• Title/Summary/Keyword: physical characterization

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Preparation and characterization of Mn doped copper nitride films with high photocurrent response

  • Yu, Aiai;Hu, Ruiyuan;Liu, Wei;Zhang, Rui;Zhang, Jian;Pu, Yong;Chu, Liang;Yang, Jianping;Li, Xing'ao
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1306-1312
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    • 2018
  • The Mn-doped copper nitride ($Cu_3N$) films with Mn concentration of 2.0 at. % have high crystallinity and uniform surface morphology. We found that the as-synthesized Mn-doped $Cu_3N$ films show suitable optical absorption in the visible region and the band gap is ~1.48 eV. A simple photodetector based on Mn doped $Cu_3N$ films was firstly fabricated via magnetron sputtering method. The fabricated device with doping of Mn demonstrated high photocurrent response and fast response shorter than 0.1 s both for rise and decay time superior to the pure $Cu_3N$. Furthermore, the energy levels of Mn-doped Cu3N matched well with ITO and Ag electrode. The excellent photoelectric properties reflect a good balance between sensitivities and response rate. Our investigation reveals the excellent potential of Mn-doped $Cu_3N$ films for application of photodetectors.

Characterization of exopolysaccharide-producing lactic acid bacteria from Taiwanese ropy fermented milk and their application in low-fat fermented milk

  • Ng, Ker-Sin;Chang, Yu-Chun;Chen, Yen-Po;Lo, Ya-Hsuan;Wang, Sheng-Yao;Chen, Ming-Ju
    • Animal Bioscience
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    • v.35 no.2
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    • pp.281-289
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    • 2022
  • Objective: The aim of this study was to characterize the exopolysaccharides (EPS)-producing lactic acid bacteria from Taiwanese ropy fermented milk (TRFM) for developing a clean label low-fat fermented milk. Methods: Potential isolates from TRFM were selected based on the Gram staining test and observation of turbid suspension in the culture broth. Random amplified polymorphic DNA-polymerase chain reaction, 16S rRNA gene sequencing, and API CHL 50 test were used for strain identification. After evaluation of EPS concentration, target strains were introduced to low-fat milk fermentation for 24 h. Fermentation characters were checked: pH value, acidity, viable count, syneresis, and viscosity. Sensory evaluation of fermented products was carried out by 30 volunteers, while the storage test was performed for 21 days at 4℃. Results: Two EPS-producing strains (APL15 and APL16) were isolated from TRFM and identified as Lactococcus (Lc.) lactis subsp. cremoris. Their EPS concentrations in glucose and lactose media were higher than other published strains of Lc. lactis subsp. cremoris. Low-fat fermented milk separately prepared with APL15 and APL16 reached pH 4.3 and acidity 0.8% with a viable count of 9 log colony-forming units/mL. The physical properties of both products were superior to the control yogurt, showing significant improvements in syneresis and viscosity (p<0.05). Our low-fat products had appropriate sensory scores in appearance and texture according to sensory evaluation. Although decreasing viable cells of strains during the 21-day storage test, low-fat fermented milk made by APL15 exhibited stable physicochemical properties, including pH value, acidity, syneresis and sufficient viable cells throughout the storage period. Conclusion: This study demonstrated that Lc. lactis subsp. cremoris APL15 isolated from TRFM had good fermentation abilities to produce low-fat fermented milk. These data indicate that EPS-producing lactic acid bacteria have great potential to act as natural food stabilizers for low-fat fermented milk.

Preparation and Characterization of Sodium Caseinate (CasNa)/Transglutaminase (TG)-coated Papers for Packaging (포장용 Sodium Caseinate(CasNa)/Transglutaminase(TG) 코팅지 제조 및 특성 분석)

  • Hwang, Jihyeon;Kim, Dowan
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.2
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    • pp.81-87
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    • 2022
  • Paper is a promising alternative to petroleum-based plastic materials for sustainable packaging applications. However, paper exhibits poor gas and water vapor barrier properties, which restrict its effective application in the packaging industry. To enhance the properties of papers, sodium caseinate (CasNa)/transglutaminase (TG) coating solutions with various TG contents were prepared and coated on the papers. The chemical and morphological structures, mechanical properties, seal strength, and water vapor barrier properties of the coated papers were thoroughly investigated. The paper properties depended significantly on the chemical and morphological structures. Pristine CasNa and CasNa/TG coating solutions were evenly coated on the paper surfaces, without any cracks. The chemical structure of the CasNa/TG coated papers was slightly influenced by TG addition, resulting in increased elongation at break and enhanced water barrier properties. To promote the use of CasNa-coated papers in packaging applications, additional investigations must be performed to prevent gas and moisture permeation and enhance the mechanical strength of these papers via chemical reactions and introduction of organic/inorganic composites.

