• Title/Summary/Keyword: pitch rate

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Electrochemical Characteristics of Lithium Battery Anode Materials Using Petroleum Pitches (석유계 피치를 사용한 리튬전지 음극소재의 전기화학적 특성)

  • Hwang, Jin Woong;Lee, Jong Dae
    • Applied Chemistry for Engineering
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    • v.28 no.5
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    • pp.534-538
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    • 2017
  • In this study, the molecular weight controlled pitches derived from pyrolyzed fuel oil (PFO) were prepared using solvent extraction and were carbonized. Electrochemical characteristics of lithium battery anode materials were investigated using these petroleum pitches. Three pitch samples prepared by the thermal reaction were 3903 (at $390^{\circ}C$ for 3 h), 4001 (at $400^{\circ}C$ for 1 h) and 4002 (at $400^{\circ}C$ for 2 h). The prepared hexane insoluble pitches were analysed by XRD, TGA, SEM and Gel permeation Chromatography (GPC). The electrochemical characteristics of the PFO-derived pitch as an anode material were investigated by constant current charge/discharge, cyclic voltammetry and electrochemical impedance tests. The coin cell using pitch (4001) and the electrolyte of $LiPF_6$ in organic solvents (EC : DMC = 1 : 1 vol%, VC 3 wt%) has better initial capacity (310 mAh/g) than that of other pitch coin cells. Also, this carbon anode showd a high initial efficiency of 82%, retention rate capability at 2 C/0.1 C of 90% and cycle retention of 85%. It was found that modified pitches improved the cycling and rate capacity performance.

An Experimental Study on Heat Transfer in the Furan Foundry Sand Fluidized Bed (Furan Foundry Sand 유동층에서 열 전달 특성에 관한 연구)

  • Park, Jong-Suen;Baek, Ko-Kil;Kim, Uen-Young;Jeon, Sung-Taek;Lee, Duck- Bong
    • Solar Energy
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    • v.15 no.3
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    • pp.105-117
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    • 1995
  • Heat transfer coefficients on a single spiral coil tube in the furan foundry sand fluidized bed have been investigated. Heat transfer coefficients(ho) to an immersed single spiral coil tube were measured in the bed. The bed diameter was 0.21 m. The following quantities were varied: (l)bed temperature, (2)mean particle diameter, (3) fluidization rate, (4)the ratio of heated coil tube pitch to diameter(p/Do), and (5)the ratio of heated coil tube pitch to mean particle diameter(p/dp). In addition, the experimental values of maximum Nusselts number were compared with the values of maximum Nusselts number predicted by the existing correlations. The values of heat transfer coefficient increase with the increase in bed temperature and fluidization rate, but decrease with increase in particle diameter. An empirical formulus of maximum Nusselts number which is applicable in the furan foundry sand fluidization bed is as follows: $$Nu_{max}=1.01\;Re^{0.48}Prg^{0.4}(p/dp)^{0.28}(p/Do)^{0.05}$$.

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An Amplitude Warping Approach to Intra-Speaker Normalization for Speech Recognition (음성인식에서 화자 내 정규화를 위한 진폭 변경 방법)

  • Kim Dong-Hyun;Hong Kwang-Seok
    • Journal of Internet Computing and Services
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    • v.4 no.3
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    • pp.9-14
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    • 2003
  • The method of vocal tract normalization is a successful method for improving the accuracy of inter-speaker normalization. In this paper, we present an intra-speaker warping factor estimation based on pitch alteration utterance. The feature space distributions of untransformed speech from the pitch alteration utterance of intra-speaker would vary due to the acoustic differences of speech produced by glottis and vocal tract. The variation of utterance is two types: frequency and amplitude variation. The vocal tract normalization is frequency normalization among inter-speaker normalization methods. Therefore, we have to consider amplitude variation, and it may be possible to determine the amplitude warping factor by calculating the inverse ratio of input to reference pitch. k, the recognition results, the error rate is reduced from 0.4% to 2.3% for digit and word decoding.

