• 한국지반공학회논문집
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• 제33권11호
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• pp.59-72
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• 2017

본 연구에서는 사질토 뒷채움재의 캔틸레버 옹벽에서 뒷굽 끝단 연직면에 작용하는 주동토압을 산정하는 방법을 제안하였다. 캔틸레버 옹벽에서 뒷굽길이에 따른 전단 영역의 변화는 벽체의 벽마찰력, 뒷채움 경사에 따라 뒷굽 끝단 연직면에 작용하는 주동토압에 영향을 준다. 뒷굽길이에 따라 변하는 파괴면각도를 가정하여 토압을 산정하는 한계평형법은 적용하기에 매우 복잡하므로 본 연구에서는 한계해석법을 사용하여 토압을 구하였다. 한계해석법으로 뒷굽길이에 따라 실제 파괴면각도가 고려된 토압을 정확히 산정하고, 이로부터 뒷굽 끝단 연직면에 작용하는 수평토압과 연직토압을 분석하였다. 본 연구결과에 의하면, 뒷굽길이가 짧아짐에 따라 내측 파괴면 경사각은 이론식보다 증가한 반면에 외측 파괴면 경사각은 영향을 받지 않았다. 뒷굽 끝단의 연직면에 작용하는 배면마찰각은 지표면 경사각과 벽면마찰각 사이의 값을 나타내었으며, 주동토압 또한 감소하였다. 최종적으로 상대적인 뒷굽길이와 뒷굽 끝단의 연직면에 작용하는 마찰각(연직토압/수평토압의 비)의 상관관계를 사용함으로써 Coulomb 토압을 간편하게 산정할 수 있도록 하였다.

• Bulletin of the Korean Chemical Society
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• 제22권1호
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• pp.30-36
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• 2001

The crystal structures of fully dehydrated $Pd^{2+}$ - and $TI^{+}$ -exchanged zeolite X, $Pd_{18}TI_{56}Si_{100}Al_{92}O_{384}(Pd_{18}TI_{50-}X$, a = $24.935(4)\AA$ and $Pd_{21}TI_{50}Si_{100}Al_{92}O_{384}(Pd_{21}TI_{50-}X$ a = $24.914(4)\AA)$, have been determined by single-crystal X-ray diffraction methods in the cubic space group Fd3 at $21(1)^{\circ}C.$ The crystals were prepared using an exchange solution that had a $Pd(NH_3)_4Cl_2\;:TINO_3$ mole ratio of 50 : 1 and 200 : 1, respectively, with a total concentration of 0.05M for 4 days. After dehydration at $360^{\circ}C$ and 2 ${\times}$$10^{-6}$ Torr in flowing oxygen for 2 days, the crystals were evacuated at $21(1)^{\circ}C$ for 2 hours. They were refined to the final error indices $R_1$ = 0.045 and $R_2$ = 0.038 with 344 reflections for $Pd_{18}Tl_{56-}X$, and $R_1$ = 0.043 and $R_2$ = 0.045 with 280 reflections for $Pd_{21}Tl_{50-}X$; I > $3\sigma(I).$ In the structure of dehydrated $Pd_{18}Tl_{56-}X$, eighteen $Pd^{2+}$ ions and fourteen $TI^{+}$ ions are located at site I'. About twenty-seven $TI^{+}$ ions occupy site II recessed $1.74\AA$ into a supercage from the plane of three oxygens. The remaining fifteen $TI^{+}$ ions are distributed over two non-equivalent III' sites, with occupancies of 11 and 4, respectively. In the structure of $Pd_{21}Tl_{50-}X$, twenty $Pd^{2+}$ and ten $TI^{+}$ ions occupy site I', and one $Pd^{2+}$ ion is at site I. About twenty-three $TI^{+}$ ions occupy site II, and the remaining seventeen $TI^{+}$ ions are distributed over two different III' sites. $Pd^{2+}$ ions show a limit of exchange (ca. 39% and 46%), though their concentration of exchange was much higher than that of $TI^{+}$ ions. $Pd^{2+}$ ions tend to occupy site I', where they fit the double six-ring plane as nearly ideal trigonal planar. $TI^{+}$ ions fill the remaining I' sites, then occupy site II and two different III' sites. The two crystal structures show that approximately two and one-half I' sites per sodalite cage may be occupied by $Pd^{2+}$ ions. The remaining I' sites are occupied by $TI^{+}$ ions with Tl-O bond distance that is shorter than the sum of their ionic radii. The electrostatic repulsion between two large $TI^{+}$ ions and between $TI^{+}$ and $Pd^{2+}$ ions in the same $\beta-cage$ pushes each other to the charged six-ring planes. It causes the Tl-O bond to have some covalent character. However, $TI^{+}$ ions at site II form ionic bonds with three oxygens because the super-cage has the available space to obtain the reliable ionic bonds.

