• Title/Summary/Keyword: plastic recycling

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Chemical Composition and Nutritional Value of Algae Meal Produced from Dairy Cow Wastes as a Feedstuff (젖소폐기물에서 생산된 Algae Meal의 화학적조성 및 사료적가치)

  • Kim, Y.K.;Eun, J.S.;Kim, S.D.
    • Journal of the Korea Organic Resources Recycling Association
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    • v.6 no.1
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    • pp.75-85
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    • 1998
  • Algal meal (cell) was produced from the solution of dairy cow wastes by fermentation of ulothrix. sp. and chlorella sp. Raw wastes mainly feces were diluted with ground water to give dry matter concentration of 0.5 w/v of wastes in 20 l amounts of ten plastic containers. Each containers were covered with plastic nets and vinyl films to protect from the insects and rain. Algea cells were harvested every 3 to 5 days and dried by sunlight and artifitial heat. Dried cells were ground by a feed meal, and analyzed and tested for the chemical composition of dry cell, in vitro DM and protein digestibility and the safty of algae. Protein contents in algae meals, ulothrix (29.37%) and chlorella (29.24%) were similar. However, chlorella contained lower Neutral detergent fiber (5.92%) than ulothrix(20,76%), and higher ash (32.86%) and calcium (12.62%) than ulothrix (28.66% and 6.09%) (P<.01). Ulothrix protein had higher for essential amino acids; valine, isoleucine and phenylalanine, than chlorella (P<.05). Algal fats contained high saturated fatty acids, C16:0 and C18:0, for ulothrix and high unsaturated fatty acids, C18:1 and C18:2, for chlorella (P<.01). In vitro digestibility of. ulothrix tended to be higher for DM, but lower for protein than chlorella. The weight gain and survival percentage were higher for pond fishes (loaches, Misgurnus sp. ) fed diet added chlorella meal than diets added ulothrix meal and control diet (P<.05).

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The Evaluation of the Packaging Properties and Recyclability with Modified Acrylic Emulsion for Flexible Food Paper Coating (유연 종이 식품 포장재의 개질 아크릴 에멀젼 코팅 특성 및 재활용성 평가)

  • Myungho Lee;In Seok Cho;Dong Cheol Lee;Youn Suk Lee
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.29 no.3
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    • pp.153-161
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    • 2023
  • The worldwide effects of COVID-19 have led to a surge in online shopping and contactless services. The consumption pattern has caused the issues such as the environmental pollution together with the increase of plastic waste. Reducing the reliance on the petroleum based plastic use for the package and replacing it with environmentally friendly material are the simple ways in order to solve those problems. Paper is an eco-friendly product with high recyclability as the food packaging materials but has still poor barrier properties. A barrier coating on surface of the paper can be achieved with the proper packaging materials featuring water, gas and grease barrier. Polyethylene (PE) or polypropylene (PP) coatings which are generally laminated or coated to paper are widely used in food packaging applications to protect products from moisture and provide water or grease resistance. However, recycling of packaging containing PE or PP matrix is limited and costly because those films are difficult to degrade in the environment. This study investigated the recyclability of modified acrylic emulsion coating papers compared to PE and PP polymer matrixes as well as their mechanical and gas barrier properties. The results showed that PE or modified acrylic emulsion coated papers had better mechanical properties compared to the uncoated paper as a control. PE or PP coating papers showed strong oil resistance property, achieving a kit rating of 12. Those papers also had a significantly higher percentage of screen reject during the recycling process than modified acrylic coated paper which had a screen rejection rate of 6.25%. In addition an uncoated paper had similar value of a screen rejection rate. It may suggest that modified acrylic emulsion coating paper can be more easily recycled than PE or PP coating papers. The overall results of the study found that modified acrylic emulsion coating paper would be a viable alternative to suggest a possible solution to an environmental problem as well as enhancing the weak mechanical and poor gas barrier properties of the paper against moisture.

Recovery of $\alpha$-iron from converter dust in a steelmaking factory (제철소 전노 dust로부터 철분강 회수에 관한 연구)

