• 제목/요약/키워드: plasma dilution

검색결과 116건 처리시간 0.028초

Ar-CO$_2$ Plasma에 의한 강(鋼)의 정련(精鍊) (Refining of Steels by $Ar-CO_2$ Plasma)

  • 장석영;김동의
    • 한국주조공학회지
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    • 제6권4호
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    • pp.284-289
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    • 1986
  • Decarburization phenomena have been studied by plasma in stainless steel, plain carbon steel and cast iron. It was also investigated the movement of impurity element P,S in the plasma jet metal pool. The plasma jet was obtained by $Ar\;-\;CO_2$ gas mixture with 5 kVA DC power source. It produced enough temperature to dissociate into activated oxygen atom by reaction of $CO_2{\leftrightarrows}CO+O^+$ and it reacted with ${\underline{C}}$ in metal pool. Decarburization rate was increased about 5 times in comparing with the conventional induction melted metal pool by $CO_2$ gas decarburization. Even under the Ar plasma jet, decarburization was obtained by agitation of metal bath by $Ar^+$ bombardment and dilution phenomena of carbon atom under the very high plasma temperature. But heavy element P and S are not much removed because they are too heavy in mass to be activated by $Ar^+$ion bombardment. Desulphurization was achieved by $Ar\;-\;CO_2$ plasma in plain carbon steel and cast iron by the reaction of $SO_2({\underline{S}}+O^+)$. But dephosphorization could not be obtained by $Ar\;-\;CO_2$ plasma, because gaseous reaction of phosphorous oxide (${\underline{P}}+O^+$) was not existed.

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Effects of Plantain (Plantago lanceolata L.) Herb and Heat Exposure on Plasma Glucose Metabolism in Sheep

  • Al-Mamun, M.;Tanaka, C.;Hanai, Y.;Tamura, Y.;Sano, H.
    • Asian-Australasian Journal of Animal Sciences
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    • 제20권6호
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    • pp.894-899
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    • 2007
  • An experiment was conducted using a [6, 6-$^2H$]glucose isotope dilution method to determine the effects of plantain (Plantago lanceolata L.) on plasma glucose metabolism in sheep taken from a thermoneutral environment and exposed to a hot environment. The sheep were fed either mixed hay (MH) of orchardgrass (Dactylis glomerata L.) and reed canarygrass (Phalaris arundinacea L.) at a 60:40 ratio or MH and plantain (PL) at a 9:1 ratio in a crossover design for each 23-day period. In both dietary treatments the metabolizable energy (ME) and crude protein intake were designed to be isoenergetic and isoproteinous at around maintenance level. The sheep were taken from a thermoneutral environment ($20^{\circ}C$, 70% RH) and exposed to a hot environment ($28-30^{\circ}C$, 70% RH) for 5 days. The isotope dilution method using a single injection of [6, 6-$^2H$]glucose was performed on the $18^{th}$ day of the thermoneutral environment and on the $5^{th}$ day of heat exposure. Plasma glucose pool size was numerically lower (p = 0.26) during heat exposure on both dietary treatments, and numerically higher (p = 0.13) on the MH diet irrespective of environmental temperature. Plasma NEFA concentration (p = 0.01) and glucose turnover rate (p = 0.03) were decreased during heat exposure, but remained similar between diets. It could be concluded that, although no positive impact of plantain on glucose metabolism was found under the present experimental conditions (plantain constituted only 10% of basal diet), plantain herb is an alternative to MH for rearing sheep in both thermoneutral and hot environments.

Effects of Early Feed Restriction on Breast and Leg Meat Composition and Plasma Lipid Concentration in Unsexed Broiler Chickens Reared in Cages

  • Santoso, U.
    • Asian-Australasian Journal of Animal Sciences
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    • 제15권10호
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    • pp.1475-1481
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    • 2002
  • The study was conducted to evaluate the effect of early feed restriction on growth, fat accumulation and meat composition in unsexed broiler chickens. In experiment 1, three hundred and fifty one-day-old broiler chicks were divided into 7 groups. Each treatment group was represented by five replicates of ten broilers each. One group was fed ad libitum as the control group and the other six groups were fed 25% ad libitum (25% multiplied by amount of feed intake of ad libitum chicks at the previous day) for 4 or 6 days, 50% ad libitum for 4 or 6 days, and 75% ad libitum for 4 or 6 days. In experiment 2, five hundred broiler chicks were divided into 10 groups. Each treatment group was represented by five replicates of ten broilers each. One group was fed ad libitum as the control group. Three initial age at which broilers were restricted (2, 4 or 6 days of age) and three type of feed restriction (physical restriction, meal feeding and diet dilution) ($3{\times}3$) were examined. They were restricted feeding for 6 days. Experimental results showed that broilers fed 25% ad libitum for 4-6 days tended to reduce leg meat fat with lower abdominal fat (p<0.05) (experiment 1). Breast meat fat was significantly higher in restricted broilers (p<0.01). Plasma triglyceride was higher in broilers fed 75% ad libitum for 4-6 days. In experiment 2, abdominal fat was lower in restricted broilers (p<0.05). Breast meat fat was significantly higher (p<0.01), whereas leg meat fat was significantly lower (p<0.05) in restricted broilers. Plasma triglyceride was significantly higher in physical feed restriction for 4 days, meal feeding for 4 days and diet dilution for 6 days (p<0.05). In conclusion, to reduce fat accumulation in abdomen and leg meat, broilers should be fed 25% ad libitum for 6 days started at 4 days, or subjected to meal feeding (6 hours per day for 6 days) started at 6 days.

