• Title/Summary/Keyword: plastic recycling

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Investigation on optimum protection potential of high-strength Al alloy(5456-H116) for application in ships (선박용 고강도 Al합금(5456-H116)의 최적 방식 전위결정에 관한 연구)

  • Kim Sung-Jong;Ko Jae-Yong
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.1
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    • pp.157-168
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    • 2006
  • Recently, interest in using Al alloys in ship construction instead of fiber-reinforced plastic (FRP) has increased because of the advantages of A) alloy ships over FRP ships, including high speed, increased load capacity. and ease of recycling. This paper investigated the mechanical and electrochemical properties of Al alloys in a slow strain rate test under various potential conditions. These results will provide reference data for ship design by determining the optimum protection potential regarding hydrogen embrittlement and stress corrosion cracking. In general, Al and Al alloys do not corrode on formation of a film that has resistance to corrosion in neutral solutions. In seawater, however, $Cl^-$ ions lead to the formation and destruction of a Passive film. In a potentiostatic experiment. the current density after 1200 sec in the Potential range of $-0.68\~-1.5\;V$ was low. This low current density indicates the protection potential range. Elongation at an applied potential of 0 V was high in this SSRT. However, corrosion protection under these conditions is impossible because the mechanical properties are worse owing to decreased strength resulting from the active dissolution reaction in parallel parts of the specimen. A film composed of $CaCO_3\;and\;Mg(OH)_2$ confers corrosion resistance. However, at potentials below -1.6 V forms non-uniform electrodeposition coating, since there is too little time to form a coating. Therefore, we concluded that the mechanical properties are poor because the effect of hydrogen gas generation exceeds that of electrodeposition. Comparison of the maximum tensile strength, elongation, and time to fracture indicated that the optimum protection potential range was from -1.45 to -0.9 V (SSCE).

Recovery of Polyethylene Telephthalate Monomer over Cu or Mn/γ-Al2O3 Catalysts (Cu, Mn/γ-Al2O3 촉매상에서 polyethylene telephthalate 단량체의 회수 연구)

  • Sim, Jae-Wook;Kim, Seung-Soo
    • Applied Chemistry for Engineering
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    • v.28 no.4
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    • pp.485-489
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    • 2017
  • Polyethylene terephthalate (PET) has been widely applied in polymers and packaging industries to produce synthetic fibers, films, drink bottles or food containers. Therefore, it has become one of the major plastic wastes. In this article, glycolysis known as one of the main methods in PET chemical recycling was investigated using a glycol to break down the polymer into a monomer. Glycolysis of PET and ethylene glycol was performed in a micro-tubing reactor under various conditions. The effect of glycolysis conditions on the product distribution was investigated at experimental conditions of the EG/PET ratio of 1~4, the reaction time of 15~90 min and the reaction temperature of $250{\sim}325^{\circ}C$ with Mn and Cu catalysts. The highest yield of bis (2-hydroxyethyl) terephthalate monomer (BHET) was obtained as 89.46 wt% under the condition of the reaction temperature of $300^{\circ}C$ and the time of 30 min using 10 wt% $Cu/{\gamma}-Al_2O_3$ catalyst, with the PET and ethylene glycol ratio of 1 : 2.

Analysis of dimension precision of mobile device components according to the clearance in blanking process using CAE (CAE를 활용한 모바일 디바이스 부품의 블랭킹 공정 시 클리어런스에 따른 치수정밀도 분석)

  • Kim, Tae-Min;Choi, Doo-Sun;Han, Bong-Seok;Han, Yu-Jin;Ko, Kang-Ho;Park, Jung-Rae;Park, Kyu-Bag;Lee, Jung-Woo;Lim, Dong-Wook
    • Design & Manufacturing
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    • v.14 no.2
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    • pp.7-13
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    • 2020
  • For one decades, mobile devices components were made with plastic material, but environmental problems have recently replaced them with metal materials such as aluminum. Generally, aluminum components are mostly produced through cutting, but this process has limitations such as productivity and chip recycling. For this reason, many researches are conducted to improve productivity by replacing with the forging press process for manufacturing mobile device components. After forging process, the flash is remained and it is necessary to eliminate the flash from the final shape of components. In this paper, one-sided clearance for blanking aluminum material wes selected for parameter affected to the dimensional precision. Because the clearance is the most important parameter in blanking process. Deriving the clearance of blanking process for high dimensional precision, five level of one-sided clearance is selected and CAE is used to analyze the dimensional precision for each case.