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Preparation and Properties of Pelletized Activated Carbons Using Coconut Char and Coal-Tar Pitch

  • Yang, Seung-Chun;Lee, Young-Seak;Kim, Jun-Ho;Lim, Chul-Kyu;Park, Young-Tae
    • Carbon letters
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    • v.2 no.3_4
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    • pp.176-181
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    • 2001
  • A series of activated carbons were prepared from coconut shells and coal-tar pitch binder by physical activation with steam in this study. The effect of variable processes such as activation temperature, activation time and ratio of mixing was investigated for optimizing those preparation parameters. The activation processes were carried out continuously. The nitrogen adsorption isotherms at 77 K on pellet-shaped activated carbons show the same trend of Type I by IUPAC classification. The average pore sizes were about 19-21${\AA}$. The specific surface areas ($S_{BET}$) of pellet typed ACs increased with increasing the activation temperature and time. Specific surface area of AC treated for 90 min at temperature $900^{\circ}C$ was 1082 $m^2/g$. The methylene blue numbers continuously increased with increasing the activation temperature and time. On the other hand, iodine numbers highly increased till activation time of 60 min, but the rate of increase of iodine numbers decreased after that time. This indicates that new micropores were created and the existing micropores turned into mesopores and macropores because of increased reactivity of carbon surface and $H_2O$.

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A Method of Intonation Modeling for Corpus-Based Korean Speech Synthesizer (코퍼스 기반 한국어 합성기의 억양 구현 방안)

  • Kim, Jin-Young;Park, Sang-Eon;Eom, Ki-Wan;Choi, Seung-Ho
    • Speech Sciences
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    • v.7 no.2
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    • pp.193-208
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    • 2000
  • This paper describes a multi-step method of intonation modeling for corpus-based Korean speech synthesizer. We selected 1833 sentences considering various syntactic structures and built a corresponding speech corpus uttered by a female announcer. We detected the pitch using laryngograph signals and manually marked the prosodic boundaries on recorded speech, and carried out the tagging of part-of-speech and syntactic analysis on the text. The detected pitch was separated into 3 frequency bands of low, mid, high frequency components which correspond to the baseline, the word tone, and the syllable tone. We predicted them using the CART method and the Viterbi search algorithm with a word-tone-dictionary. In the collected spoken sentences, 1500 sentences were trained and 333 sentences were tested. In the layer of word tone modeling, we compared two methods. One is to predict the word tone corresponding to the mid-frequency components directly and the other is to predict it by multiplying the ratio of the word tone to the baseline by the baseline. The former method resulted in a mean error of 12.37 Hz and the latter in one of 12.41 Hz, similar to each other. In the layer of syllable tone modeling, it resulted in a mean error rate less than 8.3% comparing with the mean pitch, 193.56 Hz of the announcer, so its performance was relatively good.

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Real-time Voice Change System using Pitch Change (피치 변환을 사용한 실시간 음성 변환 시스템)

  • Kim, Weon-Goo
    • Journal of the Korean Institute of Intelligent Systems
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    • v.14 no.6
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    • pp.759-763
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    • 2004
  • In this paper, real-time voice change method using pitch change technique is proposed to change one's voice to the other voice. For this purpose, sampling rate change method using DFT (Discrete Fourier Transform) method and time scale modification method using SOLA (Synchronized Overlap and Add) method is combined to change pitch. In order to evaluate the performance of the proposed method, voice transformation experiments were conducted. Experimental results showed that original speech signal is changed to the other speech signal in which original speaker's identity is difficult to find. The system is implemented using TI TMS320C6711DSK board to verify the system runs in real time.