• Bulletin of the Korean Chemical Society
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• 제21권10호
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• pp.1041-1043
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• 2000

We present the effects of temperature (between 10 K and 298 K) and of hole concentration on the frequency and intensity of characteristic phonons in polycrystalline $La_2CuO_4-related$ compounds using FT-IR spectros-copy. The influences of the concentration of carrier doped on the phonon modes are prominent in the IR spectra of $La_2CuO_4-related$ compounds. For $La_2-xSrxCuO_4({\chi}=$ 0.00, 0.03, 0.07, 0.10, and 0.15) and electrochemically (or chemically) oxidized $La_2CuO_4$, the intensities of the transverse oxygen mode around 680cm $-^1$ which cor-responds mainly to Cu-O(1) stretching vibration in the basal plane of CuO6 octahedron, are decreased and dis-appeared depending on the Sr-substitution rate and the amount of excess oxygen, while the longitudinal oxygen mode around 510 cm $-^1$ corresponding to the Cu-O(2) stretching in the basal plane of CuO6 octahedron are near-ly invariable. In particular, after two cycles of cooling-heating between 10 K and 298 K for these sample, the phonons around 680 cm $-^1$ are blue shif 13-15 cm $-^1$, while the phonons around 510 cm $-^1$ are nearly constant. The introduction of the charge carrier by doping would give rise to the small contraction of CuO6 oc-tahedron as Cu $^3+$ requires a smaller site than Cu $^2+$, which results in the shortening of the Cu-O(1) bond length and Cu-O(2) bond length with the increased La-O(2) bond length. These results in the frequency shift of the characteristic phonons. The IR spectra of $La_2Li0.5Cu0.5O_4$ which exhibits an insulator behavior despite the $Cu^3+$ of nearly 100%, corroborate our IR interpretations. The mode around 710 cm $-^1$ corresponding to Cu-O(1) stretching vibration is still strongly remained even at low temperature (10 K). Thus, we conclude that the con-duction electrons formed within $CuO_2$ planes of $La_2CuO_4-related$ superconductors screen more effectively the transverse oxygen breathing mode around 680 $cm-^1$ depending on the concentration of the doped charge carrier in $La_2CuO_4-related$ compounds, which might use as a superconductivity probe.

• 환경영향평가
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• 제27권6호
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• pp.582-594
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• 2018