Material Life Cycle Assessment of Extrusion Process of A7003 (A7003 알루미늄 합금 압출공정의 MLCA 산정기술)

  • Jo Huyng-ho;Cho Hoon;Kim Byung-min;Kim Young-jig
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2002.11a
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    • pp.43-49
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    • 2002
  • A7003 alloy has characteristics of their excellent weldability, high corrosion resistance and superior plastic working however the broadening of application for the alloy has been hampered by the lower extrudability associated by Mg content. For improvement of extrudability and enhanced recovery efficiency during Al scrap recyeling, it has been generally practiced to reduce Mg content in A7003 alloy. Therefore, it is necessary to investigate the influence of Mg content on mechanical strength and extrudability of A7003 alloy. For efficient material processing which has small amounts, life cycle assessment in material processing(MLCA) is evaluated. The quantitative analysis of energy requirements and $CO_2$ emission for production of A7003 extruded bar are estimated with different Mg content and billet pre-heating process (heating source by light oil or LPG). In particular, the estimation of energy requirements was performed within shipping and gating range (except the mining and extraction stages)to investigate the influence of the variables on energy requirements and $CO_2$ emission in detail. As Mg content increased, the flow stress and the extrusion pressure for A7003 alloy increased. It has been thought that an increment in extrusion pressure with increasing Mg content is caused by the solid solution hardening of Mg atoms in the matrix and increment in volume fraction of intermetallic compound, $Mg_2Si$. The extrudability and the tensile strength are equal to, or above that of conventional A 7003 alloy even the content of Mg varied from $1.1wt.\%\;to\;0.5wt.\%$ alloy. This means that minimizing the content of Mg in A7003 alloy can enhance recovery efficiency during Al scrap recycling. It can be quoted that rather than Mg content energy source for billet heating is a prime factor to determine the atmospheric $CO_2$ emission.

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Bloating mechanism of artificial lightweight aggregate with reject ash (잔사회를 이용한 인공경량골재의 발포기구)

  • Lee, Ki-Gang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.3
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    • pp.158-163
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    • 2012
  • The purpose of this study is to improve recycling rate of the coal reject ash by investigating bloating mechanism for artificial lightweight aggregate of reject ash. In this study, we use reject ash (R/A) and dredged soil (D/S) as raw materials. The artificial lightweight aggregates were formed by plastic forming (${\phi}$ = 10 mm) and sintered by temperature raising method at different temperatures (between 1200 and $1275^{\circ}C$). The physical properties of the aggregates such as bulk specific gravity, adsorption and microstructure of surface and cross-section are investigated with the sintering temperature and rate of R/A-D/S contents. As the result of the bulk specific gravity graphs, we can found out the inflection point at content of R/A 80 wt.%. From the microstructure images, we considered the artificial lightweight aggregates content of R/A over 80 wt.% are distributed numerous uniform micro-pores by vitrification without Black Core and the artificial lightweight aggregates of R/A below 80wt.% are distributed macro-pores with Black Core.

A Study on Characteristics of Flexural Behavior of High-strength Polymer Concrete Beams Using Recycled PET (PET 재활용 고강도 폴리머 콘크리트보의 휨거동에 관한 연구)

  • Cho Byung-Wan;Park Jong-Hwa;Park Seung-Kook;Bea Sung-Wan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05a
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    • pp.483-486
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    • 2005
  • The polymer concrete is drawing a strong interest as high-performance materials in the construction industry. Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. Also the recycling of PET in polymer concrete would help solve some of the solid waste problems posed by plastics and save energy. Polymer concrete beams using unsaturated polyester resins based on recycled polyethylene terephthalate (PET) plastic waste were used in our study for grasping its structural behavior of static and fatigue. As a result of static test, Compression stress distribution of Polymer concrete indicates linear behavior such as triangles. Although polymer concrete is high strength materials, its ductility capacity is excellent. From the fatigue test results, There was almost no difference on flexural characteristics between before and after fatigue loading. Therefore, recycled PET polymer concrete remains excellent structural ability after fatigue loading.

