• 한국염색가공학회지
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• 제35권4호
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• pp.196-205
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• 2023

Water-dispersed pigment is on-going study for without air pollution in the textile and print industry. Primer treatment is essential for the substrate to improve the printing quality of eco-friendly water-dispersed pigment ink. Otherwise in the case of untreated primer, the water-dispersed pigment ink will dry onto the surface and cause defective images. This study was conducted on film substrate coating (primer) to fix eco-friendly water-dispersed pigment ink on film substrate. The drying, bleeding, and color strength of the pigment ink were examined depending on the composition and mixing ratio of the coating solution. The mixing ratio of silica gel in the coating film is increased to 0, 0.5, 1, 2 and 3 and results that DK-1-3 of silica gel ratio of 1 showed the lowest bleeding such as 52%, the letter thickness of 0.76mm and DK-1-5 of SG ratio of 3 showed the highest bleeding such as 304%, the letter thickness of 2.02mm. The mixing ratio of SPA in the coating film is increased to 2.5, 5, 7.5, SPA ratio of 7.5 has a bleeding ratio of 9% and letter thickness of 0.544mm. It showed the closest value to 0.5mm. According to the result, the optimal mixing ratio of binder, polymer coagulant, silica gel is 100:7.5:1.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2003년도 추계학술발표논문집
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• pp.148-153
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• 2003

The influence of sizing, fiber and pigment type on coating penetration, using commercial paper and two types of handsheets as the base paper which were prepared from thermomechanical pulp(TMP) and hardwood bleached kraft pulp(KP) sized internally with alkyl ketone dimmer(AKD), was studied in terms of characteristics of coating holdout. Laboratory rod draw down coater was used for surface sizing and coating application. Characterization of coating penetration was done by measuring the roughness of the backside of coating layer. The backside of the coating was exposed by dissolving the fibers in a solution of cupriethylenedimine(CED). Data show that internal sizing of base paper is effective and surface sizing is more effective to prevent coating penetration. Comparing between the two types of base papers, backside roughness of coating layer of TMP sheet is much larger and sizing is more effective to reduce coating penetration than those of KP sheet. With regard to pigment type, clay is more effective than calcium carbonate for better coating holdout.

• 한국인쇄학회지
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• 제8권1호
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• pp.53-70
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• 1990

It is well known that viologens such as 1.1 - disubstituted 4, 4` - bipyridinium salts and those used as redox indicator, herbicide and electrocheromic display device because those possess the lowest redox potential in any organic system. Viologen salts produced reversible high blue color under the influence of radical cation by photoreduction This study is related to the synthesis of viologen derivatives and the photoreduction property in water solution stats and the polar aprotic polyvinylpyrrolidone(PVP) matrix.

• 한국세라믹학회지
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• 제48권4호
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• pp.303-306
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• 2011

[ $V_2O_5$ ]doped Karrooite pigments were synthesized by the solid state method to get stabilized brown pigment in oxidation and reduction atmosphere. Optimum substitution condition and limited dopant with $V_2O_5$ for Karrooite pigment was investigated. With calcination at $1250^{\circ}C{\sim}1400^{\circ}C$, compositions were designed varying $V_2O_5$ molar ratio by increasing 0.02mole to the formula $Mg_1-xTi_2-xM_{2x}O_5$(x = 0.01~0.09 mole). Synthesized pigments were analyzed by XRD, Raman spectroscopy and UV-vis. When $V_2O_5$ was doped from 0.01 to 0.05 mole, single phase of Karrooite was observed at temperature $1300^{\circ}C$ and soaking time 4h by Raman spectroscopy. However, it was found that excess $VO_2$ peak appeared with 0.07 and 0.09 mole of $V_2O_5$ doped to $MgTi_2O_5$. This result indicated that the maximum limit of solid solution is 0.05 mole $V_2O_5$. Karrooite pigments were applied as a ceramic pigment to achieve brown colors in lime magnesia glaze and lime barium graze at both of oxidation and reduction atmosphere. CIE color coordinates are $L^*$ = 40.34, $a^*$ = 9.94, $b^*$ = 21.40 in lime magnesia glaze.