Basic Investigation for the Development of Cleaning Technology with Ejector (이젝터를 이용한 세정기술 개발의 기초연구)

  • Park, Sang Kyoo;Yang, Hei Cheon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.1
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    • pp.29-36
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    • 2017
  • The paper presents a basic investigation for the development of cleaning technology employing an annular nozzle ejector for application to cleaning water supply and air bubble generation. The quantitative flow characteristics of the primary and suction flows, the qualitative visualization behavior of the mixed jet, and the percentage concentration of pesticide residual at different values of the ejector screw pitch were investigated. It was seen that the primary flow rate increased, while the mass ratio decreased with increase in screw pitch. Further, the mixed jet behaved like a buoyancy jet or horizontal bubbly jet, and the residual concentration of pesticide first decreased and then increased with increase in screw pitch.

Baseball Game Analysis Method Using Broadcast Video (중계 영상을 활용한 야구 경기 분석 방법)

  • Son, Jong-Woong;Lee, Myeong-jin
    • Journal of Broadcast Engineering
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    • v.25 no.4
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    • pp.576-586
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    • 2020
  • Analyzing baseball games using sensors such as radars or riders is expensive. In this paper, we propose an algorithm to detect pitch shots and hit shots using baseball video and to generate ball trajectories within hit shots using camera movement. After the pitch shot and the hit shot detection using object detection and optical flow, we generate the transformation relationship between frames and ball locations in the frame, and calculates the ball trajectory. The performance of the proposed method is evaluated for three KBO baseball video sequences, and the detection accuracy and detection rate of pitch shot and hit shot were within 89-95 [%], and the average error for shot range was 13.6[m], The direction error was 7.5° and foul classification accuracy was 98.6%.

Distribution of Silver Particles in Silver-containing Activated Carbon Fibers

  • Ryu, S.K.;Eom, S.Y.;Cho, T.H.;Edie, D.D.
    • Carbon letters
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    • v.4 no.4
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    • pp.168-174
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    • 2003
  • Silver nitrate ($AgNO_3$) powder was mixed into a reformed pitch precursor. Then, the silver-containing pitch was melt spun to form round and "C" shape fibers. A wire mesh was inserted prior to the nozzle to improve the spinnability of the silvercontaining precursor pitch. Silver particles in the carbon fibers (CFs) were detected by XRD and TEM. These tests showed that silver particles were uniformly distributed and the total amount of silver remained constant during stabilization and carbonization. Next, the silver-containing CFs were activated by steam diluted in nitrogen gas. Silver particles accelerated the activation rate, but the specific surface areas of the silver-containing ACFs were similar to those of non-silver containing ACFs at the same burn-off levels. The specific surface area of the C-shaped activated carbon fibers was larger than that of the round activated carbon fibers. The likely reason is that the surface area of a C-shaped CF is about two times larger than that of a round CF when equivalent cross-sectional areas are compared. A small amount of silver particles in the periphery of the CFs was removed during the activation, but the remainder of silver was stayed within the ACFs.

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끊김앞에서 보이는 서울말의 억양특징

  • Yun Il-Seung
    • MALSORI
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    • no.21_24
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    • pp.90-110
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    • 1992
  • The purpose of this thesis is to investigate the intonation features of the last two syllables of rhythmic units, with the exception of the sentence final unit, in the Seoul dialect of Korean. The Model 5500 Sona-graph was used to measure the pitch and duration of the target syllables. There are two classes of materials. One class was designed to determine the intonation of rhythmic units in a natural situation and the other to investigate the intonation of rhythmic units in an artificial situation, in which speakers were asked to read the materials pausing only at the marked boundaries, with a view to identifying the intonation of Seoul dialect more clearly. The findings of this investigation are as follows: (1) Korean averages an 11% rising intonation between the two syllables at the end of a rhythmic unit. (2) The rising rate between the final two syllables' pitch values at the subject rhythmic unit is generally higher than those at other units in a sentence and it seems to be meaningful syntactically. (3) Before a boundary the rhythmic units undergo 'pre-lowering', in which the pitch gradually lowers from the first syllable to the penultimate. (4) Every syllable in each rhythmic unit tends to lengthen when speakers read the materials with a pause between units and the tendency is most salient at the final syllable before a boundary.

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