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Changes in Physical Properties Especially, Three Phases, Bulk Density, Porosity and Correlations under No-tillage Clay Loam Soil with Ridge Cultivation of Rain Proof Plastic House

  • Yang, Seung-Koo;Seo, Youn-Won;Kim, Sun-Kook;Kim, Byeong-Ho;Kim, Hee-Kwon;Kim, Hyun-Woo;Choi, Kyung-Ju;Han, Yeon Soo;Jung, Woo-Jin
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.4
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    • pp.225-234
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    • 2014
  • This study was carried out to investigate the sustainable agriculture of no-tillage technique including recycling of the ridge and the furrow of a field for following crops in Korea. No-tillage systems affect soil physical properties such as three phase (solid, liquid, and air phase) and distribution of soil granular. Solid ratio of subsoil in 3-year of no-tillage (NT) treatment was remarkably lower than that in conventional (CT, 2-year of no-tillage + 1-year of tillage) treatment, while air ratio of subsoil in NT remarkably increased. Bulk density of subsoil in NT remarkably decreased. Porosity of subsoil in NT remarkably increased. Deviation of air phase, bulk density, and porosity of top soil and subsoil in NT remarkably decreased in NT compared with CT. Solid phase ratio and liquid phase ratio in NT and CT had positive (+) correlation. Solid phase ratio and air phase ratio in NT and CT had negative (-) correlation, also liquid phase ratio and air ratio had negative (-) correlation. Bulk density and liquid ratio in soil had positive (+) correlation at top soil and subsoil in NT. Bulk density and air ratio in soil had negative (-) correlation in NT and CT. Porosity and liquid phase ratio had negative (-) correlation, r =1), the significant value was lower in NT than in CT. Porosity and air phase ratio had positive (+) correlation (r =1).

Melting of PCB scrap for the Extraction of Metallic Components (PCB스크랩으로부터 유가금속성분 회수를 위한 용융처리)

  • Kwon Eui-Hyuk;Jang Sung-Hwan;Han Jeong-Whan;Kim Byung-Su;Jeong Jin-Ki;Lee Jae-Chun
    • Korean Journal of Materials Research
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    • v.15 no.1
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    • pp.31-36
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    • 2005
  • It is well known that PCB (Printed Circuit Board) is a complex mixture of various metals mixed with various types of plastics and ceramics. In this study, high temperature pyre-metallurgical process was investigated to extract valuable metallic components from the PCB scrap. For this purpose, PCB scrap was shredded and oxidized to remove plastic materials, and then, quantitative analyses were made. After the oxidation of the PCB scrap, $30.6wt\%SiO_2,\;19.3wt\%Al_2O_3\;and\;14wt{\%}CaO$ were analyzed as major oxides, and thereafter, a typical composition of $32wt\%SiO_2-20wt\%Al_2O_3-38wt{\%}CaO-10wt\%MgO$ was chosen as a basic slag system for the separation of metallic components. Moreover a size effect of crushed PCB scrap was also investigated. During experiments a high frequency induction furnace was used to melt and separate metallic components. As a result, it was found that the size of oxidized PCB scrap was needed to be less 0.9 m to make a homogeneous liquid slag and to recycle metallic components over $95\%$.

International Certification Marks Trends and Current Regulation Situation of Bio Plastics (국내외 바이오 플라스틱 규제현황, 인증마크 및 식별 표시 동향)

  • Yu, Ji-Ye;Lee, So-Young;You, Young-Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.24 no.3
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    • pp.131-140
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    • 2018
  • As global environmental problems become more serious, bio plastic suppliers in developed countries are expected to drive demand for eco friendly packaging materials due to recycling regulations and consumer's attention. To catch up with this demand, various types of bio plastics have been introduced using plants such as corn and domestic companies are increasingly interested in this. Industrial interest in bio plastics is increasing to solve the recent environmental problems. The critical disadvantages of the weak mechanical strength and expensive product cost were gradually solved by extensive researches. In order to promote the active use of bio plastics, countries around the world are operation certification marks and standard systems. In this article, we have summarized recent trends in domestic and overseas bio plastics regulations, certification marks and identification labels.

A Study on Cover Material of Waste Landfill with Engineered Stone Sludge (폐기물 매립지의 복토재로 엔지니어드스톤 슬러지의 활용에 관한 연구)

  • Kim, Youngtae;Ahn, Kwangkuk;Kang, Hongsig
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.7
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    • pp.5-10
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    • 2022
  • The industrial waste is becoming a big problem in the aspect of spatial and environmental in domestic and international. Therefore, the waste reduction and recycling policy has been being implemented as a way to solve this problem. The engineered stone sludge, which is waste, is generated duing the engineered stone production process. since engineered stone sludge is mostly treated by landfill, an increase in the amount of the sludge leads to an increase in landfill sites and treatment costs. therefore, there is a need for a method of resourcization with engineered stone sludge. So, laboratory tests (Plastic and liquid limits, compaction, unconfined compression and permeability test) were conducted to confirm the possibility of using engineered stone sludge mixed with weathered granite soil as a cover material for landfill in this study. The result shows that the mixed soil material with less that 62.5% of engineered stone sludge can be used as a cover material for landfill.