Archaeometric Characterization of Raw Materials and Tempers of Bricks Used in the Brick Tombs during Ungjin Period of Baekje (백제 웅진기 벽돌무덤에 사용된 벽돌의 재료와 첨가물 특성 분석)

  • Sungyoon Jang;Hong Ju Jin
    • Economic and Environmental Geology
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    • v.55 no.6
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    • pp.571-582
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    • 2022
  • In this study, the raw material and tempers of bricks used in three brick tombs built in Gongju, during the Ungjin period of Baekje were investigated. The royal tomb of King Muryeong, the 6th tomb in the royal tombs, and Kyochonri brick tomb remained in Gongju and the bricks of each site had different shape and physical properties despite their similarity in raw materials. As the results of the mineralogical and microstructural analysis, the bricks of the royal tombs were made of refined raw materials, and were infrequently added crushed bricks(grogs) as a tempering material. On the other hand, thick and elongated pores of bricks from the Kyochonri brick tomb were frequently found, and the remains of plant carbonization are observed in their microstructures. Since the pores are mainly distributed in a thickness of 0.3 to 1 mm, it is estimated that bricks were produced by adding a certain size of the plant to refined soil, and grogs also were added as a tempering material. In particular, it was found that adding plants and grogs in raw materials of bricks caused thick pores or cracks in the internal structure. Since the bricks of the Kyochonri brick tomb have internal cracks and low firing temperature, the ultrasonic velocity of the bricks was lower than that of the royal tomb bricks. It means that the mechanical strength of these bricks were relatively low. Accordingly, it is estimated that the tempering materials, firing temperature, and internal structures of bricks can affect durability of the brick, and it can be thought as a difference in the manufacturing technology of brick making.

Uncertainty Estimation of Single-Channel Temperature Estimation Algorithm for Atmospheric Conditions in the Seas around the Korean Peninsula (한반도 주변해역 대기환경에 대한 싱글채널 온도추정 알고리즘의 불확도 추정)

  • Jong Hyuk Lee;Kyung Woong Kang;Seungil Baek;Wonkook Kim
    • Korean Journal of Remote Sensing
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    • v.39 no.3
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    • pp.355-361
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    • 2023
  • Temperature of the Earth's surface is a crucial physical variable in understanding weather and atmospheric dynamics and in coping with extreme heat events that have a great impact on living organismsincluding humans. Thermalsensors on satellites have been a useful meansfor acquiring surface temperature information for wide areas on the globe, and thus characterization of its estimation uncertainty is of central importance for the utilization of the data. Among various factors that affect the estimation, the uncertainty caused by the algorithm itself has not been tested for the atmospheric environment of Korean vicinity. Thisstudy derivesthe uncertainty of the single-channel algorithm under the local atmospheric and oceanic conditions by using reanalysis data and buoy temperature data collected around Korea. Atmospheric profiles were retrieved from two types of reanalysis data, the fifth generation of European Centre for Medium-Range Weather Forecasts reanalysis of the global climate and weather (ERA5) and Modern-Era Retrospective analysis for Research and Applications-2 (MERRA-2) to investigate the effect of reanalysis data. MODerate resolution atmospheric TRANsmission (MODTRAN) was used as a radiative transfer code for simulating top of atmosphere radiance and the atmospheric correction for the temperature estimation. Water temperatures used for MODTRAN simulations and uncertainty estimation for the single-channel algorithm were obtained from marine weather buoyslocated in seas around the Korean Peninsula. Experiment results showed that the uncertainty of the algorithm varies by the water vapor contents in the atmosphere and is around 0.35K in the driest atmosphere and 0.46K in overall, regardless of the reanalysis data type. The uncertainty increased roughly in a linear manner as total precipitable water increased.