본 연구에서는 생물반응 인공습지 내 용존유기물질의 변동 및 저감특성을 모니터링할 목적으로 수직 수평 흐름 습지를 직렬로 복합 적용하여 호기, 혐기상태의 흐름조건을 만들어 주었고 기능성 여재를 충진한 인공습지를 고안하여 아크릴 반응조로 제작 후 성능평가를 진행하였다. 수직 수평의 인공습지의 경우 호기 및 혐기조건을 평가하기 위해 반응조 내 용존산소(DO) 농도를 측정해본 결과 호기상태의 수직흐름인공습지에서는 2.7 mg/L, 혐기상태의 수평 흐름인공습지에서는 N.D.로 측정되어 운전조건에 부합하였다. 운전시간은 140 min, 80 min, 60 min으로 변경하며 실험을 진행을 하였으며, 운전시간에 따른 자연폭기시간 20 min을 동일하게 설정해 주고 실험을 진행하였다. 운전시간 모두 미생물의 활동으로 인한 결과를 보였으며, 3D-EEM에서는 운전시간을 길게 가져갈수록 난분해성 휴믹계물질구역인 III, V구역의 유기물에서 높은 저감효과를 보이는 것으로 확인되었다. 향후 저감효과에 대한 메커니즘 분석에 대한 연구는 추가로 진행될 필요가 있을 것으로 사료되지만, 본 연구결과는 향후 인공습지를 활용한 난분해성 물질의 저감을 위한 기술발전에 기여할 수 있을 것으로 기대된다.

• Wind and Structures
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• 제28권4호
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• pp.255-270
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• 2019

Aerodynamic configurations of bridge decks have significant effects on the aerostatic torsional divergence and flutter forsuper long-span bridges, which are onset for selection of suitable bridge decksfor those bridges. Based on a cable-stayed bridge with double main spans of 1500 m, considering typical twin-box, stiffening truss and closed-box section, which are the most commonly used form of bridge decks and assumed that the rigidity of those section is completely equivalent, are utilized to investigate the effects of aerodynamic configurations of bridge decks on aerodynamic instability performance comprised of the aerostatic torsional divergence and flutter, by means of wind tunnel tests and numerical calculations, including three-dimensional (3D) multimode flutter analysis and nonlinear aerostatic analysis. Regarding the aerostatic torsional divergence, the results obtained in this study show twin-box section is the best, closed-box section the second-best, and the stiffening truss section the worst. Regarding the flutter, the flutter stability of the twin-box section is far better than that of the stiffening truss and closed-box section. Furthermore, wind-resistance design depends on the torsional divergence for the twin-box and stiffening truss section. However, there are obvious competitive relationships between the aerostatic torsional divergence and flutter for the closed-box section. Flutter occur before aerostatic instability at initial attack angle of $+3^{\circ}$ and $0^{\circ}$, while the aerostatic torsional divergence occur before flutter at initial attack angle of $-3^{\circ}$. The twin-box section is the best in terms of both aerostatic and flutter stability among those bridge decks. Then mechanisms of aerostatic torsional divergence are revealed by tracking the cable forces synchronous with deformation of the bridge decksin the instability process. It was also found that the onset wind velocities of these bridge decks are very similar at attack angle of $-3^{\circ}$. This indicatesthat a stable triangular structure made up of the cable planes, the tower, and the bridge deck greatly improves the aerostatic stability of the structure, while the aerodynamic effects associated with the aerodynamic configurations of the bridge decks have little effects on the aerostatic stability at initial attack angle of $-3^{\circ}$. In addition, instability patterns of the bridge depend on both the initial attack angles and aerodynamic configurations of the bridge decks. This study is helpful in determining bridge decksfor super long-span bridges in future.

• 한국지반신소재학회논문집
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• 제18권3호
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• pp.11-22
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• 2019