  • 김미성;김미성;오재현;김태동
    • Resources Recycling
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    • v.2 no.2
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    • pp.27-38
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    • 1993
  • In this study, we investigated the grinding and sedimentation(elutriation) process of the dusts for the effective separation of high purity iron and iron oxides. For characterization of the dust, particle size distribution and chemical composition, were examined. The results obtained in this study may be summarized as follows : 1. The converter CF(clarifier) dust of the Pohang 1st, 2nd steel making factory and EC(Evaporation Cooler), EP(Eltrostatic precititator) dust of the Kwangyang 2nd steel making factory are composed $\alpha$-Fe(21~50%), FeO(wustite)$Fe_3$$O_4$(magnetite), $Fe_2$$O_3$, CaO, $Al_2$$O_3$, $SiO_2$, and etc. 2. Pure iron has ductile characteristic in nature, particle size of the pure iron increase by increasing the grinding time. On the other hand, it is conformed that bo고 particles of hematite and magnetite become less than 325 mesh after 10 minutes grinding. 3. By applying the elutriation technique for the EC dust of the Kwangyang 2nd steel making factory, the iron powder of high content more than 99.17% of pure Fe was recovered with 37.8% yield at grinding time for 40 minutes. 4. By applying the elutriation technique for the CF dust of the Pohang 2nd steel making factory, the iron powder of high content more than 98.38% of pure Fe was recovered with 44.42% yield at grinding time for 40 minutes. 5. When magnetic separation was performed using plastic bonding magnet of 70 gauss, more than 98% Fe grade of iron powder was recovered in the size range +65 -200 mesh but the recovery of it was low.

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The Welding Surface and Mechanical Characteristics in Friction Stir Welding for 5456-H116 Alloy (마찰교반용접에 의한 5456-H116 합금의 용접 형상과 기계적 특성)

  • Kim, Seong-Jong;Han, Min-Su;Jang, Seok-Ki
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.3
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    • pp.273-278
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    • 2012
  • The use of Al alloys instead of fiber-reinforced plastic(FRP) in ship construction has increased because of the advantages of Al-alloy ships, including high speed, increased load capacity, and ease of recycling. This paper describes the effects of probe diameter on the optimum friction stir welding conditions of 5456-H116 alloy for leisure ship, measured by a tensile test. In friction stir welding using a probe diameter of 5 mm under various travel and rotation speed conditions, the best performance was achieved with a travel speed of 61 mm/min. Using a probe diameter of 6 mm, rotation speeds of 170-210 rpm, and a travel speed of 15 mm/min produced a rough surface and voids because of insufficient heat input produced by the low rotation speed. At 500-800 rpm, chips were observed, although there were no voids, and the weld surface was excellent. However, at 1100-2500 rpm, many chips were produced due to excessive heat input. Heat effects were very evident on the bottom. For a travel speed of 15 mm/min, heat input caused by friction increased as the rotation speed increased. The mechanical characteristics were degraded by accelerated softening due to increasing heat input.

Features of Foreign Marine Debris on the Dune Beach of U-i Island, Korea (우이도 사구 해안의 외국기인 해양쓰레기 특성)

  • Lee, Jong-Myoung;Jang, Yong-Chang;Hong, Sun-Wook;Choi, Hyun-Woo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.2
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    • pp.167-174
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    • 2012
  • Transport of marine debris between countries is a potential source of diplomatic conflicts. U-i Island in Shinan County, Jeonnam Province has been reported by media as being damaged by marine debris from foreign countries. However, scientific researches on those marine debris have not been published. So, the features of foreign marine debris on Seongchon Beach in U-i Island were surveyed on Feb. 2012. The ratio of marine debris from foreign countries was 34.7% by number of items, 56.3% by weight, and 48.5% by volume in $200m^2$ transacts. Most of them, 98.9% in number, were inferred to be originated from China. The most abundant items were plastic beverage bottles and black floats. The total number of black floats was 539 within the 1,100m beach. Fifteen of them had information on manufactured locations, of which 87.6% were Liaoning Province in northern China. As domestic policy cannot prevent the inflow of the marine debris from foreign countries, countermeasures should be sought out from the international cooperation with the neighboring countries. For the black floats, recycling method should be developed as lots of the same types of black floats are drifted ashore in winter. And, as the U-i Island is a National Park with its valuable natural heritages, methods should be designed to minimize impacts on dune topography and ecology.

Fabrication and Characterization of the Carbon Fiber Composite Sheets (탄소섬유를 이용한 열가소성 복합재료 시트 제조 및 특성)

  • Lee, Yun-Seon;Song, Seung-A;Kim, Wan Jin;Kim, Seong-Su;Jung, Yong-Sik
    • Composites Research
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    • v.28 no.4
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    • pp.168-175
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    • 2015
  • Recently, the applications of carbon fiber reinforced plastics (CFRPs) have become broader than ever when it comes to such industries as automotive, ships, aerospace and military because of their lightweight-ness and high mechanical properties. Thermosetting plastics like epoxy are frequently used as the binding matrix in CFRPs due to their high hardness, wetting characteristics and low viscosity. However, they cannot melted and remolded. For this reason, thermosetting plastic wastes have caused serious environmental problems with the production of fiber reinforced plastics. Thus, many studies have focused on the carbon fiber reinforced thermoplastics (CFRTPs) and recycling carbon fiber. In this study, recycled carbon fiber (RCF) was prepared from CFRPs using a pyrolysis method, which was employed to separate resin and carbon fiber. The degree of decomposition for epoxy resin was confirmed from thermal gravimetric analysis (TGA) and scanning electron microscope (SEM). The RCF was cut and ground to prepare a carbon fiber composite sheet (CFCS). CFCS was manufactured by applying recycled carbon fibers and various thermoplastic fibers. Various characterizations were performed, including morphological analyses of surface and cross-section, mechanical properties, and crystallization enthalpy of CFCS at different cooling conditions.

