• Title/Summary/Keyword: physico-chemistry

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Effects of Soil Amendment Application on Soil Physico-chemical Properties and Yields of Summer Forage Crops in the Sukmoon Reclaimed Tidal Land in Korea (석문 간척지에서 돈분액비 및 석고처리가 여름철 사료작물 수량 및 토양이화학성에 미치는 영향)

  • Choi, Ki-Choon;Yoon, Sei-Hyung;Shin, Jae-Soon;Kim, Dong-Kwan;Han, Hyo-Shim;Supanjani, Supanjani;Lee, Kyung-Dong
    • Korean Journal of Environmental Agriculture
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    • v.29 no.4
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    • pp.354-361
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    • 2010
  • Soil physico-chemical properties and microbial densities are affected by organic sources and soil amendment applied to improve soil environments or quality. Generally organic fertilizer effects on forage crops yield and soil properties are partly due to changes of soil composition. We investigated the effects of swine slurry (SS), swine slurry composting-biofilteration(SCB) and chemical fertilizer(F) with gypsum(G) combinations on soil physico-chemical properties and yields of summer forage crop in the Sukmoon reclaimed tidal land in Korea. The forage crops used in this experiment were corn and sorghum$\times$sudangrass hybrid(hereafter sorghum). Our results showed that the soil physico-chemical properties in the combined (F+G, SS+G, SCB+G) treatments increased contents of organic matter and exchangeable $Ca^{2+}$, but exchangeable $Na^+$, $K^+$ and $Mg^{2+}$ reduced to 1-10% for two forage crops, compared to non-combined (F, SS, SCB) treatment. The density of soil microorganism such as bacteria, actinomycetes and fungi, increased significantly by SS+G and SCB+G treatments. This means that treatment of combined organic fertilizer with G lowered salinity levels and improved with microbial growth. The combined treatments also increased the total yields 2.3-6.2% for corn and 2.0-8.7% for sorghum, compared with non-combined treatment. This experiment suggests the combined treatments could increase the total yields of summer forage crops and change of soil physico-chemical properties in the Sukmoon reclaimed tidal land in Korea.

Evaluation of the performance of encapsulated lifting system composting technology with a GORE(R) cover membrane: Physico-chemical properties and spectroscopic analysis

  • Al-Alawi, Mutaz;El Fels, Loubna;Benjreid, Ramadan;Szegi, Tamas;Hafidi, Mohamed;Simon, Barbara;Gulyas, Miklos
    • Environmental Engineering Research
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    • v.25 no.3
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    • pp.299-308
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    • 2020
  • Composting is among the most effective integrated waste management strategies used to recycle sewage sludge (SS) waste and generate a useful product. An encapsulated lifting system is a relatively new industrial-scale composting technology. The objective of this study was to evaluate the effectiveness of composting dewatered stabilized SS mixed with green waste using this new technology. The composting process was monitored by changes in the physico-chemical properties, UV-visible spectra, and fourier transform infrared (FTIR) spectra. The composting temperature was steady in the thermophilic range for 24 and 12 d in the intensive and maturation phases, respectively, which fulfilled the disinfection requirement. Moreover, the temperature increased rapidly to 76.8℃ within three days, and the thermophilic temperatures peaked twice and lasted longer than in traditional composting, which accelerated SS degradation and decreased the composting period necessary to obtain mature compost. FTIR spectroscopic analysis showed a diminished in methyl group derived from methylene C-H aliphatic groups because of organic matter degradation by microorganisms and an increased number of aromatic chains. The new technology may be a viable and sustainable alternative for SS management that converts waste into compost that is useful as a soil amendment.

Effects of mixture of improved Meju, Korean traditional Meju and Natto on soybean paste fermentation (재래 및 개량메주와 납두의 배합이 된장 발효에 미치는 영향)

  • Joo, Hyun-Kyu;Oh, Kyun-Teak;Kim, Dong-Hyun
    • Applied Biological Chemistry
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    • v.35 no.4
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    • pp.286-293
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    • 1992
  • This study was investigated on the change of physico-chemical properties at various mixture ratio of improved Meju and Natto during the aging of soybean paste. pH was increased on the improved Meju with increasing the mixture ratio of Natto, but pH was decreased in Korean traditional Meju. Change of nitrogen compound was 3 times higher and aging was faster in increased ratio of Korean traditional Meju than that of improved Meju. Brown color was not changed as compared to the initial stage, however the value of brown color was higher in the Korean traditional Meju than that of other group. In sensory evaluation, the mixture ratio of improved Meju, Korean traditional Meju and Natto (48 : 48 : 5) was the best acceptables.