• 한국식품과학회지
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• 제33권2호
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• pp.221-225
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• 2001

꽃양배추색소추출액의 농도를 1-65%로 조절하여 그 유동 특성을 원뿔형 회전점도계를 사용하여 $20-50^{\circ}C$의 온도범위에서 조사하였다. 꽃양배추색소추출액의 유동특성은 단순 power law model을 사용하여 설명할 수 있었다. 실험범위 내에서 꽃양배추색소추출액의 유동거동지수(n)와 점조도지수(K)는 각각 0.841-0.998 및 $0.008-31.525\;Pa{\cdot}s^n$의 값을 나타냈다. 겉보기점도의 온도의존성은 Arrhenius식에 의해 결정할 수 있었으며, 활성화에너지는 용액의 농도와 전단속도에 따라 9.36-52.48 kJ/mol의 값을 나타냈다. 전단속도 $100\;s^{-1}$에서 측정한 보기점도에 대한 용액의 농도와 온도의 영향을 다음과 같은 단일지수모델식으로 표시할 수 있었다; ${\ln}\;{\eta}_a\;=\;6.11\;-\;3103.94(1/T)\;-\;0.03C$.

• Corrosion Science and Technology
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• 제15권1호
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• pp.13-17
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• 2016

The aim of this study was to evaluate the use of iron-nickel oxide ($Fe_2O_3$.NiO) nanopowder (FeNi) as an anti-corrosion pigment for a different application. The corrosion protection ability and the mechanism involved was determined using aqueous solution of FeNi prepared in a corrosive solution containing 3.5 wt.% NaCl. Anti-corrosion abilities of aqueous solution were determined using electrochemical impedance spectroscopy (EIS) on line pipe steel (API 5L X-80). The protection mechanism involved the adsorption of metallic cations on the steel surface forming a protective film. Analysis of EIS spectra revealed that corrosion inhibition occurred at low concentration, whereas higher concentration of aqueous solution produced induction behavior.

• 한국생활과학회지
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• 제21권5호
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• pp.989-1004
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• 2012

The purpose of this study was to investigate the characteristics of the pigment and the dyeability of juniperus chinensis needles, berry, bark and heartwood extracts using distilled water, methanol, normal butanol and ethyl acetate as a solvent. Ultraviolet-visible absorption spectrum bands of the extracts were measured at around 280nm to 320nm in all the solvent extracts. The maximum absorption wavelength was able to determine tannin. All the solvent extracts except for distilled water extracts were able to confirm the presence of chlorophyll. Infrared absorption spectra (FT-IR) of all parts of the extracts showed broad absorption bands of OH due to phenolic-OH, benzene CH peak of phenol chemical structure, ether-based stretching vibration peak and the peak of flavonoid compounds that appeared in all the solvent extracts. The yield of juniper needles and heartwood in distilled water and methanol extraction were effective. Extraction of berry yields in distilled water was also effective. The yield of ethanol extraction from the bark showed better efficiency. As a result of using distilled water for the dye solution, the color of the fabrics dyed with all extracts of the needles and Y series berries generally showed light Y progression with a strong red tinge. By using a mixture of 20% ethanol and 80% distilled water for the dye solution, the color of the fabrics dyed with needles and berry extracts showed Y series dominantly. The color of the fabrics dyed with Bark and heartwood extracts were dominantly R series.

• 보존과학회지
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• 제32권3호
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• pp.417-423
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• 2016

