism cultivation processes using optical sensing membranes for simultaneous detection of dissolved oxygen and pH (용존산소와 pH의 동시 검출용 광학 센서 막을 이용한 미생물 발효공정의 온라인 모니터링)

  • Kim, Chun-Kwang;Rhee, Jong-II
    • KSBB Journal
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    • v.24 no.1
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    • pp.106-112
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    • 2009
  • An optical sensing membrane has been fabricated to measure the concentration of dissolved oxygen(DO) and pH value simultaneously. It has employed HPTS as a pH sensitive dye and a ruthenium(II) complex as a DO sensitive dye. The sensing membrane has been applied to wells in a 24-well microtiter plate. Using the 24-well microtiter plate the concentrations of dissolved oxygen and pH values have been on-line monitored during the cultivations of E.coli DH5${\alpha}$, B.cereus 318 and P.pastoris X-33. On-line monitoring of DO and pH in microorganism cultivation processes showed good performance of the sensing membrane containing 5 mM HPTS and 2 or 5 mg/mL Rudpp.

Development and Evaluation of Gasket for Polymer Electrolyte Membrane Fuel Cell Stacks (고분자 전해질 연료전지 가스켓 설계 및 성능 평가)

  • Seo, Hakyu;Han, In-Su;Jung, Jeehoon;Kim, Minsung;Shin, Hyungil;Hur, Taeuk;Cho, Sungbaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.90.1-90.1
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    • 2010
  • The design and fabrication of a metallic bipolar plate-gasket assembly for polymer electrolyte fuel cells (PEMFCs) is defined. This bipolar plate-gasket assembly was prepared by inserting a previously prepared bipolar plate in the specially designed gasket mold. For this aim, a proprietary fluoro-silicone based rubber was injected directly into the bipolar plate borders. Gaskets obtained like this showed the chemically / physically stable and the good sealibilty in typically operating PEM fuel cell conditions. And also, this bipolar plate-gasket assembly shows lots of advantages with respect to traditional PEMFCs stack assembling systems: useful application to automative stacking due to easy handling, reduced fabrication time, possibility of quality control and failed elements substitution. This bipolar plate-gasket assembly was evaluated in the short fuel cell stack and met the leakage requirement for normal operation both in short-term and in long-term operation. Especially, it was confirmed that this gasket could be applied successfully even in the high pressure FEM fuel cell systems(over 2.0 bar in absolute pressure).

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