본 연구는 양산단층대를 통과하는 고속도로 건설공사 중 암반비탈면의 파괴가 유난히 많이 발생된 원인을 규명하기 위하여 수행하였다. 이를 위해 128개소의 양산단층대 파괴 암반비탈면 대하여 불연속면 유형(절리, 층리, 단층)에 따라 face mapping과 역해석을 통해 전단강도(점착력, 내부마찰각)를 재 산정하였다. 재 산정된 점착력과 내부마찰각에 대해 분석을 하였으며 기존 문헌 및 설계 값과도 비교를 하였다. 전체적으로 본 연구에서 재 산정된 점착력과 내부마찰각이 기존 문헌 및 설계에 적용된 값보다 작은 것으로 나타났다. 이와 같은 이유로 시공 중 많은 암반비탈면에서 파괴가 발생된 것으로 보인다. 이것은 연구 대상 지역의 쇄설성퇴적암이 가지고 있는 특성과 발달된 불연속면이 큰 역할을 한 것으로 판단된다. 특히 층리 불연속면인 경우 기존 값과 비교 시 가장 큰 차이를 보이는 것으로 나타났다. 불연속면에 점토충진물이 존재하는 경우 불연속면의 유형에 따라 전단강도가 서로 다른 경향을 보이는 반면, 파쇄물이 존재하는 경우에는 전단강도 값은 불연속면의 유형에 상관없는 것으로 나타났다.

• 대한건축학회논문집:계획계
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• 제34권11호
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• pp.113-123
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• 2018

First of all, the multi-story Housing applying resident's participation in europe was classified by the menu selection method, the two-step supply method and the cooperative method. And then I analyzed flexible unit plan of cases for deriving the planning methode and the characteristics of flexibility. First, I analyzed the area and form of the unit plan, structure and Installation, fixed and variable elements to derive the planning method. The area of units are distributed from a minimum of $35m^2$ to a maximum of $150m^2$, and many of the unit planes have a narrow front and a deep depth. The structure is a long-span wall-structure or a skeleton structure, and is designed without any columns and bearing walls in the interior space for flexibility in spatial composition. The vertical shafts are located in the center of the unit in a box-form or in the corner at the unit dividing wall for free placement of interior wall. Fixed elements are framework and facility systems. Most of the future residents in the two-steps supply method and the cooperative method were able to freely design the internal space within the zoning concept proposed by the architect and change the location of the facade element within module system proposed by the architect. Second, the characteristics of the flexibility applied to the unit plan were divided in integrated flexibility, functional flexibility, construction flexibility, and supply flexibility. The integrated flexibility enables residents to give the variable space combination based on the complex structure of the inner space for providing various living experiences. Regarding functional flexibility, the three-dimensional spatial structure with neutral space has multi-functionality according to the needs of residents and easily accepts mixing of hybrid programs such as work and residence. Constructive flexibility allows residents to create identity by freely planning interior space and changing the size or location of facade components in a determined system of architects. Finally, various types of size and space composition are proposed and realized in the whole building applying menu selection method, so that flexibility in the offer can accommodate and integrate various types of living.

• 대한금속재료학회지
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• 제47권3호
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• pp.147-154
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• 2009

The effect of carbon addition on the microstructures and mechanical properties of $Ni_3Al$ and TiAl intermetallic alloys have been characterized. It is shown that carbon is not only an efficient solid solution strengthener in $Ni_3Al$ and TiAl, it is also an efficient precipitation strengthener by fine dispersion of carbide. Transmission electron microscope investigation has been performed on the particle-dislocation interactions in $Ni_3Al$ and TiAl intermetallics containing various types of fine precipitates. In an $L1_2$-ordered $Ni_3Al$ alloy with 4 mol.% of chromium and 0.2~3.0 mol.% of carbon, fine octahedral precipitates of $M_{23}C_6$ type carbide, which has the cube-cube orientation relationship with the matrix, appear during aging. Typical Orowan loops are formed in $Ni_3Al$ containing fine dispersions of $M_{23}C_6$ particles. In the L10-ordered TiAl containing 0.1~2.0 mol.% carbon, TEM observations revealed that needle-like precipitates, which lie only in one direction parallel to the [001] axis of the $L1_0$ matrix, appear in the matrix and preferentially at dislocations. Selected area electron diffraction (SAED) patterns analyses have shown that the needle-shaped precipitate is $Ti_3AlC$ of perovskite type. The orientation relationship between the $Ti_3AlC$ and the $L1_0$ matrix is found to be $(001)_{Ti3AlC}//(001)_{L10\;matrix}$ and $[010]_{Ti3AlC}//[010]_{L10\;matrix}$. By aging at higher temperatures or for longer period at 1073 K, plate-like precipitates of $Ti_2AlC$ with a hexagonal structure are formed on the {111} planes of the $L1_0$ matrix. The orientation relationship between the $(0001)_{Ti2AlC}//(111)_{L10\;matrix}$ is and $[1120]_{Ti2AlC}//[101]_{L10\;matrix}$. High temperature strength of TiAl increases appreciably by the precipitation of fine carbide. Dislocations bypass the carbide needles at further higher temperatures.

