• 제목/요약/키워드: pitting

검색결과 532건 처리시간 0.023초

대기 노출된 Al2024 알루미늄 합금 산화막에 대한 미세조직 분석 (Microstructural Analysis on Oxide Film of Al2024 Exposed to Atmospheric Conditions)

  • 권대엽;최원준;반치범
    • 한국표면공학회지
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    • 제54권2호
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    • pp.62-70
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    • 2021
  • Al2024 aluminum alloy specimens were exposed to atmospheric conditions for maximum 24 months and analyzed by electron microscopes to characterize their corrosion behavior and oxide film characteristics. As the exposure time increased from 12 months to 24 months, the number of pitting sites per 1 mm2 increased from ~100 to ~200. The uniform oxidation (or non-pitting) region of the 12-month exposure specimen showed 30~120 nm thick oxide layer, whereas the 24-month exposure specimen showed 170~200 nm thick oxide with the local oxygen penetration region up to 1 ㎛ deep. There was no local corrosion area observed in the 12-month exposure specimen except pitting. However, in the 24-month exposure specimen, local oxygen penetration region was observed beneath the uniform oxide layer and near the pitting cavity. Al2024 showed two times thicker uniform oxide layer but much shallower local oxygen penetration region than Al1050, which appears to be related to low Si concentration. Further research is needed on the effects of Mg segregation near the tip of the oxygen penetration region.

다중선형회귀법을 활용한 예민화와 환경변수에 따른 AL-6XN강의 공식특성 예측 (Prediction of Pitting Corrosion Characteristics of AL-6XN Steel with Sensitization and Environmental Variables Using Multiple Linear Regression Method)

  • 정광후;김성종
    • Corrosion Science and Technology
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    • 제19권6호
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    • pp.302-309
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    • 2020
  • This study aimed to predict the pitting corrosion characteristics of AL-6XN super-austenitic steel using multiple linear regression. The variables used in the model are degree of sensitization, temperature, and pH. Experiments were designed and cyclic polarization curve tests were conducted accordingly. The data obtained from the cyclic polarization curve tests were used as training data for the multiple linear regression model. The significance of each factor in the response (critical pitting potential, repassivation potential) was analyzed. The multiple linear regression model was validated using experimental conditions that were not included in the training data. As a result, the degree of sensitization showed a greater effect than the other variables. Multiple linear regression showed poor performance for prediction of repassivation potential. On the other hand, the model showed a considerable degree of predictive performance for critical pitting potential. The coefficient of determination (R2) was 0.7745. The possibility for pitting potential prediction was confirmed using multiple linear regression.

Evaluation of High Order Statistical Parameter for Electrochemical Noise Analysis

  • Kim, Jong Jip
    • Corrosion Science and Technology
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    • 제7권5호
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    • pp.296-299
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    • 2008
  • High order statistical parameters were evaluated using the electrochemical noise data collected during corrosion of type 430 stainless steel coupled to a inert, platinum electrode in 3.5% NaCl solution. High order statistical parameters are shown to predict uniform corrosion properly. However, Localization index, skewness of current, kurtosis and skewness of potential are capable of predicting pitting corrosion only when the transients are large with long life time. Of the high order statistical parameters evaluated, kurtosis of current is found to be the most sensitive parameter for detecting uniform and pitting corrosion.

A Study on Electrochemical Characteristics Aluminum Multi Matrix Compound (Al-MMC) of Neutron Absorber Material

  • Lee, Jung Hwan;Lee, Yunju;Yoo, Seung Chang;Kim, Seunghyun;Kim, Ji Hyun
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2018년도 추계학술논문요약집
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    • pp.179-180
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    • 2018
  • Al - MMC, used as a neutron absorber, shows pitting corrosion and/or galvanic corrosion in 3.5wt.% NaCl solution. If pitting corrosion penetrates the core, neutron absorption performance could be affected. Galvanic corrosion was observed between Al 5052 and Al 1070, and pitting corrosion was observed around $B_4C$.

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스퍼기어의 피팅 수명 예측 및 실험 (Experiments and Prediction of Pitting Life in Spur Gears)

  • 김종성;주진욱;이상돈;조용주
    • Tribology and Lubricants
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    • 제25권6호
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    • pp.399-403
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    • 2009
  • The objective of this paper is to predict pitting initiation by using a contact analysis and subsurface stress. Contact stresses are obtained by contact analysis of a semi-infinite solid based on the use of influence functions. Subsurface stress field is obtained using rectangular patch solutions. It is used Mesoscopic multiaxial fatigue criterion to predict contact fatigue life. It is important to predict pitting initiation to enhance reliability of the mechanical elements. Pitting life prediction in the spur gears which are fundamental mechanical element is presented in this paper.