Effects of Rice Straw Supplemented with Urea and Molasses on Intermediary Metabolism of Plasma Glucose and Leucine in Sheep

  • Alam, Mohammad Khairul;Ogata, Yasumichi;Sato, Yukari;Sano, Hiroaki
    • Asian-Australasian Journal of Animal Sciences
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    • 제29권4호
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    • pp.523-529
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    • 2016
  • An isotope dilution method using $[U-^{13}C]glucose$ and $[1-^{13}C]leucine$ (Leu) was conducted to evaluate the effects of rice straw supplemented with urea and molasses (RSUM-diet) on plasma glucose and Leu turnover rates in sheep. Nitrogen (N) balance, rumen fermentation characteristics and blood metabolite concentrations were also determined. Four sheep were fed either mixed hay (MH-diet), or a RSUM-diet with a crossover design for two 21 days period. Feed allowance was computed on the basis of metabolizable energy at maintenance level. The isotope dilution method was performed as the primed-continuous infusion on day 21 of each dietary period. Nitrogen intake was lower (p = 0.01) for the RSUM-diet and N digestibility did not differ (p = 0.57) between diets. Concentrations of rumen total volatile fatty acids tended to be higher (p = 0.09) for the RSUM-diet than the MH-diet. Acetate concentration in the rumen did not differ (p = 0.38) between diets, whereas propionate concentration was higher (p = 0.01) for the RSUM-diet compared to the MH-diet. Turnover rates as well as concentrations of plasma glucose and Leu did not differ between diets. It can be concluded that kinetics of plasma glucose and Leu metabolism were comparable between the RSUM-diet and the MH-diet, and rumen fermentation characteristics were improved in sheep fed the RSUM-diet compared to the MH-diet.

플라즈마 약액 활성화 방법을 이용한 Photoresist strip 가속화 연구 (The study about accelerating Photoresist strip under plasma)

  • 김수인;이창우
    • 한국진공학회지
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    • 제17권2호
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    • pp.113-116
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    • 2008
  • 반도체 소자 집적도의 비약적인 발전으로 인하여 반도체 공정은 더욱 다층화 되어가고 있다. 이러한 다층화 공정에서는 필수적으로 여러 단계의 패턴을 형성하기 위하여 Photoresist(PR)를 이용한 식각 공정을 사용하게 된다. 이러한 식각 공정에서 다단계 식각 공정으로 인한 공정시간 증가와 식각 후 남은 잔여 PR residue는 초고집적화된 현 반도체 산업에서는 소자에 치명적인 문제를 발생시킨다. 따라서 본 연구에서는 기존 PR strip 용액을 플라즈마에 의하여 액체 상태로 활성화하여 기존의 건식세정법과 습식세정법을 동시에 사용하여 PR을 효과적으로 제거하기 위한 방법을 연구하였다. 플라즈마에 의하여 약액을 활성화하기 위하여 먼저 플라즈마 약액활성화를 위한 장치를 simulation하여 실험 장치에서 균일한 gas흐름을 확인하였다. 이후 플라즈마의 세기를 0V에서 100V까지 증가시켜 약액을 활성화한 후 PR을 strip하여 각 플라즈마 세기에서의 식각률을 조사하였으며 80V에서 가장 빠른 식각률을 나타났다. 또한 0V와 80V의 Dilution에 대한 영향을 확인하였으며 약액을 Dilution 후에도 식각률은 더욱 향상됨을 확인할 수 있었다. 이러한 세정 시간의 단축은 여러 단계의 식각 공정 시간을 단축하여 반도체 공정에서 소자 생산을 위한 시간을 단축하게 된다. 또한 각 세정공정마다 증가한 세정 공정으로 인하여 세정액의 사용이 많아져 세정액 폐수로 인한 환경문제가 심각해지고 있다. 세정 약액 활성화 방법을 사용함으로써 세정액의 절감효과가 나타난다.