Study on a recipe of recycled bumper and pristine materials for application of vehicle parts (재활용 범퍼의 효율적인 적용을 위한 신재의 최적 배합비율에 관한 연구)

  • Son, Younggon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.1
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    • pp.175-180
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    • 2016
  • Waste bumpers from out-of-service vehicles are recycled in the manufacturing process of plastic parts by incorporating pristine materials after removing the coated paint on a bumper. This study examined the chemical properties and mechanical properties of a mixture of recycled bumper and pristine materials as a function of the mixing ratio. When the pristine materials and the recycled bumper pieces were mixed, the stiffness (tensile strength and the flexural modulus) was provided by their composition averages. On the other hand, the toughness (Izod impact strength and the elongation-at-break) was lower than their composition averages (i.e., negative deviation). FTIR analysis showed that these results were due to the absence of the compatibility between the pristine materials and recycled bumper pieces. When the recycled bumper pieces were loaded at more than 30 wt. %, the toughness decreased drastically. A previous study showed that a paint removal efficiency up to 80 wt.% was easily attainable. The other 20 wt.% of paint on the bumper is very difficult to remove. Therefore, this study examined the mechanical properties of a mixture of recycled bumper pieces containing the unremoved paint and recycled bumper pieces without paint. When the recycled bumper pieces containing the unremoved paint were incorporated in only small quantities, the mechanical properties were decreased to a great extent. These results show that the paint removal efficiency is very important in the recycled bumper industry.

Conductive Properties of Thermoplastic Carbon Fiber Reinforced Plastics Highly Filled with Carbon Fiber Fabrics and Conductive Carbon Fillers (탄소섬유 직물 및 전도성 탄소 필러가 고충진 된 열가소성 탄소섬유강화플라스틱의 전도 특성)

  • Kim, Seong Yun;Noh, Ye Ji;Jang, Ji-un;Choi, Seong Kyu
    • Composites Research
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    • v.34 no.5
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    • pp.290-295
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    • 2021
  • The application of lightweight structural composites to automobiles as a solution in line with global fuel economy regulations to curb global warming is recognized as a megatrend. This study was conducted to provide a technical approach that can respond to the issue of replacing parts that require conductive properties to maximize the application of thermoplastic carbon fiber reinforced plastics (CFRPs), which are advantageous in terms of repair, disposal and recycling. By utilizing the properties of the low-viscosity polymerizable oligomer matrix, it was possible to prepare a thermoplastic CFRP exhibiting excellent impregnation properties while uniformly mixing the conductive filler. Various carbon-based conductive fillers such as carbon black, carbon nanotubes, graphene nanoplatelets, graphite, and pitch-based carbon fibers were filled up to the maximum content, and electrical and thermal conductive properties of the fabricated composites were compared and studied. It was confirmed that the maximum incorporation of filler was the most important factor to control the conductive properties of the composites rather than the type or shape of the conductive carbon filler. Experimental results were observed in which it might be advantageous to apply a one-dimensional conductive carbon filler to improve electrical conductivity, whereas it might be advantageous to apply a two-dimensional conductive carbon filler to improve thermal conductivity. The results of this study can provide potential insight into the optimization of structural design for controlling the conductive properties of thermoplastic CFRPs.

No-Tillage Agriculture of Korean-Style on Recycled Ridge II. Changes in Physical Properties : Water-Stable Aggregate, Bulk density, and Three Phase Ratio to Retain Water at Plastic Film Greenhouse Soil in No-Tillage System (두둑을 재활용한 한국형 무경운 농업 II. 시설 무경운 토양의 물리적 특성 : 입단과 용적밀도 및 삼상변화)