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Physico-chemical properties of whole sweetpotatoes on precooking and frozen storage (고구마의 가열방법과 저장성에 따른 이화학적 성질)

  • Kum, Jun-Seok
    • Applied Biological Chemistry
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    • v.37 no.2
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    • pp.77-84
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    • 1994
  • Sweetpotatoes were baked (BK), microwaved (MW), microwaved/baked (MWBK), and microwaved/hold/microwaved (MWHO). Sugars, Huntercolors, compression and shear forces, sensory scores, moisture content, starch, and alcohol insoluble solids (AIS) were determined for each treatment. The BK roots contained higher (p<0.05) amount of sugars and less (p<0.05) starch. The MW roots contained higher (p<0.05) amount of starch, AIS, and less (p<0.05) sugar. The BK product resulted in the least (p<0.05) compression and shear forces needed to break it. The MW product demanded the greatest (p<0.05) force. The MWHO showed very similar results to the BK. Sensory scores for the BK and the MWHO sweetpotatoes were very acceptable. In color scores, the MWHO products were very acceptable and similar to the BK in flavor.

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Characteristics of Hydrogel Prepared from Microbial Poly($\gamma$-glutamic acid) by Chemical Crosslinker

  • Park, Jong-Soo;Choi, Seong-Hyun;Choi, Woo-Young;Yoon, Min-Ho
    • Journal of Applied Biological Chemistry
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    • v.48 no.4
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    • pp.213-217
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    • 2005
  • Microbial hydrogel was prepared with poly(${\gamma}$-glutamic acid) produced from Bacillus subtilis BS62 using crosslinking reagent, ethylene glycol diglycidyl ether (EGDE), and its physico-chemical characteristics were examined. Hydrogel which prepared from 10 grams of 10% PGA solution with $600\;{\mu}l$ of EGDE at $50^{\circ}C$ for 17 h swelled 4,320 times its dry weight, and time to reach swelling equilibrium in deionized water at 4 to $45^{\circ}C$ range was about 20 h. Swollen hydrogel shrunk in ionic solutions, and rate of shrinkage was higher in calcium chloride solution than sodium chloride solution. Swelling rate of hydrogel increased 1.3-fold of initial swelling rate for 30 min at $80^{\circ}C$.

Quantum Chemical Studies of Some Sulphanilamide Schiff Bases Inhibitor Activity Using QSAR Methods

  • Baher, Elham;Darzi, Naser;Morsali, Ali;Beyramabadi, Safar Ali
    • Journal of the Korean Chemical Society
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    • v.59 no.6
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    • pp.483-487
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    • 2015
  • The different calculated quantum chemical descriptors by DFT method were used for prediction of some sulphanilamide Schiff bases inhibitor activity as a binding constant (log K). Multiple linear regression (MLR) and artificial neural network (ANN) were employed for developing the useful quantitative structure activity relationship (QSAR) model. The obtained results presented superiority of ANN model over the MLR one. The offering QSAR model is very easy to computation and Physico-Chemically interpretable. Sensitivity analysis was used to determine the relative importance of each descriptor in ANN model. The order of importance of each descriptor according to this analysis is: molecular volume, molecular weight and dipole moment, respectively. These descriptors appear good information related to different structure of sulphanilamide Schiff bases can participate in their inhibitor activity.