A Fundamental Study on Laboratory Experiments in Rock Mechanics for Characterizing K-COIN Test Site (K-COIN 시험부지 특성화를 위한 암석역학 실내실험 기초 연구)

  • Seungbeom Choi;Taehyun Kim;Saeha Kwon;Jin-Seop Kim
    • Tunnel and Underground Space
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    • v.33 no.3
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    • pp.109-125
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    • 2023
  • Disposal repository for high-level radioactive waste secures its safety by means of engineered and natural barriers. The performance of these barriers should be tested and verified through various aspects in terms of short and/or long-term. KAERI has been conducting various in-situ demonstrations in KURT (KAERI Underground Research Tunnel). After completing previous experiment, a conceptual design of an improved in-situ experiment, i.e. K-COIN (KURT experiment of THMC COupled and INteraction), was established and detailed planning for the experiment is underway. Preliminary characterizations were conducted in KURT for siting a K-COIN test site. 15 boreholes with a depth of about 20 m were drilled in three research galleries in KURT and intact rock specimens were prepared for laboratory tests. Using the specimens, physical measurements, uniaxial compression, indirect tension, and triaxial compression tests were conducted. As a result, specific gravity, porosity, elastic wave velocities, uniaxial compressive strength, Young's modulus, Poisson's ratio, Brazilian tensile strength, cohesion, and internal friction angle were estimated. Statistical analyses revealed that there did not exist meaningful differences in intact rock properties according to the drilled sites and the depth. Judging from the uniaxial compressive strength, which is one of the most important properties, all the specimens were classified as very strong rock so that mechanical safety was secured in all the regions.

A study on the asperity degradation of rock joint surfaces using rock-like material specimens (유사 암석 시편을 사용한 암석 절리면 돌출부 손상 연구)

  • Hong, Eun-Soo;Kwon, Tae-Hyuk;Cho, Gye-Chun
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.11 no.3
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    • pp.303-314
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    • 2009
  • Image analyses for sheared joint specimens are performed to study asperity degradation characteristics with respect to the roughness mobilization of rock joints. Four different types of joint specimens, which are made of high-strength gypsum materials, are prepared by replicating the three-dimensional roughness of rock joints. About twenty jointed rock shear tests are performed at various normal stress levels. The characteristic and scale of asperity degradation on the sheared joint specimens are analyzed using the digital image analysis technique. The results show that the asperity degradation characteristic mainly depends on the normal stress level and can be defined by asperity failure and wear. The asperity degradation develops significantly around the peak shear displacement and the average amount of degraded asperities remains constant with further displacement because of new degradation of small scale asperities. The shear strength results using high-strength gypsum materials can not fully represent physical properties of each mineral particles of asperities on the natural rock joint surface. However the results of this quantitative estimation for the relationship between the peak shear displacement and the asperity degradation suggest that the characterization of asperity degradation provides an important insight into mechanical characteristics and shear models of rock joints.

Modified AWSSDR method for frequency-dependent reverberation time estimation (주파수 대역별 잔향시간 추정을 위한 변형된 AWSSDR 방식)

  • Min Sik Kim;Hyung Soon Kim
    • Phonetics and Speech Sciences
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    • v.15 no.4
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    • pp.91-100
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    • 2023
  • Reverberation time (T60) is a typical acoustic parameter that provides information about reverberation. Since the impacts of reverberation vary depending on the frequency bands even in the same space, frequency-dependent (FD) T60, which offers detailed insights into the acoustic environments, can be useful. However, most conventional blind T60 estimation methods, which estimate the T60 from speech signals, focus on fullband T60 estimation, and a few blind FDT60 estimation methods commonly show poor performance in the low-frequency bands. This paper introduces a modified approach based on Attentive pooling based Weighted Sum of Spectral Decay Rates (AWSSDR), previously proposed for blind T60 estimation, by extending its target from fullband T60 to FDT60. The experimental results show that the proposed method outperforms conventional blind FDT60 estimation methods on the acoustic characterization of environments (ACE) challenge evaluation dataset. Notably, it consistently exhibits excellent estimation performance in all frequency bands. This demonstrates that the mechanism of the AWSSDR method is valuable for blind FDT60 estimation because it reflects the FD variations in the impact of reverberation, aggregating information about FDT60 from the speech signal by processing the spectral decay rates associated with the physical properties of reverberation in each frequency band.