  • Yang, Seung-Koo;Shin, Gil-Ho;Kim, Sun-Kook;Kim, Hee-Kwon;Kim, Hyun-Woo;Jung, Woo-Jin
    • Korean Journal of Organic Agriculture
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    • v.24 no.4
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    • pp.719-733
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    • 2016
  • This study was carried out to investigate the effect of no-tillage on sequential cropping supported from recycling of first crop ridge on the productivity of crop and physical properties of soil under green house condition. This study is a part of "No-tillage agriculture of Korea-type on recycled ridge". From results for distribution of soil particle size with time process after tillage, soil particles were composed with granular structure in both tillage and no-tillage. No-tillage soil in distribution of above 2 mm soil particle increased at top soil and subsoil compared with tillage soil. Tillage and one year of no-tillage soil were not a significant difference at above 0.25 mm~below 0.5 mm, above 0.5 mm~below 1.0 mm, and above 1.0 mm of water-stable aggregate. Two years of no-tillage soil was significantly increased by 8.2%, 4.5%, and 1.7% at above 0.25 mm~below 0.5 mm, above 0.5 mm~below 1.0 mm, and above 1.0 mm of water-stable aggregate, respectively, compared with one year of no-tillage. Bulk density of top soil was $1.10MG\;m^3$ at tillage and $1.30MG\;m^3$ at one year of no-tillage. Bulk density of top soil was $1.14MG\;m^3$ at two years and $1.03MG\;m^3$ at three years of no-tillage, respectively. Bulk density of subsoil was a similar tendency. Solid phase ratio in top soil and subsoil was increased at one year of no-tillage compared with tillage soil, while soil phase ratio decreased at two and three years of no-tillage. Pore space ratio in tillage top soil (58.5%) was decreased by 8.5% at compared with no-tillage soil (51.0%). Pore space ratio was 56.9% and 61.2% at two and three years of no-tillage soil, respectively. Subsoil was a similar tendency. Gaseous phase ratio was decreased at one year of no-tillage soil, and increased at two and three years of no-tillage soil compared with tillage soil. Liquid phase ratio in top soil was increased at one year of no-tillage (28.3%), and decreased at two years (23.4%) and at three years (18.3 %) of no-tillage soil compared with tillage soil (24.2%). Subsoil was a similar tendency. Liquid phase ratio in subsoil was increased than top soil.

No-tillage Agriculture of Korean-Type on Recycled Ridge I. Changes in Physical Properties : Soil Crack, Penetration Resistance, Drainage, and Capacity to Retain Water at Plastic Film Greenhouse Soil by Different Tillage System (두둑을 재활용한 한국형 무경운 농업 I. 경운방법에 따른 시설재배 토양의 물리적 특성: 균열, 관입저항, 배수, 보수력 변화)

  • Yang, Seung-Koo;Jung, Woo-Jin
    • Korean Journal of Organic Agriculture
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    • v.24 no.4
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    • pp.699-717
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    • 2016
  • This study was carried out to investigate the effect of no-tillage on sequential cropping supported from recycling of first crop ridge on the growth of pepper plant and physical properties of soil under green house condition. 1. Degree of crack on soil by tillage and no-tillage Soil cracks found in ridge and not found in row. At five months of tillage, crack number and crack length in length ridge were 3 and 37~51 cm in tillage. Maximum width and maximum depth in length ridge were 30 mm and 15.3cm in tillage. Crack number and crack length in width ridge were 7.5 and 7~28 cm in tillage. Maximum width and maximum depth in width ridge were 29 mm and 15.3 cm in tillage. At a year of no-tillage, crack number and crack length in length ridge were 1.0 and 140~200 cm in tillage. Maximum width and maximum depth in length ridge were 18 mm and 30 cm in a year of no-tillage. Crack number and crack length in width ridge were 11 and 6~22 cm in a year of no-tillage. Maximum width and maximum depth in width ridge were 22 mm and 18.5 cm in a year of no-tillage. Soil crack was not found at 2 years of no-tillage in sandy Jungdong series (jd) soil. Soil crack was found at 7 years of no-tillage in clayish Jisan series (ji) soil. 2. Penetration resistance on soil Penetration resistance was increased significantly at no-tillage in Jungdong series (jd). Depth of cultivation layer was extended at no-tillage soil compared with tillage soil. Penetration resistance of plow pan was decreased at 1 year of no-tillage compared with than tillage soil. Penetration resistance was linearly increased with increasing soil depth at tillage in Jisan series (ji). Penetration resistance on top soil was remarkably increased and then maintained continuously at no-tillage soil. 3. Drainage and moisture content of soil Moisture content of ridge in top soil was not significant difference at both tillage and no-tillage. Moisture content of ridge in 20 cm soil was 14% at no-tillage soil and 25% at tillage soil. 4. Change of capacity to retain water in soil Capacity to retain water in top soil was not significant difference at 1 bar both tillage and no-tillage. Capacity to retain water in soil was slightly higher tendency in 1 year and 2 years of no-tillage soil than tillage soil. Capacity to retain water in soil was increased at 15 bar both tillage and no-tillage. Capacity to retain water in subsoil was slightly higher tendency at 1 bar and 3 bar in 2 years of no-tillage than tillage soil and a year of no-tillage soil.