HCA AND TWC HYBRID SYSTEM FOR REDUCING COLD-START EMISSION

  • Lee, S.C.;Jang, J.H.;Lee, B.Y.;Bae, J.H.;Choung, S.J.
    • International Journal of Automotive Technology
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    • v.5 no.1
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    • pp.1-7
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    • 2004
  • In line with the Super Ultra Low Emission Vehicle (SULEV) regulation, the main idea in this study has been focused on the utilization of hydrocarbon adsorber (HCA) to adsorb the excess hydrocarbons emitted during a period of engine cold-start, As main recipes of HCA materials, many types of zeolite as well as the combination of alumina and precious metals were used, Representative physico-chemical factors of zeolite such as acidic and hydrophobic properties were characterized. The optimum recipe of HCA materials was also determined. Among the acid properties of zeolites, the Si/Al ratio was found to be the most important factor to get higher hydrocarbon adsorption capacity.

Graphene oxide dispersed polyvinyl chloride/alkyd green nanocomposite film: Processing and physico-mechanical properties

  • Yadav, Mithilesh;Ahmad, Sharif;Chiu, Fang-Chyou
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.246-256
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    • 2018
  • Graphene oxide (GO) reinforced Polyvinyl chloride (PVC)-Waterborne Castor Alkyd (WCA) nanocomposites (PVC/WCA/GO) films were processed through solution blending technique. TGA showed that the thermal stability of PVC/WCA/GO-0.5 films was better than that of PVC/WCA blend film. With incorporation of 0.5 wt.% GO, the tensile strength and elastic modulus of the blend nanocomposite have significantly improved by about 260% and 185%, respectively, compared with neat polymer. The physicomechanical properties of these films suggest that the PVC/WCA/GO nanocomposite films may have a potential scope for their application in packaging industries. The results are supported by characterizations like FTIR, XRD, TEM and FESEM.

Mechanical properties and microstructure of innovative bio-mortar containing different aggregates

  • Abo-El-Eanein, S.A.;Abdel-Gawwad, H.A.;El-Mesallamy, Amani M.D.;El-Belbasi, Hussein I.;Ayoub, Hebah. G.
    • Geosystem Engineering
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    • v.21 no.5
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    • pp.291-296
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    • 2018
  • The aim of this work is to study the effect of aggregate type on the physico-mechanical properties and microstructure of bio-mortar (BM). Three different aggregates such as sand, dolomite and basalt were used. BM was prepared by mixing aggregates with bacterial cells (Sporosarcina Pasteurii) and one equimolar (1 M) of $urea/CaCl_2.2H_2O$. The results proved that the chemical composition and physical properties of aggregates play an important role in the microbial precipitation rate as well as size, morphology and crystallinity of the precipitated calcite, which strongly reflects on the properties of the prepared BM. The BM containing dolomite gave the highest compressive strength and lowest water absorption.

Physico-chemical Properties and Antibacterial Activities of Lactonic Sophorolipid (락톤형 소포로리피드의 물리화학적 특성 및 항균효과)

  • Cho, Soo A;Eom, Gyeong Tae;Jin, Byung Suk
    • Applied Chemistry for Engineering
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    • v.30 no.3
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    • pp.303-307
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    • 2019
  • Sophorolipid is a biological surfactant of the glycolipid structure produced by Candida bombicola, which generally exists as a mixture of acidic and lactonic forms. In this study, we investigated physico-chemical properties, antibacterial activities, and cytotoxicity of the sophorolipid containing more than 96% of the lactonic form, produced by the gene regulation of production strains and application of a metabolic engineering technique. The lactonic sophorolipid showed a weak acidity in the range of pH 3.2~4.6 when diluted in water at the concentrations from 1 to 0.001 wt%. The $pK_a$ value of the lactonic sophorolipid was estimated to be around 4.3 from the acid-base titration curve. The critical micelle concentration (CMC) of the lactonic sophorolipid was $10^{-2}wt%$, at which the surface tension of aqueous solution was reduced to 36 mN/m. The lactonic sophorolipid showed the minimum inhibitory concentrations (MIC) of $1{\times}10^{-3}$ and $5{\times}10^{-3}g/mL$ against Propionibacterium acnes and Corynebacterium xerosis, respectively. The MTT (3-(4,5-Dimethylthiazol-2-yl)-2,5-Diphenyltetrazolium Bromide] assay showed that cytotoxicity of the lactonic sophorolipid was ten times lower than that of triclosan.