백토안료의 제조 공정 중 분쇄 및 수비단계에서 아교수를 적용하고 이에 따른 영향을 분석하였다. 분쇄 공정에서 아교수를 적용한 경우, 일반 증류수를 사용했을 때보다 미분의 생성량이 감소하고 분급도가 향상되는 것으로 나타났다. 일반적으로 분쇄 성능 및 분쇄 한계에는 마찰력이 많은 영향을 미친다. 따라서 분쇄 조건에 따른 마찰력을 측정한 결과, 아교수를 적용한 경우 상대적으로 마찰력이 감소하는 것으로 확인되었다. 결국 분쇄 공정에서 아교수를 사용하는 것은 마찰력을 감소시켜 결과적으로 분급도를 향상시키기 위한 것으로 판단된다. 안료 제조 공정 중 수비단계에서 아교수를 적용한 결과, 아교수 적용 시 동일한 조건에서 보다 큰 입도의 입자를 수비해 내는 것이 가능한 것으로 나타났다. 이와 같은 결과는 수비액으로 아교수를 사용한 경우, 아교의 농도가 증가함에 따라 수비액의 점도가 증가하여 입자의 침강속도가 감소하기 때문인 것으로 확인되었다. 결국 수비 공정에서 아교수를 사용한 것은 수비액의 점도를 증가시켜 수비를 통해 선별할 수 있는 입도의 범위를 확대하고, 보다 세밀한 입도 구간으로 입자를 선별하기 위한 것으로 판단된다.

• 대한가정학회지
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• 제38권11호
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• pp.127-135
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• 2000

The natural dyestuff, grape skin dye was manufactured from grape skin by boiling in 0.1% HCI solution, eliminating the sugar and powdering in freeze dryer. Cotton, wool, silk and nylon fabrics were dyed under several conditions using the manufactured grape skin dye to investigate the dyeability and color fastness. Dyeing was operated in acidic dyebath of pH 4 because the grape skin is anionic. The color of dyed fabrics were affected on temperature of dyeing solution. Under 80$\^{C}$, the color of dyed fabrics were red or violet, but changed to brown in laundering. Above 100$\^{C}$, the color were brown and safe in laundering. Dyeabilities on wool, silk, and nylon fabrics were good, especially silk fabrics were dyed deeper than others. Dyeability was developed with concenturation of dyeing solution. All the dyed fabrics were excellent in color fastness to crocking and laundering. Light fastness was low to moderate. The light fastness of dyed nylon fabrics were as poor as grade 1, but they could be improved to grade 3∼4 by aftertreatment with gallic acid.

• 펄프종이기술
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• 제40권5호
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• pp.60-69
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• 2008

The principal reasons for applying a pigment coating to paper are to improve appearance and printability. The pigment coating provides a surface that is more uniform and more receptive to printing ink than are the uncoated fibers and, in turn, both facilitates the printing process and enhances the graphic reproduction. The improvement in print quality is readily apparent, especially in image areas or when multiple colors are involved. Although pigment coating of paper is to improve the printability, coated paper is not completely free from printing defects. Actually there are a number printing defects that are observed only with the coated papers. Among the printing defects that are commonly observed for coated papers, print mottle during multi-color offset printing is one of the most concerned defects, and it appears not only on solid tone area but also half dot print area. There are four main causes of print mottle ranging from printing inks, dampening solution, paper, and printing press or its operation. These indicates that almost every factors associated with lithographic printing can cause print mottle. Among these variation of paper quality influences most significantly on print mottle problems in multicolor offset printing, and this indicates that paper is most often to be blamed for its product deficiency as far as print mottle problems are concerned. Furthermore, most of the print mottle problems associated with paper is observed when coated papers are printed. Uncoated papers rarely show mottling problems. This indicates that print mottle is the most serious quality problems of coated paper products. Overcoming the print mottle is becoming more difficult because the operating speeds of coating and printing machines are increasing, coating weights are decreasing, and the demands on high-quality printing are increasing. Print mottle in offset printing is caused by (a) nonuniform back trap of ink caused by a nonuniform rate of ink drying, referred as "back trap mottle, and (b) nonuniform absorption of the dampening solution. Furthermore, both forms of print mottle have some relationship to the structure of the coated layer. The surest way of eliminating ink mottling is to eliminate unevenness in the base paper. Coating solutions, often easier to put into practice, should, however, be considered. In this paper the principal factors influencing print mottle of coated papers will be discussed. Especially the importance of base paper roughness, binder migration, even consolidation of coating layers, control of the drying rate, types of binders, etc. will be described.