난류 부분예혼합화염과 로테이팅 아크 플라즈마를 이용한 난연성 유증기의 연소처리 (Reduction of Lean VOC Emission by Reforming with a Rotating Arc Plasma and Combustion with a Turbulent Partially-Premixed Flame)

  • 안태국;이대훈;박선호
    • 한국연소학회지
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    • 제22권1호
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    • pp.23-31
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    • 2017
  • Large-scale fuel tanks emit massive amount of hardly-combustible VOC mixtures which are light hydrocarbon species in dilution with nitrogen and carbon dioxide. We have developed a lab-scale burner to combust those VOC mixtures by use of a turbulent partially-premixed flame as a pilot flame. For a higher HC treatment ratio, the mixture gases were reformed by a rotating arc plasma device. The results showed that the nitrogen mole fraction and the injecting speed of the VOC mixture influence on the performance of the burner. It was also found that the size of the pilot flame and the power supplied to the plasma device determine the overall HC treatment ratio and the concentrations of CO and NOx in the exhaust gas.

속성수를 이용한 쓰레기 매립지 침출수의 오염물질 흡수제거(II) (Absorption of Heavy Metals of Waste Leachate Using by Fast Growing Trees(II))

  • 우수영
    • 한국농림기상학회지
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    • 제5권1호
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    • pp.36-42
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    • 2003
  • 쓰레기 매립지 침출수의 중금속과 유해성분을 자작나무와 이태리 포플러 묘목이 얼마나 흡수, 제거하는지를 알아보기 위해서 침출수 원액, 50% 침출수, 25% 침출수 그리고 대조구 등 4개의 처리로 나누어서 관수하였다. 실험이 끝난 후에 뿌리, 줄기, 잎을 분쇄기로 분쇄하고 그 함량을 Inductively Coupled Plasma emission spectrometer(ICP)로 조사하였다. 위에서 살펴 본 것과 같이 이태리 포플러와 자작나무 모두 쓰레기 매립지 침출수의 유해 중금속을 흡수 할 수 있는 능력이 있어 매립지나 황폐지 같은 지역의 빠른 조림을 위해서 활용이 기대되는 수종임을 알 수 있다. 특히 토양의 비소(As), 수은(Hg), 코발트(Co)그리고 니켈(Ni)등의 오염이 문제가 되는 지역에 이들 수종을 식재하게 되면 뿌리를 통해서 이들 원소를 흡착, 흡수할 수 있는 효과를 올릴 수 있다.

$CF_4$$O_2$혼합가스를 이용한 산화막과 질화막의 선택적 식각에 관한 연구 (Selective etch of silicon nitride, and silicon dioxide upon $O_2$ dilution of $CF_4$ plasmas)

  • 김주민;원태영
    • E2M - 전기 전자와 첨단 소재
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    • 제8권1호
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    • pp.90-94
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    • 1995
  • Reactive Ion Etching(RIE) of Si$_{3}$N$_{4}$ in a CF$_{4}$/O$_{2}$ gas plasma exhibits such good anisotropic etching properties that it is widely employed in current VLSI technology. However, the RIE process can cause serious damage to the silicon surface under the Si$_{3}$N$_{4}$ layer. When an atmospheric pressure chemical vapor deposited(APCVD) SiO$_{2}$ layer is used as a etch-stop material for Si$_{3}$N$_{4}$, it seems inevitable to get a good etch selectivity of Si$_{3}$N$_{4}$ with respect to SiO$_{2}$. Therefore, we have undertaken thorough study of the dependence of the etch rate of Si$_{3}$N$_{4}$ plasmas on $O_{2}$ dilution, RF power, and chamber pressure. The etch selectivity of Si$_{3}$N$_{4}$ with respect to SiO$_{2}$ has been obtained its value of 2.13 at the RF power of 150 W and the pressure of 110 mTorr in CF$_{4}$ gas plasma diluted with 25% $O_{2}$ by flow rate.

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Development of a Nutritional Supplement Certified Reference Material for Elemental Analysis

  • Lee, Jong Wha;Heo, Sung Woo;Kim, Hwijin;Lim, Youngran;Lee, Kyoung-Seok;Yim, Yong-Hyeon
    • Mass Spectrometry Letters
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    • 제9권4호
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    • pp.105-109
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    • 2018
  • A certified reference material (CRM) for the analysis of inorganic nutrients in nutritional supplements has been developed. Accurate mass fractions of chromium (Cr), iron (Fe), copper (Cu), and zinc (Zn) were determined by isotope dilution inductively coupled plasma mass spectrometry (ID ICP/MS). The measurement results were used to assign certified values for the CRM, which were metrologically traceable to the definitions of the measurement units in the International System of Units (SI). Production of a candidate reference material (RM) and the certification processes are summarized. Each nutrient in the CRM showed good homogeneity, which was estimated using relative standard deviations of the measurement results of twelve bottles in a batch. This CRM is expected to be an important reference to improve reliability and comparability of nutrient analyses in nutritional supplements and related samples in analytical laboratories.