『상한론(傷寒論)』변병진단체계(辨病診斷體系)에 근거하여 소시호탕(小柴胡湯) 투여 후 호전된 부종 증례 1례 (A Case Report of Pitting Edema treated by Soshiho-tang based on Shanghanlun Provisions)

  • 박서연;이성준
    • 대한상한금궤의학회지
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    • 제9권1호
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    • pp.37-45
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    • 2017
  • Objective : The purpose of this paper is to report the improvement of patient with pitting edema treated by herb medication based on Shanghanlun disease pattern identification diagnostic system. Methods : According to 'Disease Pattern Identification Diagnostic System based on Shanghanlun Provisions', the patient was diagnosed with Taeyang-byung, number 96 provision, and took Soshiho-tang herb medication 30days. The changing symptom of pitting edema is reported depended on the edema scale and the statement of patient during treatment. Results : The pitting edema of patient disappeared by 96 provision of Soshiho-tang seclected according to Shanghanlun provisions. Conclusions : This case report suggests that two words on the 96 provision of Shanghanlun, '或 心下悸, 小便不利'(palpitations below the heart, inhibited urination) indcate close relationship between palpitation and decrease of genital secretions, which affected the edema in this case.

Pitting Corrosion of Inconel Alloy 600 at Elevated Solution Temperatures

  • Park, Jin-Ju;Pyun, Su-Il
    • 전기화학회지
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    • 제6권4호
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    • pp.271-281
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    • 2003
  • The present article is concerned with pitting corrosion of Inconel alloy 600 at elevated solution temperatures. This article first summarized the previous works on the characteristics and the growth models of oxide film grown on alloy 600 at elevated solution temperatures. Thereafter, this article reviewed previous works on the morphological study on pitting corrosion of alloy 600 as functions of solution temperature and such anion additives as thiosulphate, sulphate, nitrate and bicarbonate ions in terms of pit morphology and its fractal dimension.

nconel 600위에 증착된 TiN 박막의 고온 NaCl 수용액에서의 CPP 실험에 의한 핏팅저항성의 연구 (A Study on Pitting Resistance of TiN Film Coated on Inconel 600 by CPP Test in High Temperature NaCl Solution)

  • 김용일;정한섭;김홍회;이원종
    • 한국세라믹학회지
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    • 제32권11호
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    • pp.1301-1307
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    • 1995
  • Pitting corrosion of TiN film deposited on Inconel 600 by plasma assisted chemical vapor deposition (PACVD) was investigated. Cyclic potentiodynamic polarization (CPP) tests were conducted in order to determine the pit nucleation potentials, Enp, of the TiN-deposited sample and the bare Inconel 600 in deaerated NaCl solution at 25, 135 and 20$0^{\circ}C$. The effects of the TiN film thickness, the solution temperature and the Cl- concentration on Enp were studied. Enp of the TiN-deposited sample which had the film thickness above 1${\mu}{\textrm}{m}$ were higher than those of the bare Inconel 600 by 300~600mV at all the solution temperatures, implying the pitting resistance improvement of the TiN film. The morphologies of the pits generated after immersion test were examined with a scaning electron microscopy. The higher was the solution temperature, the more corrosion products, mainly composed of Cr and Ni oxides, were formed.

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동관에서 pH, 알칼리도, 염소이온이 부식에 미치는 영향 (Effects of pH, Alkalinity, Chloride Ion on the Copper Pipe Corrosion)

  • 조관형;김선일;우달식
    • 한국환경보건학회지
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    • 제33권1호
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    • pp.43-48
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    • 2007
  • This study investigated the effects of pH, alkalinity, and chlorine ion which are important water quality impact factors to the corrosion in the simulated distribution system where the copper pipe is affixed. The result shows that pitting index was increased as the alkalinity and chloride ion increase in the distilled water, but there was no relation to pH. Actually the uniform corrosion rate was decreased as the pH increase with the laboratory tap water. In conclusion, it is necessary to control the pH which stands above minimum 7.5 to prevent pitting corrosion in the copper pipe. Consequently, comprehensive research about the effect of lime soda($Ca(OH)_2$) which was used as a coagulation additive in the water treatment plant to pipe corrosion must be accomplished additionally.

Estimation of Stress Intensity Factors for 3-Dimensional Surface Defects under Axial Tensile Loads Using the Finite Element Method

  • Jeon, Byung-Young;Kumar, Y.V. Satish;Kang, Sung-Won
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2002년도 추계학술대회 논문집
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    • pp.267-272
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    • 2002
  • Pitting corrosion is a very common occurrence in marine structures. Therefore, the 3-D finite element analysis is carried out to determine the stress intensity factors at the pit depth and also at the surface of the pit. The pits are modeled as a part of sphere, based on the pit depth and the pit diameter as specified by the Ship Structural Committee. The pit depth and pit diameter are function of the percentage of pitting that the plate is subjected to. A dog-bone shaped specimen is subjected to different intensities of pitting and the stress intensity factors are determined under axial tensile loads.

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