• 문화기술의 융합
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• 제8권1호
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• pp.507-512
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• 2022

연구 대상은 교량 접속도로 절취비탈면으로서 파괴 위험 가능성이 큰 중생대 경상누층군 퇴적암 비탈면이다. 비탈면의 구성 암석은 사암, 미사암 및 암맥이며, 불연속면은 층리와 전단절리, 인장절리 및 암맥 접촉면이 발달한다. 구간별로 파괴의 유형과 규모는 암석의 종류와 불연속면의 배향에 따라 다양하나 평면파괴가 우세하고, 파괴암체의 크기는 대부분 1m³ 이하이다. face-mapping 자료, SMR, 암석의 물성·역학시험, 구간별 지질횡단면도 분석 및 한계평형해석으로 종합·검토한 결과, 대표적 단면 모두 건기 시와 우기 시의 허용안전율에 크게 미달하여 대책공법이 필요 하였다. 따라서 경제성, 효율성, 현장 특성, 등을 고려하여 비탈면 내 구간과 위치에 따라 대책공법 안을 제안하였고 대책공법을 적용한 후 비탈면의 건기 및 우기 시의 안전율은 모두 허용안전율을 상회 하였다. 특히, 법면 face-mapping 자료와 법면에 수직인 여러 대표 구간의 지질횡단면도, 그를 기본도면으로 사용한 한계평형해석 및 대책공법 제시는 비탈면의 객관적인 해석 및 안정성 검토의 합리적인 도구가 될 것으로 예상한다.

• Korean Chemical Engineering Research
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• 제60권3호
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• pp.446-451
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• 2022

본 연구에서는 용량 및 장기 안정성을 개선하기 위하여 나노 실리콘 시트와 CNT를 정전기적 결합을 통해 피치가 코팅된 나노 실리콘 시트/CNT 복합체를 합성하였다. NaCl의 결정면에 스토버 법을 통해 제조된 나노 실리카 시트를 마그네슘 열 환원법을 사용하여 나노 실리콘 시트로 환원하였다. 산 처리를 통해 음으로 도전된 CNT와 APTES 표면처리를 통한 양으로 도전된 나노 실리콘 시트를 결합하여 나노 실리콘 시트/CNT 복합소재를 합성하였으며, 석유계 피치를 코팅하기 위하여 THF를 용매로 사용하였다. 제조된 음극복합소재의 물리적 특성은 FE-SEM, XRD, EDS를 통하여 분석하였고, LiPF₆ (EC:DMC:EMC = 1:1:1 vol%)를 전해액으로 사용하여 전지를 제조하였으며, 전기화학적 특성을 충·방전 사이클, 율속, differential capacity, EIS 테스트를 통해 조사하였다. 높은 조성의 실리콘과 전도성이 좋은 CNT를 사용할 경우 고용량 및 안정성이 우수한 음극소재를 제조할 수 있음을 알 수 있었다. 피치가 코팅된 나노 실리콘 시트/CNT 음극복합소재는 초기 방전 용량이 2344.9 mAh/g을 보였으며, 50 사이클 이후 용량 유지율이 81%로 피치가 코팅되지 않은 복합소재에 비해 개선된 전기화학적 성능을 확인할 수 있었다.