Utilization of Wood by-product and Development of Horticultural Growing Media (임산부산물을 이용한 원예용 혼합상토 개발)

  • Jung, Ji Young;Lim, Ki-Byung;Kim, Ji Su;Park, Han Min;Yang, Jae-Kyung
    • Horticultural Science & Technology
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    • v.33 no.3
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    • pp.435-442
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    • 2015
  • The main objective of this work was to identify and evaluate possible substrate alternatives or amendments to peat moss. This study involves the physical and chemical characterization and growth test of wood sawdust and wood fiber in order to evaluate their use as components of horticultural media. The carbohydrate content, C/N ratio, pH, phenolic compound, total porosity and water holding capacity were 58.9%, 425.1, 4.8, 181.8 ($mg{\cdot}g^{-1}$), 82.5% and 47.1% in wood sawdust and 41.1%, 240.8, 5.9, 29.8 ($mg{\cdot}g^{-1}$), 90.6% and 56.2% in wood fiber, respectively. Wood sawdust (K, $998.0mg{\cdot}100g^{-1}$ ; Ca, $1196.0mg{\cdot}100g^{-1}$; Mg, $105.6mg{\cdot}100g^{-1}$) and wood fiber (K, $1250.1mg{\cdot}100g^{-1}$; Ca, $1982.6mg{\cdot}100g^{-1}$; Mg, $173.1mg{\cdot}100g^{-1}$) showed adequate mineral elements properties compared to peat moss (K, $0.02mg{\cdot}100g^{-1}$; Ca, $0.57mg{\cdot}100g^{-1}$; Mg, $0.13mg{\cdot}100g^{-1}$) for their use as growing media. The mixtures of the horticultural media were prepared using different substrate as wood sawdust and wood fiber to grow Chinese cabbage (Brassica campestris L.) in a greenhouse. The seed germination, leaf area and stem height were 75%, $0.50cm^2$ and 2.8 cm in PS substrate (containing 30% peat moss, 10% perlite and 60% wood sawdust) and 95%, $0.65cm^2$ and 3.3 cm in PF substrate (containing 30% peat moss, 10% perlite and 60% wood fiber), respectively. The seed germination and stem height of the PF substrate (containing 30% peat moss, 10% perlite and 60% wood fiber) was higher than those in peat moss (control). Utilization of wood by-product can be considered as an alternative media component to substitute the widely using expensive peat moss.

Magnetic and Electric Transport Properties of MnTe Thin Film Grown by Molecular Beam Epitaxy (분자선 증착법에 의해 성장한 MnTe 박막의 자기적 및 전기수송 특성)

  • Kim, Woo-Chul;Bae, Sung-Whan;Kim, Sam-Jin;Kim, Chul-Sung;Kim, Kwang-Joo;Yoon, Jung-Bum;Jung, Myung-Hwa
    • Journal of the Korean Magnetics Society
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    • v.17 no.2
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    • pp.81-85
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    • 2007
  • MnTe layers of high crystalline quality were successfully grown on Si(100) : B and Si(111) substrates by molecular beam epitaxy (MBE). Under tellurium-rich condition and the substrate temperature around $400^{\circ}C$, a layer thickness of $700{\AA}$ could be easily obtained with the growth rate of $1.1 {\AA}/s$. We investigated the structural, magnetic and transport properties of MnTe layers by using x-ray diffraction (XRD), superconducting quantum interference device (SQUID) magnetometry, and physical properties measurement system (PPMS). Characterization of MnTe layers on Si(100) : B and Si(111) substrates by XRD revealed a hexagonal structure of polycrystals with lattice parameters, ${\alpha}=4.143{\pm}0.001{\AA}\;and\;c=6.707{\pm}0.001{\AA}$. Investigation of magnetic and transport properties of MnTe films showed anomalies unlike antiferromagnetic powder MnTe. The temperature dependence of the magnetization data taken in zero-field-tooling (ZFC) and field-cooling (FC) conditions indicates three magnetic transitions at around 21, 49, and 210 K as well as the great irreversibility between ZFC and FC magnetization in the films. These anomalies are attributable to a magnetic-elastic coupling in the films. Magnetization measurements indicate ferromagnetic behaviour with hysteresis loops at 5 and 300 K for MnTe polycrystalline film. The coercivity ($H_c$) values at 5 and 300 K are 55 and 44 Oe, respectively. In electro-transport measurements, the temperature dependence of resistivity revealed a noticeable semiconducting behaviours and showed conduction via Mott variable range hopping at low temperatures.